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Equilibrium, kinetic and thermodynamic studies of the adsorption of acidic dye onto bagasse fly ash
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  • Journal title : Carbon letters
  • Volume 12, Issue 3,  2011, pp.143-151
  • Publisher : Korean Carbon Society
  • DOI : 10.5714/CL.2011.12.3.143
 Title & Authors
Equilibrium, kinetic and thermodynamic studies of the adsorption of acidic dye onto bagasse fly ash
Shouman, Mona A.; Fathy, Nady A.; El-Khouly, Sahar M.; Attia, Amina A.;
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 Abstract
Bagasse fly ash (BFA) is one of the important wastes generated in the sugar industry; it has been studied as a prospective low-cost adsorbent in the removal of congo red (CR) from aqueous solutions. Chemical treatment with was applied in order to modify the adsorbability of the raw BFA. Batch studies were performed to evaluate the influence of various experimental parameters such as dye solution pH, contact time, adsorbent dose, and temperature. Both the adsorbents were characterized by Fourier-transform infrared spectrometer, energy-dispersive X-ray spectrophotometer and nitrogen adsorption at 77 K. Equilibrium isotherms for the adsorption of CR were analyzed by Langmuir, Freundlich and Temkin models using non-linear regression technique. Intraparticle diffusion seems to control the CR removal process. The obtained experimental data can be well described by Langmuir and also followed second order kinetic models. The calculated thermodynamic parameters indicate the feasibility of the adsorption process for the studied adsorbents. The results indicate that BFA can be efficiently used for the treatment of waste water containing dyes.
 Keywords
bagasse fly ash;congo red removal;equilibrium and kinetic studies;
 Language
English
 Cited by
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 References
1.
Gregory AR, Elliot J, Kluge P. Ames testing of Direct Black 38 parallels carcinogenicity testing. J Appl Toxicol, 1, 308 (1981). http://dx.doi.org/10.1002/jat.2550010608. crossref(new window)

2.
McKay G, Otterburn MS, Aga JA. Fuller's earth and fired clay as adsorbents for dyestuffs. Equilibrium and rate studies. Water Air Soil Pollut, 24, 307 (1985). http://dx.doi.org/10.1007/BF00161790. crossref(new window)

3.
Gong R, Li M, Yang C, Sun Y, Chen J. Removal of cationic dyes from aqueous solution by adsorption on peanut hull. J Hazard Mater, 121, 247 (2005). http://dx.doi.org/10.1016/j.jhazmat.2005.01.029. crossref(new window)

4.
McKay G, Allen SJ, McConvey IF, Otterburn MS. Transport processes in the sorption of colored ions by peat particles. J Colloid Interface Sci, 80, 323 (1981). http://dx.doi.org/10.1016/0021-9797(81)90192-2. crossref(new window)

5.
Seshadri S, Bishop PL, Agha AM. Anaerobic/aerobic treatment of selected Azo dyes in wastewater. Waste Manage (Oxford), 14, 127 (1994). http://dx.doi.org/10.1016/0956-053x(94)90005-1. crossref(new window)

6.
Janos P, Buchtova H, Ryznarova M. Sorption of dyes from aqueous solutions onto fly ash. Water Res, 37, 4938 (2003). http://dx.doi.org/10.1016/j.watres.2003.08.011. crossref(new window)

7.
Panswad T, Wongchaisuwan S. Mechanisms of dye wastewater colour removal by magnesium carbonate-hydrated basic. Water Sci Technol, 18, 139 (1986).

