JOURNAL BROWSE
Search
Advanced SearchSearch Tips
Preparation and Characterization of KOH-Activated Carbons Developed from Petroleum Coke
facebook(new window)  Pirnt(new window) E-mail(new window) Excel Download
  • Journal title : Carbon letters
  • Volume 10, Issue 4,  2009, pp.293-299
  • Publisher : Korean Carbon Society
  • DOI : 10.5714/CL.2009.10.4.293
 Title & Authors
Preparation and Characterization of KOH-Activated Carbons Developed from Petroleum Coke
Sayed Ahmed, S.A.; Abo El-Enin, Reham M.M.; El-Nabarawy, Th.;
  PDF(new window)
 Abstract
Potassium hydroxide activated carbons were prepared from Egyptian petroleum cokes with different KOH/coke ratios and at different activation temperatures and times. The textural properties were determined by adsorption of nitrogen at . The adsorption of iodine and methylene blue was also investigated at . The surface area and the non-micropore volume increased whereas the micropore volume decreased with the increase of the ratio KOH/coke. Also the surface area and porosity increased with the rise of activation temperature from 500 to . Textural parameter considerably increased with the increase of activation time from 1 to 3 h. Further increasing of activation time from 3 to 4 h was associated with a less pronounced increase in textural parameters. The adsorption of iodine shows the same trend of surface area and porosity change exhibited by nitrogen adsorption, with KOH/coke ratio and temperature of activation. Adsorption of methylene blue follows pseudo-first-order kinetics and its equilibrium adsorption follows Langmuir and D-R models.
 Keywords
KOH/coke;Preparation;Characterization;Nitrogen;Methylene blue;Iodine adsorption;
 Language
English
 Cited by
1.
Adsorption properties of activated carbon prepared from pre-carbonized petroleum coke in the removal of organic pollutants from aqueous solution,;;;

Carbon letters, 2011. vol.12. 3, pp.152-161 crossref(new window)
2.
Influence of Amine Grafting on Carbon Dioxide Adsorption Behaviors of Activated Carbons,;;

Bulletin of the Korean Chemical Society, 2011. vol.32. 9, pp.3377-3381 crossref(new window)
 References
1.
Mingho, W.; Qingfang, Z.; Jieshan, Q.; Xia H.; Yansheng G.; Zhaofeng, L.; Aijun, Y.; Xin S. Fuel 2005, 84, 1992. crossref(new window)

2.
Si Hyun, L.; Cheong Song, C. Fuel Process. Technol. 2000, 64, 141. crossref(new window)

3.
Takayuki, K.; Mitsuchiro, K.; Maurice, S.; Onyango, F. W.; Hitoki M. Appl. Therm. Eng. 2008, 28, 865. crossref(new window)

4.
Tseng, R. L.; Tseng, S. K. J. Colloid Interface Sci. 2005, 287, 428. crossref(new window)

5.
Stavropoulas, G. G.; Zabaniotou, A. A. Micropor Mesopor. Mater. 2005, 82, 79. crossref(new window)

6.
Lillo-Rodenas, M. A.; Cazorla-Amoros, D.; Linares-Solano, A. Carbon 2003, 41, 267. crossref(new window)

7.
Matani, S.; Lee, S. I.; Saito, K.; Yoon, S. H.; Korai, Y.; Mochida, I. Carbon 2005, 43, 2295. crossref(new window)

8.
Ahmadpour, A.; Do, D. D. Carbon 1996, 34, 471. crossref(new window)

9.
Ehrburger, P.; Addoun, A.; Addoun, F.; Ddonnet, J. B. Fuel 1986, 65, 1447. crossref(new window)

10.
Lozono-Castello, D.; Lillo-Rodenas, M. A.; Cazorla-Amoros, D.; Linares-Rodenas, A. Carbon 2001, 39, 741. crossref(new window)

11.
Yong, Z.; Bu-xing, H. Adsorp. Sci.; Technol. 2001, 19, 59. crossref(new window)

12.
Mohammad, A.; Muhammed, A. R.; Mohammad, A. M.; Mohammad, B. S. Adsorp. Sci. & Techol. 2006, 24, 761. crossref(new window)

13.
Puziy, A. M.; Poddubnaya, O. I.; Martinez-Alonso, A.; Suarez-Garcia, F.; Tascon, J. M. D. Carbon 2003, 41, 1181. crossref(new window)

14.
Hayashi, J.; Uclubayashi, M.; Harikawa, T.; Muroyama, K.; Gomes, V. G. Carbon 2002, 40, 2747. crossref(new window)

15.
Derpyshire, F.; Jagtoyen, M.; Thwaites, M. "Activated Carbons-Production; Application", in "Porosity in Carbon", ed. J. W. Patrick, E. Amold, London, 1995, 228.

16.
Lua, A. C.; Yang, T.; Guo, J. J. Anal. Appl. Pyrolysis 2004, 72, 279. crossref(new window)

17.
Phan, N. H.; Rio-S., F. C.; Le Cloirec, P.; Nguyen, T. H. Carbon 2006, 44, 2569. crossref(new window)

18.
Tseng, R. L. J. Hazardous Materials 2007, 147, 1020. crossref(new window)

19.
Fawzi, B.; Sameer, A.-A.; Leema, M. Adsorp. Sci. & Technol 2003, 21, 597. crossref(new window)

20.
Brunauer, S.; Deming, D. W.; Deming, L. S.; Teller, E. J. Am. Chem. Soc. 1940, 62, 1723. crossref(new window)

21.
Sing, K. S. W. Chem. Ind. London, 1968, 1520.

22.
Huiping, Z.; Ying Y.; Lichun Y. Adsop. Sci. & Technol. 2008, 26, 533. crossref(new window)

23.
Azeuedo Diana, C. S.; Araiyo, J. C. S.; Moises, B.-N; Torres, B.; Jaguaribe, F.; Cavalante, L. Microp or Mesopor 2007, 100, 361. crossref(new window)

24.
Park, S.-J.; Jung, W.-Y.; J. Colloid. Interf. Sci. 2002, 250, 93. crossref(new window)

25.
Sing, K. S. W.; Everett, D. H.; Haul, R. A. W.; Moscou, L.; Pierotti, R. A.; Rouquerol, J.; Siemieniewska, T. Pure Appl. Chem. 1985, 57, 603. crossref(new window)

26.
Dubinin, M. M.; Radushkevich, L. V. Proc. Acad. Sci. USSR, Phys. Cem. Sect. 1947, 55, 331.

27.
Youssef, A. M.; El-Nabarawy, Th.; Samra, S. E. Colloids and Surfaces. A: Physicochem. Eng.: Aspects 2004, 235, 153. crossref(new window)