Advanced SearchSearch Tips
Application of Multiresidue Analysis Method of Unregistered Pesticides in Korea for Imported Food
facebook(new window)  Pirnt(new window) E-mail(new window) Excel Download
 Title & Authors
Application of Multiresidue Analysis Method of Unregistered Pesticides in Korea for Imported Food
Jeon, Young-Hwan; Kim, Hyo-Young; Hwang, Jeong-In; Kim, Ji-Hwan; Do, Jung-Ah; Im, Moo-Hyeog; Oh, Jae-Ho; Kwon, Ki-Sung; Lee, Joong-Keun; Lee, Young-Deuk; Kim, Jang-Eok;
  PDF(new window)
BACKGROUND: Recently in Korea, the import of agricultural products is rising due to the increasing amount of trade. Unregistered pesticides, allidochlor, propachlor, propham, cycloate, diallate and pebulate are widely used as pesticides for rice cultivation in foreign countries, while they are not registered in Korea. Therefore, the residue amount of imported agri-foods should be verified using the proper official analytical method for each of them that has not registered in Korea. METHODS AND RESULTS: This work was conducted to apply the official method of Korea Food & Drug Administration (KFDA) for determining multi class pesticide multiresidues in agricultural commodities. Brown rice and orange which have different characteristics as a matrix were selected as representative samples for residue analysis. The recoveries of cycloate, diallate and pebulate by GC/MS in fortified brown rice and orange with levels of 0.04~0.4 mg/kg were ranged from 82.8% to 110.3%. The quantification limits of three pesticides in brown rice and orange were 0.04 mg/kg. CONCLUSION: As a result, this method can surely be used as an official method for routine analysis of unregistered pesticides in Korea for imported agri-food.
 Cited by
국내 미등록 유기인계 농약의 수입 농식품에 대한 다성분 잔류분석법,전영환;황정인;안지운;김효영;도정아;오재호;황인균;임무혁;이중근;이영득;김장억;

한국환경농학회지, 2012. vol.31. 3, pp.277-285 crossref(new window)
수입 Valencia 오렌지의 크기와 품질특성의 상관성,조덕조;유승열;박주현;까오야핑;김슬기;이제영;권은진;권중호;

한국식품저장유통학회지, 2014. vol.21. 3, pp.365-372 crossref(new window)
가스 크로마토그래피를 이용한 수입농산물 중 국내 미등록 농약의 다성분 동시분석법 적용,이지원;강정균;권혜영;노진호;진용덕;이제봉;홍수명;김택겸;조남준;

농약과학회지, 2015. vol.19. 3, pp.161-173 crossref(new window)
Relationship between the fruit size and the quality properties of imported Valencia oranges, Korean Journal of Food Preservation, 2014, 21, 3, 365  crossref(new windwow)
Multiresidue Analysis Method for Determination of Unregistered Organophosphorus Pesticides in Korea for Imported Agri-Food, Korean Journal of Environmental Agriculture, 2012, 31, 3, 277  crossref(new windwow)
Gas Chromatographic Method for Multiresidue Analysis of Unregistered Pesticides in Imported Agricultural Commodities, The Korean Journal of Pesticide Science, 2015, 19, 3, 161  crossref(new windwow)
Borras, E., Sanchez, P., Munoz, A., Tortajada-Genaro L.A., 2011. Development of a gas chromatography-mass spectrometry method for the determination of pesticides in gaseous and particulate phases in the atmosphere, Analytica. Chimica. Acta. 699, 57-65. crossref(new window)

Breen, J.L., 2007. International trade implications of pesticide residues in food, Korena J. Pesti. Sci. 58-64.

Delgado, M.J.S., Barroso, S.R., Fernandez-Tostado, G.T., Polo-Diez, M.J., 2001. Stability studies of carbamate pesticides and analysis by gas chromatography with flame ionization and nitrogen-phosphorus detection, J. Chromatogr. A. 921, 287-296. crossref(new window)

Dugay, J., Miege, C., Hennion, M.C., 1998. Effect of the various parameters governing solid-phase microextraction for the trace-determination of pesticides in water, J. Chromatogr. A. 795, 27-42. crossref(new window)

Gilreath, J.P., Santos, B.M., 2004. Herbicide dose and incorporation depth in combination with 1,3-dichloropropene plus chloropicrin for Cyperus rotundus control in tomato and pepper, Crop Prot. 23, 205-210. crossref(new window)

Hirahara, Y., Kimura, M., Inoue, T., Uchikawa, S., Otani, S., Hirose, H., Suzuki, S., Uchida, Y., 2006. Screening method for the determination of 199 pesticides in agricultural products by gas chromatography/ion trap mass spectrometry (GC/MS/MS), Food Hyg. Saf. Sci. 47, 213-221. crossref(new window)

