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The Stabilizing Role of Cyclodextrins on Keggin Phosphotungstic Acid by Complexation Unveiled by Electrospray Mass Spectrometry
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  • Journal title : Mass Spectrometry Letters
  • Volume 6, Issue 1,  2015, pp.13-16
  • Publisher : Korean Society Mass Spectrometry
  • DOI : 10.5478/MSL.2015.6.1.13
 Title & Authors
The Stabilizing Role of Cyclodextrins on Keggin Phosphotungstic Acid by Complexation Unveiled by Electrospray Mass Spectrometry
Fan, YanXuan; Zhang, Yan; Jia, QiaoDi; Cao, Jie; Wu, WenJie;
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This study demonstrated the stabilizing role of a cyclodextrin on Keggin via hydrogen bonding complexation unveiled by ESI-MS. The distinctive fragmentation pathways of the -CD complexes from that of discrete showed that the so-called "weak" non-covalent interactions can effectively change the dissociation chemistry of POM in the gas phase. The influence of different types of solvents and organic additives such as -CD on the stability of Keggin was also addressed firstly by ESI-MS.
POM/CD non-covalent complexes;Electrospray ionization mass spectrometry;Stability;
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