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Application of Silica-supported Ionic Liquid Catalysts to Cycloaddition of CO2
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  • Journal title : Applied Chemistry for Engineering
  • Volume 27, Issue 3,  2016, pp.239-244
  • Publisher : The Korean Society of Industrial and Engineering Chemistry
  • DOI : 10.14478/ace.2016.1031
 Title & Authors
Application of Silica-supported Ionic Liquid Catalysts to Cycloaddition of CO2
Kim, Dong-Woo; Kim, Hyeon-Gook; Cho, Deug-Hee;
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The catalytic applicability of various ionic liquids immobilized on different silica-supports such as amorphous, SBA, MCM and commercial silica for the cycloaddition of and epoxides is reviewed in this work. The effects of different structures of supported ionic liquids and silica supports in the synthesis cyclic carbonate by the cycloaddition of have been remarked. The studies revealed that ionic liquids possessing functional groups or metals exhibited increased catalytic performance towards cyclic carbonate synthesis. Moreover, the reusability of SSIL catalyst and mechanism for the cycloaddition of were studied.
carbon dioxide;cycloaddition;ionic liquid;immobilization;silica;
 Cited by
D. G. Gavin and C. J. Bower, Options for reducing greenhouse gases in the global environment, Proc. of the JAPAN-EC, Japan (1991).

S. Inoue, T. Tsuruta, and H. Koinuma, Copolymerzation of carbon dioxide and epoxide, J. Polym. Sci. Polym. Lett., 7(4), 287-292 (1969). crossref(new window)

S. Inoue and N. Yamazaki, Organic and Bioorganic Chemistry of Carbon Dioxide, Kodansha Ltd., Tokyo (1981).

S. H. Cho, B. C. Bai, H. R. Yu, and Y. S. Lee, Carbon capture and $CO_2/CH_4$ separation technique using porous carbon materials, Appl. Chem. Eng., 22(5), 343-347 (2011).

U. Romano, Dimethyl carbonate and its production technology, Chim. Ind., 75, 303-306 (1993).

A. A. G. Shaikh and S. Sivaram, Organic carbonates, Chem. Rev., 96(3), 951-976 (1996). crossref(new window)

K. Weissermel and H. J. Arpe, Industral Organic Chemestry, 3rd ed., Wiley-VCH, New York (1997).

C. E. Song, W. H. Shim, E. J. Roh, and J. H. Choi, Scandium (III) triflate immobilized in ionic liquids: A novel and recyclable catalytic system for Friedel-Crafts alkylation of aromatic compounds with alkenes, Chem. Commun., 17, 1695-1696 (2000).

D. W. Kim, R. Roshan, J. Tharun, K. A. Cherian, and D. W. Park, Catalytic applications of immobilized ionic liquids for synthesis of cyclic carbonates from carbon dioxide and epoxides, Korean J. Chem. Eng., 30(11), 1973-1984 (2013). crossref(new window)

L. Han, S. W. Park, and D. W. Park, Silica grafted imidazolium-based ionic liquids: efficient heterogeneous catalysts for chemical fixation of $CO_{2}$ to a cyclic carbonate, Energy Environ. Sci., 2, 1286-1292 (2009). crossref(new window)

L. Han, H. J. Choi, S. J. Choi, B. Liub, and D. W. Park, Ionic liquids containing carboxyl acid moieties grafted onto silica: Synthesis and application as heterogeneous catalysts for cycloaddition reactions of epoxide and carbon dioxide, Green Chem., 13, 1023-1028 (2011). crossref(new window)

L. Han, M. S. Park, S. J. Choi, Y. J. Kim, S. M. Lee, and D. W. Park, Incorporation of metal ions into silica-grafted imidazolium-based ionic liquids to efficiently catalyze cycloaddition reactions of $CO_{2}$ and epoxides, Catal. Lett., 142, 259-266 (2012). crossref(new window)

J. Q. Wang, D. L. Kong, J. Y. Chen, F. Cai, and L. N. He, Synthesis of cyclic carbonates from epoxides and carbon dioxide over silica-supported quaternary ammonium salts under supercritical conditions, J. Mol. Catal. A: Chem., 249, 143-148 (2006). crossref(new window)

J. Q. Wang, X. D. Yue, F. Cai, and L. N. He, Solventless synthesis of cyclic carbonates from carbon dioxide and epoxides catalyzed by silica-supported ionic liquids under supercritical conditions, Catal. Commun., 8, 167-172 (2007). crossref(new window)

Y. Kishimoto and I. Ogawa, Amine-catalyzed, one-pot coproduction of dialkyl carbonates and 1,2-Diols from epoxides, alcohols, and carbon dioxide, Ind. Eng. Chem. Res., 43, 8155- 8162 (2004). crossref(new window)

J. W. Huang and M. Shi, Chemical fixation of carbon dioxide by $NaI/PPh_{3}/PhOH$, J. Org. Chem., 68, 6705-6709 (2003). crossref(new window)

H. Kawanami, A. Sasaki, K. Matsui, and Y. Ikushima, A rapid and effective synthesis of propylene carbonate using a supercritical $CO_{2}$-ionic liquid system, Chem. Commun., 7, 896-897 (2003).

S. Udayakumar, S. W. Park, D. W. Park, and B. S. Choi, Immobilization of ionic liquid on hybrid MCM-41 system for the chemical fixation of carbon dioxide on cyclic carbonate, Catal. Commun., 9, 1563-1570 (2008). crossref(new window)

S. Udayakumar, M. K. Lee, H. L. Shim, S. W. Park, and D. W. Park, Imidazolium derivatives functionalized MCM-41 for catalytic conversion of carbon dioxide to cyclic carbonate, Catal. Commun., 10, 659-664 (2009). crossref(new window)

S. Udayakumar, V. Raman, H. L. Shim, and D. W. Park, Cycloaddition of carbon dioxide for commercially-imperative cyclic carbonates using ionic liquid-functionalized porous amorphous silica, Appl. Catal. A: Gen., 368, 97-104 (2009). crossref(new window)

M. M. Dharman, H. J. Choi, D. W. Kim, and D. W. Park, Synthesis of cyclic carbonate through microwave irradiation using silica-supported ionic liquids: Effect of variation in the silica support, Catal. Today, 164, 544-547 (2011). crossref(new window)