Publisher : Korean Society of Environmental Engineering
DOI : 10.4491/eer.2014.029
Title & Authors
Characterization of Quintinite Particles in Fluoride Removal from Aqueous Solutions Kim, Jae-Hyun; Park, Jeong-Ann; Kang, Jin-Kyu; Son, Jeong-Woo; Yi, In-Geol; Kim, Song-Bae;
The aim of this study was to characterize quintinite in fluoride removal from aqueous solutions, using batch experiments. Experimental results showed that the maximum adsorption capacity of fluoride to quintinite was 7.71 mg/g. The adsorption of fluoride to quintinite was not changed at pH 5-9, but decreased considerably in highly acidic (pH < 3) and alkaline (pH > 11) solution conditions. Kinetic model analysis showed that among the three models (pseudo-first-order, pseudo-second-order, and Elovich), the pseudo-second-order model was the most suitable for describing the kinetic data. From the nonlinear regression analysis, the pseudo-second-order parameter values were determined to be and . Equilibrium isotherm model analysis demonstrated that among the three models (Langmuir, Freundlich, and Redlich-Peterson), both the Freundlich and Redlich-Peterson models were suitable for describing the equilibrium data. The model analysis superimposed the Redlich-Peterson model fit on the Freundlich fit. The Freundlich model parameter values were determined from the nonlinear regression to be and 1/n=0.51. This study demonstrated that quintinite could be used as an adsorbent for the removal of fluoride from aqueous solutions.
Nanocomposite for the detoxification of drinking water: effective and efficient removal of fluoride and bactericidal activity, New J. Chem., 2015, 39, 12, 9143
Recent advances and spectroscopic perspectives in fluoride removal, Applied Spectroscopy Reviews, 2016, 1
Analytical methods for determination and sensing of fluoride in biotic and abiotic sources: a review, Anal. Methods, 2016, 8, 27, 5338
Phosphate sorption to quintinite in aqueous solutions: Kinetic, thermodynamic and equilibrium analyses, Environmental Engineering Research, 2015, 20, 1, 73
A new efficient forest biowaste as biosorbent for removal of cationic heavy metals, Bioresource Technology, 2015, 175, 629
Delorme F, Seron A, Gautier A, Crouzet C. Comparison of the fluoride, arsenate and nitrate anions water depollution potential of a calcined quintinite, a layered double hydroxide compound. J. Mater. Sci. 2007;42:5799-5804.
Miyata S. Anion-exchange properties of hydrotalcite-like compounds. Clays Clay Miner. 1983;31:305-311.
Hernandez-Moreno MJ, Ulibarri MA, Rendon JL, Serna CJ. IR characteristics of hydrotalcite-like compounds. Phys. Chem. Miner. 1985;12:34-38.
Costantino U, Marmottini F, Nocchetti M, Vivani R. New synthetic routes to hydrotalcite-like compounds: characterisation and properties of the obtained materials. Eur. J. Inorg. Chem. 1998;1998:1439-1446.
Goh KH, Lim TT, Dong Z. Application of layered double hydroxides for removal of oxyanions: a review. Water Res. 2008;42:1343-1368.
Ma W, Zhao N, Yang G, Tian L, Wang R. Removal of fluoride ions from aqueous solution by the calcination product of Mg-Al-Fe hydrotalcite-like compound. Desalination 2011;268:20-26.
Cai P, Zheng H, Wang C, et al. Competitive adsorption characteristics of fluoride and phosphate on calcined Mg-Al-CO3 layered double hydroxides. J. Hazard. Mater. 2012;213-214:100-8.
Ayoob S, Gupta AK. Fluoride in drinking water: a review on the status and stress effects. Crit. Rev. Environ. Sci. Technol. 2006;36:433-487.
Mohapatra M, Anand S, Mishra BK, Giles DE, Singh P. Review of fluoride removal from drinking water. J. Environ. Manag. 2009;91:67-77.
Bhatnagar A, Kumar E, Sillanpaa M. Fluoride removal from water by adsorption: a review. Chem. Eng. J. 2011;171:811-840.
Lv L, He J, Wei M, Evans DG, Zhou Z. Treatment of high fluoride concentration water by MgAl-CO3 layered double hydroxides: kinetic and equilibrium studies. Water Res. 2007;41:1534-1542.
Batistella L, Venquiaruto LD, Luccio MD, et al. Evaluation of acid activation under the adsorption capacity of double layered hydroxides of Mg-Al-CO3 type for fluoride removal from aqueous medium. Ind. Eng. Chem. Res. 2011;50:6871-6876.
Mandal S, Mayadevi S. Defluoridation of water using as-synthesized Zn/Al/Cl anionic clay adsorbent: Equilibrium and regeneration studies. J. Hazard. Mater. 2009;167:873-878.
Kim JH, Lee CG, Park JA, Kang JK, Yoon SY, Kim SB. Fluoride removal using calcined Mg/Al layered double hydroxides at high fluoride concentrations. Water Sci. Technol. Water Supply 2013;13:249-256.
Lv L. Defluoridation of drinking water by calcined MgAl-CO3 layered double hydroxides. Desalination 2007;208:125-133.
Wang H, Chen J, Cai Y, Ji J, Liu L, Teng HH. Defluoridation of drinking water by Mg/Al hydrotalcite-like compounds and their calcined products. Appl. Clay Sci. 2007;35:59-66.
Lv L, He J, Wei M, Evans DG, Duan X. Factors influencing the removal of fluoride from aqueous solution by calcined Mg-Al-CO3 layered double hydroxides. J. Hazard. Mater. 2006;133:119-128.
Das DP, Das J, Parida K. Physicochemical characterization and adsorption behavior of calcined Zn/Al hydrotalcite-like compounds (HTlc) towards removal of fluoride from aqueous solution. J. Colloid Interface Sci. 2003;261:213-220.
Diaz-Nava C, Solache-Rios M, Olguin MT. Sorption of fluoride ions from aqueous solutions and well drinking water by thermally treated hydrotalcite. Sep. Sci. Technol. 2003;38:131-147.
Zhou J. Cheng Y. Yu J. Liu G. Hierarchically porous calcined lithium/aluminum layered double hydroxides: facile synthesis and enhanced adsorption towards fluoride in water. J. Mater. Chem. 2011;21:19353-19361.
Mandal S, Mayadevi S. Adsorption of fluoride ions by Zn-Al layered double hydroxides. Appl. Clay Sci. 2008;40:54-62.
Yu CH, Al-Saadi A, Shih SJ, Qiu L, Tam KY, Tsang SC. Immobilization of BSA on silica-coated magnetic iron oxide nanoparticle. J. Phys. Chem. C 2009;113:537-543.
Han YU, Lee WS, Lee CG, Park SJ, Kim KW, Kim SB. Entrapment of Mg-Al layered double hydroxide in calcium alginate beads for phosphate removal from aqueous solution. Desalination Water Treat. 2011;36:178-186.
Zhang L, Hong S, He J, Gan F, Ho YS. Adsorption characteristic studies of phosphorus onto laterite. Desalination Water Treat. 2011;25:98-105.
Halsey G. Physical adsorption on non-uniform surfaces. J. Chem. Phys. 1948;16:931-937.