Advanced SearchSearch Tips
Disproportionation/Dehydrocoupling of Endocrine Disruptor, Tributyltin Hydride to Polystannanes Using Cp2TiCl2/N-Selectride (Cp`
facebook(new window)  Pirnt(new window) E-mail(new window) Excel Download
  • Journal title : Journal of the Chosun Natural Science
  • Volume 6, Issue 1,  2013, pp.34-38
  • Publisher : The Research Institute of Chosun Natural Science
  • DOI : 10.13160/ricns.2013.6.1.034
 Title & Authors
Disproportionation/Dehydrocoupling of Endocrine Disruptor, Tributyltin Hydride to Polystannanes Using Cp2TiCl2/N-Selectride (Cp`
Park, Jaeyoung; Kim, Seongsim; Lee, Beomgi; Cheong, Hyeonsook; Lee, Ki Bok; Woo, Hee-Gweon;
  PDF(new window)
Tributyltin hydride (), an endocrine disruptor, was slowly polymerized by the group 4 -selectride (Cp`
Disproportionation;Dehydrocoupling;Polystannane;Titanocene;N-Selectride;Endocrine Disruptor;
 Cited by
J. E. Mark, H. R.Allock, and R.West, "Inorganic polymers", Prentice Hall, New Jersey, 1992.

H. R. Allcock and F. W. Lampe, "Contemporary polymer chemistry", 2nd ed.; Prentice-Hall, Singapore, 1992.

S. Yajima, M. Omori, J. Hayashi, K. Okamura, T. Matsuzawa, and C. Liaw, "Simple synthesis of continuous SiC fibre with high tensile strength", Chem. Lett., pp. 551-554, 1976.

P. A. Bianconi and T. W. Weidman, "Poly(N-hexylsilyne): synthesis and properties of the first alkyl silicon [RSI]„ network polymer", J. Am. Chem. Soc., Vol. 110, pp. 2342-2344, 1988. crossref(new window)

B. F. Griffing and R. Wet, "Contrast enhanced photoresists processing and modeling", Polym. Eng. Sci., Vol. 23, pp. 947-952, 1983. crossref(new window)

P. Trefonas III, J. R. Damewood Jr., R. West, and R. D. Miller, "Organosilane high polymers: thermochromic behavior in solution", Organometallics, Vol. 4, pp. 1318-1319, 1985. crossref(new window)

L. A. Harrah, and J. M. Zeigler, "Electronic spectra of polysilanes", Macromolecules, Vol. 20, pp. 601-608, 1987. crossref(new window)

K. Sakamoto, M. Yoshida, and H. Sakurai, "Highly ordered high-molecular weight alternating polysilylene copolymer prepared by anionic polymerization of masked disilene", Macromolecules, Vol. 23, pp. 4494-4496, 1990. crossref(new window)

C. Aitken, J. F. Harrod, and U. S. Gill, "Structural studies of oligosilanes produced by catalytic dehydrogenative coupling of primary organosilanes", Can. J. Chem., Vol. 65, pp. 1804-1809, 1987. crossref(new window)

J. F. Harrod and S. S. Yun, "Silyltitanocene complexes as catalysts for the hydrogenation, isomerization, and hydrosilylation of olefins", Organometallics, Vol. 6, pp. 1381-1387, 1987. crossref(new window)

C. Aitken, J.-P. Barry, F. Gauvin, J. F. Harrod, A. Malek, and D. Rousseau, "A survey of catalytic activity of. eta. 5-cyclopentadienyl complexes of Groups 4-6 and uranium and thorium for the dehydrocoupling of phenylsilane", Organometallics, Vol. 8, pp. 1732-1736, 1989. crossref(new window)

H.-G. Woo and T. D. Tilley, "$\sigma$-Bond metathesis reactions of Si-H and M-Si bonds. New routes to d0 metal silyl complexes", J. Am. Chem. Soc. Vol. 111, pp. 3757-3758, 1989. crossref(new window)

