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Sequential adsorption - photocatalytic oxidation process for wastewater treatment using a composite material TiO2/activated carbon
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  • Journal title : Environmental Engineering Research
  • Volume 20, Issue 2,  2015, pp.181-189
  • Publisher : Korean Society of Environmental Engineering
  • DOI : 10.4491/eer.2014.070
 Title & Authors
Sequential adsorption - photocatalytic oxidation process for wastewater treatment using a composite material TiO2/activated carbon
Andriantsiferana, Caroline; Mohamed, Elham Farouk; Delmas, Henri;
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A composite material was tested to eliminate phenol in aqueous solution combining adsorption on activated carbon and photocatalysis with in two different ways. A first implementation involved a sequential process with a loop reactor. The aim was to reuse this material as adsorbent several times with in situ photocatalytic regeneration. This process alternated a step of adsorption in the dark and a step of photocatalytic oxidation under UV irradiation with or without . Without , the composite material was poorly regenerated due to the accumulation of phenol and intermediates in the solution and on particles. In presence of , the regeneration of the composite material was clearly enhanced. After five consecutive adsorption runs, the amount of eliminated phenol was twice the maximum adsorption capacity. The phenol degradation could be described by a pseudo first-order kinetic model where constants were much higher with (about tenfold) due to additional radicals. The second implementation was in a continuous process as with a fixed bed reactor where adsorption and photocatalysis occurred simultaneously. The results were promising as a steady state was reached indicating stabilized behavior for both adsorption and photocatalysis.
Activated carbon;Adsorption;Advanced oxidation process;Hydrogen peroxide;Photocatalysis;Titanium dioxide;
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Lagunas-Allue L, Martinez-Soria MT, Sanz-Asensio J, Salvador A, Ferronato C, Chovelon JM. Photocatalytic degradation of boscalid in aqueous titanium dioxide suspension: Identification of intermediates and degradation pathways. Appl. Catal. B 2010;98:122-131. crossref(new window)

Elmolla ES, Chaudhuri M. Photocatalytic degradation of amoxicillin, ampicillin and cloxacillin antibiotics in aqueous solution using UV/$TiO_2$ and UV/$H_2O_2$/$TiO_2$ photocatalysis. Desalination 2010;252:46-52. crossref(new window)

HHH Lin, AYC Lin. Photocatalytic oxidation of 5-fluorouracil and cyclophosphamide via UV/$TiO_2$ in an aqueous environment. Water Res. 2014;48:559-568. crossref(new window)

Konstantinou IK, Albanis TA. $TiO_2$-assisted photocatalytic degradation of azo dyes in aqueous solution: kinetic and mechanistic investigations. A review. Appl. Catal. B 2004;49:1-14. crossref(new window)

Rizzo L. Bioassays as a tool for evaluating advanced oxidation processes in water and wastewater treatment. Water Res. 2011;45:4311-4340. crossref(new window)

Benoit-Marquie F, Puech-Costes E, Braun A, Oliveros E, Maurette MT. Photocatalytic degradation of 2,4-dihydroxybenzoic acid in water : efficiency optimization and mechanistic investigation. J. Photochem. Photobiol. A chem. 1997;108: 65-71. crossref(new window)

Arana J, Melian JAH, Rodriguez JMD, et al. $TiO_2$-photocatalysis as a tertiary treatment of naturally treated wastewater. Catal. Today 2002;76:279-289. crossref(new window)

Areerachakul N, Vigneswaran S, Ngo HH, Kandasamy J. Granular activated carbon (GAC) adsorption-photocatalysis hybrid system in the removal of herbicide from water. Sep. Purif. Technol. 2007;55:206-211. crossref(new window)

Zhang L, Kanki T, Sano N, Toyoda A. Development of $TiO_2$ photocatalyst reaction for water purification. Sep. Purif. Technol. 2003;31:105-110. crossref(new window)

Shon HK, Vigneswaran S, Ngo HH, Kim JH. Chemical coupling of photocatalysis with flocculation and adsorption in the removal of organic matter. Water Res. 2005;39:2549-2558. crossref(new window)

Lee DK, Kim SC, Cho IC, Kim SJ, Kim SW. Photocatalytic oxidation of microcystin-LR in a fluidized bed reactor having $TiO_2$-coated activated carbon. Sep. Purif. Technol. 2004;34: 59-66. crossref(new window)

Toyoda M, Nanbu Y, Kito T, Hiranob M, Inagaki M. Preparation and performance of anatase-loaded porous carbons for water purification. Desalination 2003;159:273-282. crossref(new window)

Tao Y, Schwartz S, Wu CY, Mazyck DW. Development of a $TiO_2$/AC composite photocatalyst by dry impregnation for the treatment of methanol in humid airstreams. Ind. Eng. Chem. Res. 2005;44:7366-7372. crossref(new window)

Kim KD, Dey NK, Seo HO, Kim YD, Lim DC, Lee M. Photocatalytic decomposition of toluene by nano-diamond supported $TiO_2$ prepared using atomic layer deposition. Appl. Catal. A: Gen. 2011;408:148-155. crossref(new window)

