Advanced SearchSearch Tips
Development of On-Site Process for Refractory 2,4-Dichlorophenol Treatment
facebook(new window)  Pirnt(new window) E-mail(new window) Excel Download
 Title & Authors
Development of On-Site Process for Refractory 2,4-Dichlorophenol Treatment
Park, Kyeong-Deok; Kim, Il-Kyu;
  PDF(new window)
This study showed that on-site ferrate(VI) solution was synthesized by wet oxidation method and applied aqueous 2,4-dichlorophenol(DCP) solution to evaluate the degradation efficiency. On-site ferrate(VI) solution was synthesized by putting in the strong alkali solution with NaClO and NaOH and applied DCP solution directly. DCP solution was extracted by the liquid-liquid method and analyzed by GC-ECD. The factors such as pH, DCP initial concentration, injected ferrate(VI) dosage, temperature were investigated. The optimum pH and temperature conditions of DCP degradation were obtained in neutral condition and . And the experimental results showed that DCP removal efficiency also increased with the decrease of DCP initial condition and the injected ferrate(VI) dosage.
2,4-Dichlorophenol;On-Site Process;Various Aqueous Conditions;Selective Oxidation;Ferrate(VI);
 Cited by
A. Karci, I. Arslan-Alaton, T. Olmez-Hanci and M. Bekbolet, 2012, "Transformation of 2,4-Dichlorophenol by $H_2O_2$-UV-C, Fenton and Photo-Fenton Processes: Oxidation Products and Toxicity Evolution", Journal of Photochemistry and Photobiology A: Chemistry. Vol. 230, pp. 65-73. crossref(new window)

D. Petroutsos, P. Katapodis, M. Samiotaki, G. Panayotou and D. Kekos, 2008, "Detoxification of 2,4-Dichlorophenol by the Marine Microalga Tetraselmis Marina", Phytochemistry, Vol. 69, No. 3, pp. 707-714. crossref(new window)

O. E. Igbinosa, E. E. Odjadjare, V. N. Chigor, I. H. Igbinosa, A. O. Emoghene, F. O. Ekhaise, N. O. Igiehon and O. G. Idemudia, 2013, "Toxicological Profile of Chlorophenols and Their Derivatives in the Environment The Public Health Perspective", The Scientific World Journal, Vol. 2013, pp. 1-11.

W. Z. Tang and C. P. Huang, 1996, "2,4-Dichlorophenol Oxidation Kinetics by Fenton's Reagent", Environmental Technology, Vol. 17, pp. 1371-1378. crossref(new window)

L. F. Kenneth and O. Hutzinger, 1996, "Polychlorinated Benzene, Phenol, Dibenzo-PDioxin, and Dibenzofuran in Heterogeneous Combustion Reactions of Acetylene", Environ. Sci. Technol., Vol. 30, No. 3, pp. 998-1008. crossref(new window)

I. Kim, 2014, "Degradation of 2,3-dichlorophenol by a Photo-Fenton Process with Continuous Pump-Feeding of Hydrogen Peroxide", Journal of the Korean Society for Power System Engineering Vol. 18, No. 6, pp. 84-90.

S. Hager, R. Bauer and G. Kudielka, 2000, "Photocatalytic Oxidation of Gaseous Chlorinated Organics over Titanium Dioxide", Chemosphere, Vol. 41, No. 8, pp. 1219-1225. crossref(new window)

Y. H. Lee, M. Cho, J. Y. Kim and J. Y. Yoon, 2004, "Chemistry of Ferrate (Fe(VI)) in Aqueous Solution and Its Applications as a Green Chemical", J. Ind. Eng. Chem., Vol. 10, No. 1, pp. 161-171.

V. K. Sharma, 2002, "Potassium ferrate(VI); an Environmentally Friendly Oxidant", Advances in Environmental Research, Vol. 6, pp. 143-156. crossref(new window)

S. Licht and X. Yu, 2005, "Electrochemical Alkaline Fe(VI) Water Purification and Remediation," Environ. Sci. Technol., Vol. 39, No. 20, pp. 8071-8076. crossref(new window)

Y. H. Lee, I. H. Um and J. Y. Yoon, 2003, "Arsenic(III) Oxidation by Iron(VI) (Ferrate) and Subsequent Removal of Arsenic(V) by Iron(III) Coagulation", Environ. Sci. Technol., Vol. 37, No. 24, pp. 5750-5756. crossref(new window)

J. H. Nam, I. K. Kim, J. H. Kwon and Y. D. Kim, 2015, "Applications of Electrochemical ferrate(VI) for Degradation of Trichloroethylene in the Aqueous Phase", Desalination and Water Treatment, pp. 1-8.