H.-G. Woo and T. D. Tilley, "Dehydrogenative polymerization of silanes to polysilanes by zirconocene and hafnocene catalysts. A new polymerization mechanism" J. Am. Chem. Soc., Vol. 111, pp. 8043-8044, 1989. crossref(new window)

H.-G. Woo, R. H. Heyn, and T. D. Tilley, "$\sigma$-Bond metathesis reactions for d0 metal-silicon bonds that produce zirconocene and hafnocene hydrosilyl complexes", J. Am. Chem. Soc., Vol. 114, pp. 5698-5707, 1992. crossref(new window)

H.-G. Woo, J. F. Walzer, and T. D. Tilley, "Dehydropolymerization of bis-and tris(silyl)arenes to highly crosslinked disilanylenearylene polymers, catalyzed by [($eta.5-C_5H_5$)($eta.5-C_5Me_5$) $ZrH_2]_2$", Macromolecules, Vol. 24, pp. 6863-6866, 1991. crossref(new window)

T. Imori, H.-G. Woo, J. F. Walzer, and T. D. Tilley, "Disilanylenearylene oligomers and polymers from dehydropolymerization of 1,4-RH2SiC6H4SiH2R (R= methyl, ethyl, and hexyl)" Chem. Mater., Vol. 12, pp. 1487-1492, 1993.

J. F. Harrod, "Transformations of organometallics into common and exotic materials; Design and activation", R. M. Laine, Ed., NATO ASI Series E : Appl. Sci. no. 141, Martinus Nijhoff Publishers, Amsterdam, pp. 103, 1988.

V. K. Dioumaev and J. F. Harrod, "Catalytic dehydrocoupling of phenylsilane with "cation-like" zirconocene derivatives: A new approach to longer silicon chains", Organometallics, Vol. 13, pp. 1548-1550, 1994. crossref(new window)

T. D. Tilley, "The coordination polymerization of silanes to polysilanes by a". sigma.-bond metathesis" mechanism. Implications for linear chain growth", Acc. Chem. Res., Vol. 26, pp. 22-29, 1993. crossref(new window)

T. Imori and T. D. Tilley, "The influence of catalyst structure on the dehydropolymerization of phenylsilane", Polyhedron, Vol. 13, pp. 2231-2243, 1994. crossref(new window)

H. G. Woo, S.-Y. Kim, M.-K. Han, E. J. Cho, and I. N. Jung, "Dehydrohomopolymerization and dehydrocopolymerization of new alkylsilanes: synthesis of poly (3-aryl-1-silabutanes)", Organometallics, Vol. 14, pp. 2415-2421, 1995. crossref(new window)

W. K. Zou and N.-L. Yang, "Experimental observation of the magnitude and sign of the third order optical nonlinearity in polydibutylstannane", Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.), Vol. 33, pp. 188-189, 1992.

L. R. Sita, "A new strategy for the synthesis of homologously pure linear polystannane oligomers", Organometallics, Vol. 11, pp. 1442-1444, 1992. crossref(new window)

T. Imori and T. D. Tilley, "High molecular mass polystannanes via dehydropolymerization of di(nbutyl) stannane", J. Chem. Soc., Chem. Commun., pp. 1607, 1993.

T. Imori, V. Lu, H. Cai, and T. D. Tilley, "Metal-catalyzed dehydropolymerization of secondary stannanes to high molecular weight polystannanes", J. Am. Chem. Soc., Vol. 117, pp. 9939, 1995.

H.-G. Woo, S.-Y. Kim, W.-G. Kim, E. J. Cho, S. H. Yeon, and I. N. Jung, "Dehydropolymerization of Bis (silyl) alkylbenzenes to Highly Cross-Linked Polysilanes, Catalyzed by Group 4 Metallocene Complex", Bull. Korean Chem. Soc., Vol. 16, pp. 1109-1112, 1995.

