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Pt@Cu/C Core-Shell Catalysts for Hydrogen Production Through Catalytic Dehydrogenation of Decalin
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 Title & Authors
Pt@Cu/C Core-Shell Catalysts for Hydrogen Production Through Catalytic Dehydrogenation of Decalin
Kang, Ji Yeon; Lee, Gihoon; Jeong, Yeojin; Na, Hyon Bin; Jung, Ji Chul;
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Pt@Cu/C core-shell catalysts were successfully prepared by impregnation of a carbon support with copper precursor, followed by transmetallation between platinum and copper. The Pt@Cu/C core-shell catalysts retained a core of copper with a platinum surface. The prepared catalysts were used for hydrogen production through catalytic dehydrogenation of decalin for eventual application to an onboard hydrogen supply system. Pt@Cu/C core-shell catalysts were more efficient at producing hydrogen via decalin dehydrogenation than Pt/C catalysts containing the same amount of platinum. Supported core-shell catalysts utilized platinum highly efficiently, and accordingly, are lower-cost than existing platinum catalysts. The combination of impregnation and transmetallation is a promising approach for preparation of Pt@Cu/C core-shell catalysts.
Pt@Cu/C core-shell;impregnation;transmetallation;hydrogen production;decalin dehydrogenation;
 Cited by
J. Houghton, Global Warming, Cambridge University press, Cambridge (1997).

S. M. Ibrahim, Korean J. Chem. Eng., 31, 1792 (2014). crossref(new window)

L. Barreto, A. Makihara and K. Riahi, Int. J. Hydrogen Energy, 28, 267 (2003). crossref(new window)

S. G. Chalk and J. F. Miller, J. Power Sources, 159, 73 (2006). crossref(new window)

S. Satyapal, J. Petrovic, C. Read, G. Thomas and G. Ordaz, Catal. Today, 120, 246 (2007). crossref(new window)

J. V. Pande, A. Shukla and R. B. Biniwale, Int. J. Hydrogen Energy, 37, 6756 (2012). crossref(new window)

W. -F. Chen, K. Sasaki, C. Ma, A. I. Frenkel, N. Marinkovic, J. T. Muckerman, T. Zhu and R. R. Adzic, Angew. Chem. Int. Ed., 51, 6131 (2012). crossref(new window)

R. B. Biniwale, S. Rayalu, S. Devotta and M. Ichikawa, Int. J. Hydrogen Energy, 33, 360 (2008). crossref(new window)

L. Schlapbach and A. Zuttel, Nature, 414, 353 (2001). crossref(new window)

V. Ananthachar and J. J. Duffy, Sol. Energ., 78, 687 (2005). crossref(new window)

G. Cacciola, N. Giordano and G. Restuccia, Int. J. Hydrogen Energy, 9, 411 (1984). crossref(new window)

A. A. Shukla, P. V. Gosavi, J. V. Pande, V. P. Kumar, K. V. R. Chary and R. B. Biniwale, Int. J. Hydrogen Energy, 35, 4020 (2010). crossref(new window)

M. P. Lazaro, E. Garcla-Bordeje, D. Sebastian, M. J. Lazaro and R. Moliner, Catal. Today, 138, 203 (2008). crossref(new window)

D. Sebastian, C. Alegre, L. Calvillo, M. Perez, R. Moliner and M. J. Lazaro, Int. J. Hydrogen Energy, 39, 4109 (2014). crossref(new window)

C. Zhang, X. Liang and S. Liu, Int. J. Hydrogen Energy, 36, 8902 (2011). crossref(new window)

R. B. Biniwale, N. Kariya and M. Ichikawa, Catal. Lett., 105, 83 (2005). crossref(new window)

S. Hodoshima, S. Takaiwa, A. Shono, K. Satoh and Y. Saito, Appl. Catal. A: Gen., 283, 235 (2005). crossref(new window)

S. Hodoshima, H. Arai, S. Takaiwa and Y. Saito, Int. J. Hydrogen Energy, 28, 1255 (2003). crossref(new window)

A. Shukla, S. Karmakar and R. B. Biniwale, Int. J. Hydrogen Energy, 37, 3719 (2012). crossref(new window)

J. K. Ali, E. J. Newson and D. W. T. Rippin, Chem. Eng. Sci., 49, 2129 (1994). crossref(new window)

C. Shinohara, S. Kawakami, T. Moriga, H. Hayashi, S. Hodoshima, Y. Saito and S. Sugiyama, Appl. Catal. A: Gen., 266, 251 (2004). crossref(new window)

Y. Saito, K. Aramaki, S. Hodoshima, M. Saito, A. Shono, J. Kuwano and K. Otake, Chem. Eng. Sci., 63, 4935 (2008). crossref(new window)

D. Jian-ping, S. Chang, S. Jin-ling, Z. Jiang-hong and Z. Zhen-ping, J. Fuel Chem. Techno., 37, 468 (2009). crossref(new window)

M. Neergat and R. Rahul, J. Electrochem. Soc., 159, 234 (2012). crossref(new window)

A. Sarkar and A. Manthiram, J. Phys. Chem. C, 114, 4725 (2010).

G. Lee, Y. Jeong, B.-G. Kim, J. S. Han, H. Jeong, H. B. Na and J. C. Jung, Catal. Communs., 67, 40 (2015). crossref(new window)

G. Lee, J. Y. Kang, Y. Jeong and J. C. Jung, Korean J. Mater. Res., 25, 191 (2015). crossref(new window)