Q. Han, H. Wang, W. Dong, T. Liu, Y. Yin and H. Fan, 2015, "Degradation of Bisphenol A by ferrate(VI) Oxidation; Kinetics, Products and Toxicity Assessment", Chemical Engineering Journal, Vol. 262, pp. 34-40. crossref(new window)

P. Zhang, G. Zhang, J. Dong, M. Fan and G. Zeng, 2012, "Bisphenol A Oxidative Removal by Ferrate (Fe(VI)) under a Weak Acidic Condition", Separation and Purification Technology, Vol. 84, No. 9, pp. 46-51. crossref(new window)

B. Yang, G. G. Ying, Z. F. Chen, J. L. Zhao, F. Q. Peng and X. W. Chen, 2014, "Ferrate(VI) Oxidation of Tetrabromobisphenol A in Comparison with Bisphenol A", Water Research, Vol. 62, No. 1, pp. 211-219. crossref(new window)

B. Yang, G. G. Ying, L. J. Zhang, L. J. Zhou, S. Liu and Y. X. Fang, 2011, "Kinetics Modeling and Reaction Mechanism of ferrate(VI) Oxidation of Benzotriazoles", water research, Vol. 45, pp. 2261-2269. crossref(new window)

V. K. Sharma, J. O. Smith and F. J. Millero, 1997, "Ferrate(VI) Oxidation of Hydrogen Sulfide", Environ. Sci. Technol., Vol. 31, No. 9, pp. 2486-2491. crossref(new window)

V. K. Sharma, W. Rivera, J. O. Smith and B. O'Brien, 1998, "Ferrate(VI) Oxidation of Aqueous Cyanide", Environ. Sci. Technol., Vol. 32, No. 17, pp. 2608-2613. crossref(new window)

Y. Wang, H. Liu, G. Liu, Y. Xie and S. Gao, 2015, "Oxidation of Diclofenac by Potassium Ferrate (VI): Reaction Kinetics and Toxicity Evaluation", Science of the Total Environment, Vol. 506-507, pp. 252-258. crossref(new window)

M. H. Lim and M. J. Kim, 2009, "Removal of Natural Organic Matter from River Water Using Potassium Ferrate(VI)", Water Air Soil Pollut, Vol. 200, pp. 181-189. crossref(new window)

G. R. Xu, Y. P. Zhang and G. B. Li, 2009, "Degradation of Azo Dye Active Brilliant Red X-3B by Composite Ferrate Solution", Journal of Hazardous Materials, Vol. 161, No. 2-3, pp. 1299-1305. crossref(new window)

R. Prucek, J. Tucek, J. Kolarik, I. Huskova, J. Filip, R. S. Varma, V. K. Sharma and R. Zboril, 2015, "Ferrate(VI)-Prompted Removal of Metals in Aqueous Media: Mechanistic Delineation of Enhanced Efficiency via Metal Entrenchment in Magnetic Oxides", Environ. Sci. Technol., Vol. 49, pp. 2319-2327. crossref(new window)

X. Tang, H. Zheng, H. Teng, Y. Sun, J. Guo, W. Xie, Q. Yang and W. Chen, 2014, "Chemical Coagulation Process for the Removal of Heavy Metals from Water: a Review", Desalination and Water Treatment, pp. 1-16.

S. Sailo, L. Pachuau, J. K. Yang, S. M. Lee,and D. Tiwari, 2015, "Efficient Use of ferrate(VI) for the Remediation of Wastewater Contaminated with Metal Complexes", Environ. Eng. Res., Vol. 20, No. 1, pp. 89-97. crossref(new window)

J. Ma and W. Liu, 2002, "Effectiveness and Mechanism of Potassium ferrate(VI) Preoxidation for Algae Removal by Coagulation", Water Research, Vol. 36, pp. 871-878. crossref(new window)

R. Gandhi, 2013, "Treatment of Combined Sewer Overflows Using Ferrate (VI)", The University of Western Ontario.

V. K. Sharma, R. A. Rendon, F. J. Millero and F. G. Vazquez, 2000, "Oxidation of Thioacetamide by ferrate(VI)", Marine Chemistry, Vol. 70, No. 1-3, pp. 235-242. crossref(new window)

D. Tiwari, H. U. Kim, B. J. Choi, S. M. Lee, O. H. Kwon, K. M. Choi and J. K. Yang, 2007, "Ferrate(VI); A Green Chemical for the Oxidation of Cyanide in Aqueous-Waste Solutions", Journal of Environmental Science and Health, Part A: Toxic/Hazardous Substances and Environmental Engineering, Vol. 42, No. 6, pp. 803-810. crossref(new window)

N. Graham, C. C. Jiang, X. Z. Li, J. Q. Jiang and J. Ma, 2004, "The Influence of pH on the Degradation of Phenol and Chlorophenols by Potassium Ferrate", Chemosphere, Vol. 56, pp. 949-956. crossref(new window)

F. J. Benitez, J. Beltran-Heredia, J. L. Acero and F. J. Rubio, 2000, "Rate Constants for the Reactions of Ozone with Chlorophenols in Aqueous Solutions", Journal of Hazardous Materials, Vol. 79, No. 3, pp. 271-285. crossref(new window)

Z. Macova, K. Bouzek, J. Hives, V. K. Sharma, R. J. Terryn and J. C. Baum, 2009, "Research Progress in the Electrochemical Synthesis of ferrate(VI)", Electrochimica Acta, Vol. 54, No. 10, pp. 2673-2683. crossref(new window)

W. F. Wagner, J. R. Gurip and E. N. Hart, 1952, "Factors Affecting Stability of Aqueous Potassium Ferrate(VI) Solutions", Anal. Chem., Vol. 24, No. 9, pp. 1497-1498. crossref(new window)