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Simultaneous and quantitative determination of anion biocides in soil by liquid chromatography-tandem mass spectrometry
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  • Journal title : Analytical Science and Technology
  • Volume 28, Issue 5,  2015, pp.317-322
  • Publisher : The Korean Society of Analytical Science
  • DOI : 10.5806/AST.2015.28.5.317
 Title & Authors
Simultaneous and quantitative determination of anion biocides in soil by liquid chromatography-tandem mass spectrometry
Yang, Eun-Young; Shin, Ho-Sang;
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Simultaneous analytical method has developed for the determination of anion biocides in soil by liquid chromatography-tandem mass spectrometry (LC-MS/MS). Chlorite and chlorate in soil were extracted with pure water, and cyanuric acid and sodium dodecylbenzenesulfonate (Na-DBS) were extracted with mobile phase (0.25 mM ammonium formate in 20 mM formic acid : acetonitrile (1:1)). The extract was injected into the LC-MS/MS system after filtration. The method detection limits in this study were 0.04 mg/kg for chlorite, 0.04 mg/kg for chlorate, 0.27 mg/kg for cyanuric acid, and 0.05 mg/kg for Na-DBS, respectively. The method was applied to the analysis of 50 soil samples collected from 40 sites sprayed with biocides and 10 background sites. As a result, anion biocides were not detected in all sites.
chlorite;chlorate;cyanuric acid;Na-DBS;soil;LC-MS/MS;
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