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Photoluminescence analysis of Lewis base coordinate europium(III) β-diketonate complex
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  • Journal title : Analytical Science and Technology
  • Volume 28, Issue 3,  2015, pp.204-211
  • Publisher : The Korean Society of Analytical Science
  • DOI : 10.5806/AST.2015.28.3.204
 Title & Authors
Photoluminescence analysis of Lewis base coordinate europium(III) β-diketonate complex
Sung-Hwan, Lee; Gyu-Hwan, Lee;
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Lanthanide complexes have attracted much attention because of their unique light emitting property. The light-emitting efficiencies of europium β-diketonate complexes were compared with those of complexes coordinated by the ligands of amines or phosphine oxides. The results demonstrated that the complexes that were coordinated by phosphine oxides had higher light-conversion performance than those coordinated by amines. The highest light-emitting efficiency was observed when the ligand of trioctylphosphine oxide was coordinated. In order to determine the coordination equivalency of trioctylphosphine oxide in the above complexes, 31P-NMR and their photoluminescence spectra were measured. The findings showed that the europium β-diketonate complex had one or two coordination equivalencies of trioctylphosphine oxide according to the steric hindrance of its original ligand.
europium β-diketonate;EuFOD;lanthanide;down shifting;trioctylphosphine oxide;
 Cited by
M. Haase and H. Schaefer, Angew. Chem., Int. Ed., 50, 5808-5829 (2011). crossref(new window)

A. Shalav, B. S. Richards, T. Trupke, K. W. Kramer and H. U. Gudel, J. Appl. Phys. Lett., 86, 013505 (2005). crossref(new window)

M. Pollnau, D. R. Gamelin, S. R. Luthi, H. U. Luthi and M. P. Hehlen, Phys. Rev., 61, 3337-3346 (2000). crossref(new window)

C. Strumpel, M. McCann, G. Beaucarne, V. Arkhipov, A. Slaoui, V. Svrcek, V. Svrcek, del C. Canizo and I. Tobias, Sol. Energy Mater. Sol. Cells., 91, 238-249 (2007). crossref(new window)

B. S. Richards, Sol. Energy Mater. Sol. Cells., 90, 2329-2337 (2006). crossref(new window)

T. Trupke, M. A. Green and P. Wurfel, J. Appl. Phys., 92, 1668-1674 (2002). crossref(new window)

J. Chrysochoos, J. Chem. Phys., 60, 1110-1112 (1974). crossref(new window)

M. Montalti, L. Prodi, N. Zaccheroni, L. Charbonniere, L. Douce and R. Ziessel, J. Am. Chem. Soc., 123, 12694-12695 (2001). crossref(new window)

G. Blasse, J. Chem. Phys., 45, 2356-2360 (1966). crossref(new window)

B. L. An, J. X. Shi, W. K. Wong, K. W. Cheah, R. H. Li, Y. S. Yanf and M. L. Gong, J. Lumin, 99, 155-160 (2002). crossref(new window)

K. Binnemans, Chem. Rev., 109, 4283-4374 (2009). crossref(new window)

H. R. Li, J. Lin, H. J. Zhang, L. S. Fu, Q. G. Meng and S. B. Wang, Chem. Mater., 14, 3651-3655 (2002). crossref(new window)

O. Laporte and W. F. Meggers, J. Optical Society Am, 11, 459-462 (1925). crossref(new window)

S. I. Weissman, J. Chem. Phys., 10, 214-217 (1942). crossref(new window)

A. Beeby, I. M. Clarkson, R. S. Dickins, S. Faulkner, D. Parker, L. Royle, A. S. de Sousa, J. A. Gareth Williams and M. Woods, J. Chem. Soc. Perkin Trans., 2, 493-503 (1999).

A. I. Voloshin, N. M. Shavaleev and V. P. Kazakov, J. Luminescence., 93, 191-197 (2001). crossref(new window)

A. H. Bruder, S. R. Tanny, H. A. Rockefeller and C. S. Springer, Inorg. Chem., 13, 880-885 (1974). crossref(new window)

G. Vicentini, L. B. Zinner, J. Zukerman-Schpector and Zinner, K. Coordination Chem. Rev., 196, 353-382 (2000). crossref(new window)

N. B. Lima, S. M. Goncalves, S. A. Junior and A. M. Simas, Sci. Reports., 3, 2395-2302 (2013). crossref(new window)

L. B. Melby, N. J. Rose, E. Abramson and J. C. Caris, J. Am. Chem. Soc., 86, 5117-5125 (1964). crossref(new window)

S. M. Mattson, E. J. Abramson and L. C. Thomson, J. less-common Metals., 112, 373-380 (1985). crossref(new window)

A. T. Kandil and K. Farah, J. Inorg. Nucl. Chem., 42, 1491-1494 (1980). crossref(new window)

H. Iwanaga, A. Amano, F. Furuya and Y. Yamasaki, Jpn. J. Apply. Phys., 45, 558-562 (2006). crossref(new window)