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Availability of Heavy Metals in Soils with Different Characteristics and Controversial Points for Analytical Methods of Soil Contamination in Korea
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 Title & Authors
Availability of Heavy Metals in Soils with Different Characteristics and Controversial Points for Analytical Methods of Soil Contamination in Korea
Jung, Goo-Bok; Kim, Won-Il; Lee, Jong-Sik; Shin, Joung-Du; Kim, Jin-Ho; Yun, Sun-Gang;
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 Abstract
This experiment was conducted to investigate available extraction capacity and potential mobility of heavy metal according to the distribution property and contamination level of heavy metals in soils and to suggest a reform measure of soil environment assessment methodology applied with soil quality and the official soil heavy metal test methods in domestic and foreign countries. The soils were collected from the natural forest paddy with long-term application of same type fertilizer, and paddies near metal mine and industrial complex. The post-treatment methods of soil were partial extraction, acid digestion and sequential extraction methods. For the heavy metal contents with different soil properties, it was shown that their natural forest and paddy soil were slightly low and similar to the general paddy soil, while their paddies near metal mine and industrial complex were higher than the standard level of Soil Environment Protection Act. Heavy metal concentrations in the soils with different soil properties had difference between extractant by US-EPA 3051a method. There were highly significant positive relationships in both two methods. It was appeared that the higher extractable concentration ratio with 0.1N-HCl to total heavy metal content with extractant the greater total heavy metal content. There were highly significant positive correlationship between total heavy metal content and extractable content with 0.1N-HCl. For extractable capacity of soil extractable solution compared to the total heavy metal content it was appeared that it extractable method with 0.1N-HCl was higher than those with EDTA and DTPA. In extractable ratio with 0.1N-HCl in the contaminated paddy soils near mine and industrial complex, it was shown that the lower soil pH, the higher total heavy metal content. The order of a potential mobility coefficient by distribution of heavy metal content with ie different typies in the soil was Cd>Ni>Zn>Cu>Pb. It could be known that contamination characteristics of heavy metals with different types of soils were affected by different heavy metal components, contamination degree and soil chemical properties, and heavy metal concentration with different extractable methods had great variations with adjacent environment. To be compared with assessment methodology of soil environment impact at domestic and foreign countries with our results, it might be considered that there was necessary to make a single analysis method based on total heavy metal content with environmental overloading concept because of various analysis methods for total heavy metal content and present analysis method with great variation according to soil environment. In spite of showing higher concentration of heavy metal with acidic digestion than the extractable method, it might be considered that there is need to be adjusted the national standard of soil heavy metal contamination.
 Keywords
Soil;Heavy metal;Analytical method;Availability;Soil standard;Sequential extraction;
 Language
Korean
 Cited by
1.
우리나라 토양의 중금속 자연배경농도 평가,윤정기;김동호;김태승;박종겸;정일록;김종하;김혁;

한국지하수토양환경학회지:지하수토양환경, 2009. vol.14. 3, pp.32-39
2.
우리나라 농경지 중금속 동태 및 작물흡수 연구동향,이지호;김지영;고우리;정은정;;정구복;김두호;김원일;

한국환경농학회지, 2012. vol.31. 1, pp.75-95 crossref(new window)
3.
중금속 오염 농경지에 처리된 안정화제의 적용에 따른 토양 내 생물유효도 변화,오세진;김성철;김록영;옥용식;윤현수;오승민;이진수;양재의;

한국토양비료학회지, 2012. vol.45. 6, pp.973-982 crossref(new window)
4.
Comparing Bioavailability of Cadmium and Arsenic in Agricultural Soil Under Varied pH Condition,;;;;;;;

한국토양비료학회지, 2015. vol.48. 1, pp.57-63 crossref(new window)
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Change of Bioavailability in Heavy Metal Contaminated Soil by Chemical Amendment, Korean Journal of Soil Science and Fertilizer, 2012, 45, 6, 973  crossref(new windwow)
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Current research trends for heavy metals of agricultural soils and crop uptake in Korea, Korean Journal of Environmental Agriculture, 2012, 31, 1, 75  crossref(new windwow)
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Comparing Bioavailability of Cadmium and Arsenic in Agricultural Soil Under Varied pH Condition, Korean Journal of Soil Science and Fertilizer, 2015, 48, 1, 57  crossref(new windwow)
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