H.-G. Woo, S.-J. Song, H. You, E. J. Cho, and I. N. Jung, "Catalytic redistribution/ dehydrocoupling of 2-phenyl-1,3-disilapropane by $Cp_2MCl_2$/Red-Al system (M=Ti, Hf)", Bull. Korean Chem. Soc., Vol. 17, pp. 475-478, 1996.

T. Nakanishi, J.-I. Nishikawa, Y. Hiromori, H. Yokoyama, M. Koyanagi, S. Takasuga, J.-I. Ishizaki, M. Watanabe, S.-I. Isa, N. Utoguchi, N. Itoh, Y. Kohno, T. Nishihara, and K.Tanaka, "Trialkyltin compounds bind retinoid X receptor to alter human placental endocrine functions", Molecular Endocrinology 2005, Vol. 19, pp. 2502-2516. crossref(new window)

P. T. S. Wong, Y. K. Chau, O. Kramar, and G. A. Bengert, "Structure-toxicity relationship of tin compounds on algae", Canadian J. Fisheries and Aquatic Sci., Vol. 39, pp. 483-488, 1982. crossref(new window)

C. Boraiko, and J.Batt, "Evaluation of employee exposure to organic tin compounds used as stabilizers at PVC processing facilities", Tin Stabilizers Association Occup. Environ. Hyg., Vol. 2, pp. 73-76, 2005. crossref(new window)

H.-G. Woo, J.-M. Park, S.-J. Song, S.-Y.Yang, I.-S. Kim, and W.-G. Kim, "Catalytic Dehydropolymerization of Di-n-butylstannane n-Bu2SnH2 by Group 4 and 6 Transition Metal Complexes", Bull. Korean Chem. Soc., Vol. 18, pp. 1291-1295, 1997.

R. A. Benkeser, H. Landesman, and D. J. Foster, "The formation of arylsilylpotassium compounds", J. Am. Chem. Soc., Vol. 74, pp. 648-650, 1952.. crossref(new window)

A. K. Sawyer, "Some reactions of organotin hydrides with organotin oxides and alkoxides", J. Am. Chem. Soc., Vol. 87, pp. 537-539, 1965. crossref(new window)

B. Becher, R. J. P. Corriu, C. Guerin, and B. J. L. Henner, "Hypervalent silicon hydrides: evidence for their intermediacy in the exchange reactions of di-and tri-hydrogenosilanes catalysed by hydrides (NaH, KH and $LiAlH_4$)", J. Organomet. Chem., Vol. 369, pp. 147-154, 1989. crossref(new window)

B. Becker, R. Corriu, C. Guerin, and B. Henner, "Catalytic preparation of oligomeric polysilanes", Polym. Prep. (Am. Chem. Soc., Div. Polym. Chem.)., Vol. 56, pp. 854, 1987.

R. J. P. Corriu, "Hypervalent species of silicon: structure and reactivity", J. Organomet. Chem., Vol. 400, pp. 81-106, 1990. crossref(new window)

H.-G. Woo, S.-J. Song, E. J. Cho, and I. N. Jung, "Redistribution of bis-and tris(silyl)methanes catalyzed by Red-Al", Bull. Korean Chem. Soc., Vol. 17, pp. 123-124, 1996.

H.-G. Woo, Ph.D. Thesis University of California at San Diego, California, 1990.

C. Aitken, J. F. Harrod, A. Malek, and E. Samuel, "Oligomerization of phenylgermanes by catalytic dehydrocoupling", J. Organomet. Chem., Vol. 249, pp. 285-291, 1988.

J. E. Noh, H.-G. Woo, and H. Cheong, Manuscript in preparation.

D. P. Curran and C. T. Chang, "Atom transfer cyclization reactions of ${\alpha}$-iodo carbonyls", Tetrahedron Letts., Vol. 28, pp. 2477-2480, 1987. crossref(new window)

D. P. Curran and M.-H. Chen. "Atom transfer cycloaddition. A facile preparation of functionalized (methylene) cyclopentanes", J. Am. Chem. Soc., Vol. 109, pp. 6558-6560, 1987. crossref(new window)