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Analysis of Multiple Pesticide Residues in Apples and Pears Using Gas-Liquid Chromatography
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 Title & Authors
Analysis of Multiple Pesticide Residues in Apples and Pears Using Gas-Liquid Chromatography
Park, Ju-Hwang; Kim, Taek-Kyum; Oh, Chang-Hwan; Kim, Jeong-Han; Lee, Young-Deuk; Kim, Jang-Eok;
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 Abstract
A rapid analytical method was developed to determine multiple pesticide residues in apples and pears using gas-liquid chromatography (GLC). The samples were extracted with water-miscible solvents and purified by cleanup procedures serially comprising liquid-liquid partition and solid-phase extraction (SPE). Each analyte was separated and determined by a high-resolution GLC equipped with electron-capture detector (ECD) and nitrogen-phosphorous detector (NPD). A total of 196 pesticides, which were previously classified into 5 groups each for ECD and NPD based on their retention behaviors on the capillary column and responses to the detector, were subjected to the recovery experiment. In compliance with the analytical criteria, 70 to 120% of recovery and less than 20% relative standard deviation the proposed method could be successfully applied to analyze 136 and 133 pesticide residues in apples and pears, respectively, which enabled not only rapid screening but quantitation of the residues. Even though less reliability was resulted from unacceptable recovery range, rest of pesticides including 43 and 45 analyzes in apples and pears, could be also detected for their identity. The proposed method fliled to cover 17 and 18 pesticides for apples and pears, which mostly showed high polarity or heat-lability but could be suitable far fast surveilance or monitoring of fruit harvests.
 Keywords
multiple pesticide residues;solid-phase extraction (SPE);apple;pear;GLC analysis;
 Language
Korean
 Cited by
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4.
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1.
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2.
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 References
1.
식품의약품안전청 (1999) 식품공전 P.37-106

2.
식품의약품안전청 (1999) 식품공전 별책 제 7. 일반시험법,P.110-256

3.
殘留農藥基準便覽 (1994) 日本食品衛生協會 173pp

4.
C, Patricia (1995) Official metthods of analysis AOAC international, Pesticide and industrial chemical residues, 16th ed., Chapter 10, USA

5.
Mcmahon, B. M. (1994) Pesticide Analytical Manual Volume I : Multiresidue Methods, 3rd ed., FDA. USA

6.
Pang, G. F., Cao, Y. J. and Fan, C. L. (1995) Modification of AOAC multiresidue method for determining synthetic pyrethroid residues in fruits, vegetables and grains, Part I : Acetonitrile extraction system and optimization of Florisil cleanup and chromatography, J.AOAC International 78(6), 1481-1488

7.
Zoonen, P. V. and Rijksinstituut, V. (1996) Analytical methods for pesticide residues in foodstuffs, 6th ed., Ministryof Public Health, Welfare and Sport, Netherlands

8.
Kim, T. J., Eo, Y. W. and Kim, Y. S. (1987) A Study on the Separation and Determination of Organochlorine Pesticides by Capillary Column Gas-liquid Chromatography, J. Korean Chem. Soc. 31(5), 425-433

9.
김택제, 어연우(1990) 다성분 잔류농약 동시 분석법에 관한 연구(3차), KIAT 연구보고서

10.
Kim, W. S., Lee, B. H. and Park, H, J. (1996) Study on the Development of Simultaneous Analytical Method for the Residual Organic Chloride Pesticides by Gas Chromatography, J. Korean Environ Sci. 5(5), 561-567

11.
Niessner, G, Buchberger, W. and Eckerstorfer, R. (1999)Multiresidue screening methods for fhe determination ofpesticides in plant materials, J. Chromatogr. A 846, 341-348 crossref(new window)

12.
Serrano, R, Lopez, F. J. and Hemandez, F. (1999) Multiresidue determination of persistent organochlorine and organophosphorus compounds in whale tissues using automated liquid chromatographic clean up and gas chromatographic-mass spectrometric detection, J. Chromatogr. A 855, 633-643 crossref(new window)

13.
Colume, A., Cardenas, S., Gallego, M. and Valcairel, M.(2001) Semiautomatic multiresidue gas chromatographic method for the screening of vegetables for 25 organochlorine and pyrethroid pesticides, Anal. Chem. Acta 436,153-162 crossref(new window)

14.
Castro,J., Sanchez-Brunete, C. and Tadeo, J. L. (2001) Multiresidue analysis of insecticides in soil by gas chromatography with electron-capture detection and confirmation by gas chromatography-mass spectrometry, J.Chromatogr. A 918, 371-380 crossref(new window)

15.
Ho, W. H. and Hsieh, S. J. (2001) Solid phase microextraction associated with microwave assited extraction of organochlorine pesticides in medicinal plants, Anatytica Chimica Acta 428, 111-120 crossref(new window)

16.
Ahmed, F. E. (2001) Analyses of pesticides and their metabolites in foods and drinks, Trends in anal. chem.20(11), 649-661 crossref(new window)

17.
Valverde, A., Aguilera, A., Rodriguez, M. and Boulaid, M. (2001) What are we determining using gas chromatographic multiresidue methods: tralomethrin or deltamethrin?, J. Chromatogr. A 943, 101-111 crossref(new window)

18.
Lacassie, E., Marquet, P, Gaulier, J. M., Dreyfuss, M. F.and Lachahre, G. (2001) Sensitive and specific multiresidue methods for the determination of pesticides ofvarious classes in clinical and forensic toxicology, Forensic Sci. Int'l 121, 116-125 crossref(new window)

19.
Lehotay, S. J. (1997) SupercnticaI fluid extraction ot pesticide in foods, J. Chromatogr. A 785, 289-312 crossref(new window)

20.
Sabic, H., Jeannot, R., Roudeau, B. (2000) Muldresidue methods using solid-phase extraction techniques for monitoring priority pesticides, including triazines and degradation products, in ground and surface waters, J. Chromatogr. A 885, 217-236 crossref(new window)