Sun J, Wang X, Sun J, Sun R, Sun S, Qiao L. Photocatalytic degradation and kinetics of Orange G using nano-sized Sn(IV)/$TiO_2$/AC photocatalyst. J. Mol. Catal. A Chem. 2006; 260:241-246. crossref(new window)

El-Sheikh AH, Newman AP, Al-Daffaee H, Phull S, Cresswell N, York S. Deposition of anatase on the surface of activated carbon. Surf. Coat. Technol. 2004;187:284-292. crossref(new window)

Andriantsiferana C, Mohamed EF, Delmas H. Photocatalytic degradation of an azo-dye on $TiO_2$/activated carbon composite material. Environ. Technol. 2014;35:355-363. crossref(new window)

Mills A, Elliott N, Parkin IP, O'Neill SA, Clark RJ. Novel $TiO_2$ CVD films for semiconductor photocatalysis. J. Photochem. Photobiol. A Chem. 2002;151:171-179. crossref(new window)

Zhang X, Zhou M, Lei L. Preparation of photocatalytic $TiO_2$ coatings of nanosized particles on activated carbon by APMOCVD. Carbon 2005;43:1700-1708. crossref(new window)

Teng F, Zhang G, Wang Y, et al. The role of carbon in the photocatalytic reaction of carbon/$TiO_2$ photocatalysts. Appl. Surf. Sci. 2014;320:703-709. crossref(new window)

Horikoshi S, Sakamoto S, Serpone N. Formation and efficacy of $TiO_2$/AC composites prepared under microwave irradiation in the photoinduced transformation of the 2-propanol VOC pollutant in air. Appl. Catal. B 2013;140-141:646-651. crossref(new window)

Tanguay JF, Suib SL, Coughlin RW. Dichloromethane photodegradation using titanium catalysts. J. Catal. 1989;117: 335-347. crossref(new window)

Fernandez A, Lassaletta G, Jimenez VM, et al. Preparation and characterization of $TiO_2$ photocatalysts supported on various rigid supports (glass, quartz and stainless steel), Comparative studies of photocatalytic activity in water purification. Appl. Catal. B 1995;7:49-63. crossref(new window)

Zazueta ALL, Destaillats H, Puma GL. Radiation field modeling and optimization of a compact and modular multi-plate photocatalytic reactor (MPPR) for air/water purification by Monte Carlo method. Chem. Eng. J. 2013;217:475-485. crossref(new window)

Matos J, Laine J, Hermann JM. Effect of the type of activated carbons on the photocatalytic degradation of aqueous organic pollutants by UV-irradiated titania. J. Catal. 2001;200:10-20. crossref(new window)

Goei R, Lim TT. Asymmetric $TiO_2$ hybrid photocatalytic ceramic membrane with porosity gradient: Effect of structure directing agent on the resulting membranes architecture and performances. Ceram. Int. 2014;40:6747-6757. crossref(new window)

Tryba B, Morawski AW, Inagaki M. Application of $TiO_2$- mounted activated carbon to the removal of phenol from water. Appl. Catal. B 2003;41:427-433. crossref(new window)

Tsumura T, Kojitani N, Umemura H, Toyoda M, Inagaki M. Composites between photoactive anatase-type $TiO_2$ and adsorptive carbon. Appl. Surf. Sci. 2002;196:429-436. crossref(new window)

Herrmann JM. Heterogeneous photocatalysis: fundamentals and applications to the removal of various types of aqueous pollutants. Catal. Today 1999;53:115-129. crossref(new window)

Matos J, Laine J, Hermann JM, Uzcategui D, Brito JL. Influence of activated carbon upon titania on aqueous photocatalytic consecutive runs of phenol photodegradation. Appl. Catal. B 2007;70:461-469. crossref(new window)

Garcia-Munoz P, Carbajo J, Faraldos M, Bahamonde A. Photocatalytic degradation of phenol and isoproturon: Effect of adding an activated carbon to titania catalyst. J. Photochem. Photobiol. A Chem. 2014;287:8-18. crossref(new window)

Ao CH, Lee SC. Enhancement effect of $TiO_2$ immobilized on activated carbon fiber for the photodegradation of pollutants at typical indoor air level. Appl. Catal. B 2003;44:191-205. crossref(new window)

Chiang YC, Chiang PC, Huang CP. Effects of pore structure and temperature on VOC adsorption on activated carbon. Carbon 2001;39:523-534. crossref(new window)

Wang JP, Chen YZ, Feng HM, Zhang SJ, Yu HQ. Removal of 2,4 - dichlorophenol from aqueous solution by static-air-activated carbon fibers. J. Colloid Interface Sci. 2007;313: 80-85. crossref(new window)

Augugliaro V, Palmisano L, Schiavello M, Sclafani A. Photocatalytic degradation of nitrophenols in aqueous titanium dioxide dispersion. Appl. Catal. 1991;69:323-340. crossref(new window)

Gupta H, Tanaka S. Photocatalytic mineralisation of perchlororthylene using titanium dioxide. Water Sci. Technol. 1995;31:47-54.

