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Synthesis of CO2 Adsorbent with Various Aminosilanes and its CO2 Adsorption Behavior
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  • Journal title : Applied Chemistry for Engineering
  • Volume 27, Issue 1,  2016, pp.80-85
  • Publisher : The Korean Society of Industrial and Engineering Chemistry
  • DOI : 10.14478/ace.2015.1128
 Title & Authors
Synthesis of CO2 Adsorbent with Various Aminosilanes and its CO2 Adsorption Behavior
Jeon, Jae Wan; Ko, Young Soo;
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The carbon dioxide adsorption behavior of silica with a large specific surface area and pore volume functionalized with aminosilane compounds via in-situ polymerization and functionalization method were investigated. The organosilanes include amino functional group capable of adsorbing carbon dioxide. Elemental analyzer, in situ FT-IR and thermogravimetric analyzer were used to characterize the sorbents and to determine their adsorption behavior. Comparison of different aminosilane loading in the support revealed that polyaminosilane functionalization of 70% of the pore volume in the support was better in terms of the adsorption capacity and amine efficiency than that of 100% of the pore volume of the support. Furthermore, the sorbents showed a higher adsorption capacity at an adsorption temperature of than at due to the thermal expansion of synthesized polyaminosilanes inside the pore of silica. The N-[3-(trimethoxysilyl)propyl]ethylenediamine (2NS) sorbent with 70% of the pore volume functionalized showed the highest adsorption capacity of 9.2 wt% at .
capture;sorbent;silica;aminosilane;in-situ polymerization;
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