8.
Malik PK, Saha SK. Oxidation of direct dyes with hydrogen peroxide using ferrous ion as catalyst. Sep Purif Technol, 31, 241 (2003). http://dx.doi.org/10.1016/s1383-5866(02)00200-9. crossref(new window)

9.
Koch M, Yediler A, Lienert D, Insel G, Kettrup A. Ozonation of hydrolyzed azo dye reactive yellow 84 (CI). Chemosphere, 46, 109 (2002). http://dx.doi.org/10.1016/s0045-6535(01)00102-3. crossref(new window)

10.
Ciardelli G, Corsi L, Marcucci M. Membrane separation for wastewater reuse in the textile industry. Resour Conservat Recycl, 31, 189 (2001). http://dx.doi.org/10.1016/s0921-3449(00)00079-3. crossref(new window)

11.
Mall ID, Srivastava VC, Agarwal NK, Mishra IM. Removal of congo red from aqueous solution by bagasse fly ash and activated carbon: kinetic study and equilibrium isotherm analyses. Chemosphere, 61, 492 (2005). http://dx.doi.org/10.1016/j.chemosphere.2005.03.065. crossref(new window)

12.
Capar G, Yetis U, Yilmaz L. The most effective pre-treatment to nanofiltration for the recovery of print dyeing wastewaters. Desalination, 212, 103 (2007). http://dx.doi.org/10.1016/j.desal. 2006.09.020. crossref(new window)

13.
Gad HMH, El-Sayed AA. Activated carbon from agricultural byproducts for the removal of Rhodamine-B from aqueous solution. J Hazard Mater, 168, 1070 (2009). http://dx.doi.org/10.1016/j.jhazmat.2009.02.155. crossref(new window)

14.
Soleimani Dorcheh A, Abbasi MH. Silica aerogel: synthesis, properties and characterization. J Mater Process Technol, 199, 10 (2008). http://dx.doi.org/10.1016/j.jmatprotec.2007.10.060. crossref(new window)

15.
Kuprianov VI, Janvijitsakul K, Permchart W. Co-firing of sugar cane bagasse with rice husk in a conical fluidized-bed combustor. Fuel, 85, 434 (2006). http://dx.doi.org/10.1016/j.fuel.2005.08.013. crossref(new window)

16.
Fotovat F, Kazemian H, Kazemeini M. Synthesis of Na-A and faujasitic zeolites from high silicon fly ash. Mater Res Bull, 44, 913 (2009). http://dx.doi.org/10.1016/j.materresbull.2008.08.008. crossref(new window)

17.
Srivastava VC, Swamy MM, Mall ID, Prasad B, Mishra IM. Adsorptive removal of phenol by bagasse fly ash and activated carbon: equilibrium, kinetics and thermodynamics. Colloids Surf Physicochem Eng Aspects, 272, 89 (2006). http://dx.doi.org/10.1016/j.colsurfa.2005.07.016. crossref(new window)

18.
Gupta VK, Jain CK, Ali I, Sharma M, Saini VK. Removal of cadmium and nickel from wastewater using bagasse fly ash--a sugar industry waste. Water Res, 37, 4038 (2003). http://dx.doi.org/10.1016/s0043-1354(03)00292-6. crossref(new window)

19.
Mane VS, Mall ID, Srivastava VC. Use of bagasse fly ash as an adsorbent for the removal of brilliant green dye from aqueous solution. Dyes Pigments, 73, 269 (2007). http://dx.doi.org/10.1016/j.dyepig.2005.12.006. crossref(new window)

20.
Moreno-Castilla C, Carrasco-Marin F, Parejo-Perez C, Lopez Ramon MV. Dehydration of methanol to dimethyl ether catalyzed by oxidized activated carbons with varying surface acidic character. Carbon, 39, 869 (2001). http://dx.doi.org/10.1016/s0008-6223(00)00192-5. crossref(new window)

21.
Fu Y, Viraraghavan T. Removal of Congo Red from an aqueous solution by fungus Aspergillus niger. Adv Environ Res, 7, 239 (2002). http://dx.doi.org/10.1016/s1093-0191(01)00123-x. crossref(new window)

22.
Malik DJ, Strelko Jr V, Streat M, Puziy AM. Characterisation of novel modified active carbons and marine algal biomass for the selective adsorption of lead. Water Res, 36, 1527 (2002). http://dx.doi.org/10.1016/s0043-1354(01)00348-7. crossref(new window)