Herrmann JM, Guillard C, Pichat P. Heterogeneous photocatalysis: an emerging technology for water treatment. Catal. Today 1993;17:7-20. crossref(new window)

Chu W. Modeling the quantum yields of herbicide 2,4-D decay in UV/$H_2O_2$ process. Chemosphere 2001;44:935-941. crossref(new window)

Dionysiou DD, Suidan MT, Baudin I, Laine JM. Effect of hydrogen peroxide on the destruction of organic contaminants-synergism and inhibition in a continuous-mode photocatalytic reactor. Appl. Catal. B 2004;50:259-269. crossref(new window)

Chen S, Liu Y. Study on the photocatalytic degradation of glyphosate by $TiO_2$ photocatalyst. Chemosphere 2007;67: 1010-1017. crossref(new window)

Achilleos A, Hapeshi E, Xekoukoulotakis NP, Mantzavinos D, Fatta-Kassinosa D. Factors affecting diclofenac decomposition in water by UV-A/$TiO_2$ photocatalysis. Chem. Eng. J. 2010;161:53-59. crossref(new window)

Ilisz I, Laszlo Z, Dombi A. Investigation of the photodecomposition of phenol in near-UV-irradiated aqueous $TiO_2$ suspension. I: Effect of charge-trapping species on the degradation kinetic. Appl. Catal. A 1999;180:25-33. crossref(new window)

Adan C, Carbajo J, Bahamonde A, Martinez-Arias A. Phenol photodegradation with oxygen and hydrogen peroxide over $TiO_2$ and Fe-doped $TiO_2$. Catal. Today 2009;143:247-252. crossref(new window)

Brunauer S, Emmett PH, Teller E. Adsorption of gases in multimolecular layers. J. Am. Chem. Soc. 1938;60:309-319. crossref(new window)

Horvath G, Kawazoe KJ. Method for the calculation of effective pore size distribution in molecular sieve carbon. J. Chem. Eng. Japan 1983;16:470-475. crossref(new window)

Barrett EP, Joyner LG, Halenda PP. The determination of pore volume and area distributions in porous substances. J. Am. Chem. Soc. 1951;73:373-380. crossref(new window)

Laszlo K, Tombacz E, Novak C. pH-dependent adsorption and desorption of phenol and aniline on basic activated carbon. Colloids Surf. A Physicochem. Eng. Asp. 2007;306:95-101. crossref(new window)

Kumar A, Kumar S, Kumar S, Gupta DV. Adsorption of phenol and 4-nitrophenol on granular activated carbon in basal salt medium: Equilibrium and kinetics. J. Hazard. Mater. 2007;147:155-166. crossref(new window)

Liu C, Tang Z, Chen Y, Su S, Jiang W. Characterization of mesoporous activated carbons prepared by pyrolysis of sewage sludge with pyrolusite. Bioresour. Technol. 2010;101:1097-1101. crossref(new window)

Andriantsiferana C, Julcour-Lebigue C, Creanga-Manole C, Delmas H, Wilhelm AM. Competitive Adsorption of p-Hydroxybenzoic Acid and Phenol on Activated Carbon: Experimental Study and Modeling. J. Environ. Eng. 2013;139: 402-409. crossref(new window)

Mohamed EF, Andriantsiferana C, Wilhelm AM, Delmas H. Competitive adsorption of phenolic compounds from aqueous solution using sludge based activated carbon. Environ. Technol. 2011;32:1325-1336. crossref(new window)

Cordero T, Duchamp C, Chovelon JM, Ferronato C, Matos J. Influence of L-type activated carbons on photocatalytic activity of $TiO_2$ in 4-chlorophenol photodegradation. J. Photochem. Photobiol. A Chem. 2007;191:122-131. crossref(new window)

Ahmed S, Rasul MG, Martens WN, Brown R, Hashib MA. Heterogeneous photocatalytic degradation of phenols in wastewater: a review on current status and developments. Desalination 2010;261:3-18. crossref(new window)

Grabowska E, Reszczynska J, Zaleska A. Mechanism of phenol photodegradation in the presence of pure and modified-$TiO_2$: A review. Water Res. 2012;46:5453-5471. crossref(new window)

Zhang X, Li A, Jiang Z, Zhang Q. Adsorption of dyes and phenol from water on resin adsorbents: effect of adsorbate size and pore size distribution. J. Hazard. Mater. 2006;137: 1115-1122. crossref(new window)

Santos A, Yustos P, Quintanilla A, Rodriguez S, Garcia-Ochoa F. Route of the catalytic oxidation of phenol in aqueous phase. Appl. Catal. B 2002;39:97-113. crossref(new window)

Muruganandham M, Swaminathan M. Photocatalytic decolourisation and degradation of Reactive Orange 4 by $TiO_2$-UV process. Dyes Pigm. 2006;68:133-142. crossref(new window)