Konstantinou, I.K., Sakkas, V.A., Albanis, T.A., 2002. Photocatalytic degradation of propachlor in aqueous $TiO_{2}$ suspensions. Determination of the reaction pathway and identification of intermediate products by various analytical methods, Water Res. 36, 2733-2742. crossref(new window)

Lambropoulou, D.A., Konstantinou, I.K., Albanis, T.A., 2000. Determination of Herbicides in Natural Waters Using Solid Phase Microextraction (SPME) and Gas Chromatography Coupled with Flame Thermionic and Mass Spectrometric Detection, Intern. J. Environ. Anal. Chem. 78, 223-240. crossref(new window)

Lanyi, K., Dinya, Z., 2005. Photodegradation study for assessing the environmental fate of some triazine-, urea-and thiolcarbamate-type herbicides, Microchem. J. 80, 79-87. crossref(new window)

Lee, E.M., Lee, H.R., Riu, M.J., Park, H.W., Na, Y.R., Song, H.H., Keum, Y.S., Zhu, Y., Kim, J.H., 2009. Establishment of analytical method of prochloraz in cabbage, apple, mandarin, pepper and hulled rice with GC-ECD, Korean J. Environ. Agri. 28, 427-434. crossref(new window)

Lehotay, S.J., Kok, A., Hiemstra, M., Bodegraven, P., 2005. Validation of a fast and easy method for the determination of residues from 229 pesticides in fruits and vegetables using gas and liquid chromatography and mass spectrometric detection, J. AOAC Int. 88, 595-614.

Magnucka, E.G., Suzuki, Y., Pietr, S.J., Kozubek, A., Zarnowski, R., 2009. Cycloate, an inhibitor of fatty acid elongase, modulates the metabolism of verylong- side-chain alkylresorcinols in rye seedlings, Pest Manag. Sci. 65, 1065-1070. crossref(new window)

Mayer-Helm, B., Hofbauer, L., Müller J., 2006. Development of a multi-residue method for the determination of 18 carbamates in tobacco by highperformance liquid chromatography/positive electrospray ionisation tandem mass spectrometry, Rapid Commun. Mass Spectrom. 20, 529-536. crossref(new window)

Nakamura, M., Noda, S., Kosugi, M., Ishiduka, N., Mizukoshi, K., Taniguchi, M., Nemoto, S., 2010. Determination of dithiocarbamates and milneb residues in foods by gas chromatography-mass spectrometry, Food Hyg. Saf. Sci. 51, 213-219. crossref(new window)

Orejuela, E., Silva, M., 2004. Determination of Propham and Chlorpropham in Postharvest-Treated Potatoes by Liquid Chromatography with Peroxyoxalate Chemiluminescence Detection, Analytical Letters. 37, 2531-2543. crossref(new window)

Park, J.H., Kim, T.K., Oh, C.H., Kim, J.H., Lee, Y.D., Kim, J.E., 2004. Analysis of multiple pesticide residues in apples and pears using Gas-Liquid chromatography, Korean J. Environ. Agri. 23, 148-157. crossref(new window)

Park, S.H., 2008. Safety management system of GM food, Food Sci. Indust. 41, 5-15.

Pous, X., Ruíz, M.J., PicO, Y., Font, G., 2001. Determination of imidacloprid, metalaxyl, myclobutanil, propham, and thiabendazole in fruits and vegetables by liquid chromatography-atmospheric pressure chemical ionization-mass spectrometry, Fresenius J. Anal. Chem. 371, 182-189. crossref(new window)

Tomlin, C.D.S., 2006. The Pesticide Manual (14th), pp. 232-233, 800-801, 870-871, 881-882, 1109, 1129.

Yang, X., Zhang, H., Liu, Y., Wang, J., Zhang, Y.C., Dong, A.J., Zhao, H.T., Sun, C.H., Cui, J., 2011. Multiresidue method for determination of 88 pesticides in berry fruits using solid-phase extraction and gas chromatography-mass spectrometry: Determination of 88 pesticides in berries using SPE and GC-MS, Food Chem. 127, 855-865. crossref(new window)

Zhao, Y.G., Shen, H.Y., Shi, J.W., Chen, X.H., Jin, M.C., 2011. Preparation and characterization of amino functionalized nano-composite material and its application for multi-residue analysis of pesticides in cabbage by gas chromatography-.triple quadrupole mass spectrometry, J. Chromatogr. A. 1218, 5568-5580. crossref(new window)