23.
Finqueneisel G, Zimny T, Albiniak A, Siemieniewska T, Vogt D, Weber JV. Cheap adsorbent. Part 1: Active cokes from lignites and improvement of their adsorptive properties by mild oxidation. Fuel, 77, 549 (1998). http://dx.doi.org/10.1016/S0016-2361(97)00249-4. crossref(new window)

24.
Prasetyoko D, Ramli Z, Endud S, Hamdan H, Sulikowski B. Conversion of rice husk ash to zeolite beta. Waste Manage (Oxford), 26, 1173 (2006). http://dx.doi.org/10.1016/j.wasman.2005.09.009. crossref(new window)

25.
Rodriguez A, Garcia J, Ovejero G, Mestanza M. Adsorption of anionic and cationic dyes on activated carbon from aqueous solutions: equilibrium and kinetics. J Hazard Mater, 172, 1311 (2009). http://dx.doi.org/10.1016/j.jhazmat.2009.07.138. crossref(new window)

26.
Worathanakul P, Payubnop W, Muangpet A. Characterization for post-treatment effect of bagasse ash for silica extraction. Proc World Acad Sci Eng Tech, 56, 360 (2009).

27.
Singh BK, Nayak PS. Sorption equilibrium studies of toxic nitro-substituted phenols on fly ash. Adsorpt Sci Technol, 22, 295 (2004). http://dx.doi.org/10.1260/0263617041514901. crossref(new window)

28.
Mall ID, Srivastava VC, Agarwal NK. Removal of Orange-G and Methyl Violet dyes by adsorption onto bagasse fly ash--kinetic study and equilibrium isotherm analyses. Dyes Pigments, 69, 210 (2006). http://dx.doi.org/10.1016/j.dyepig.2005.03.013. crossref(new window)

29.
Banat F, Al-Asheh S, Al-Makhadmeh L. Utilization of raw and activated date pits for the removal of phenol from aqueous solutions. Chem Eng Technol, 27, 80 (2004). http://dx.doi.org/10.1002/ceat.200401868. crossref(new window)

30.
Malik PK. Use of activated carbons prepared from sawdust and rice-husk for adsoprtion of acid dyes: a case study of acid yellow 36. Dyes Pigments, 56, 239 (2003). http://dx.doi.org/10.1016/s0143-7208(02)00159-6. crossref(new window)

31.
Attia AA, Khedr SA, Elkholy SA. Adsorption of chromium ion (VI) by acid activated carbon. Braz J Chem Eng, 27, 183 (2010). http://dx.doi.org/10.1590/S0104-66322010000100016. crossref(new window)

32.
Ho YS, McKay G. Pseudo-second order model for sorption processes. Process Biochem, 34, 451 (1999). http://dx.doi.org/10.1016/s0032-9592(98)00112-5. crossref(new window)

33.
Aksu Z. Biosorption of reactive dyes by dried activated sludge: equilibrium and kinetic modelling. Biochem Eng J, 7, 79 (2001). http://dx.doi.org/10.1016/s1369-703x(00)00098-x. crossref(new window)

34.
Furusawa T, Smith JM. Intraparticle mass transport in slurries by dynamic adsorption studies. AlChE J, 20, 88 (1974). http://dx.doi.org/10.1002/aic.690200111. crossref(new window)

35.
Kannan N, Sundaram MM. Kinetics and mechanism of removal of methylene blue by adsorption on various carbons--a comparative study. Dyes Pigments, 51, 25 (2001). http://dx.doi.org/10.1016/s0143-7208(01)00056-0. crossref(new window)

36.
Mall ID, Srivastava VC, Agarwal NK, Mishra IM. Adsorptive removal of malachite green dye from aqueous solution by bagasse fly ash and activated carbon-kinetic study and equilibrium isotherm analyses. Colloids Surf Physicochem Eng Aspects, 264, 17 (2005). http://dx.doi.org/10.1016/j.colsurfa.2005.03.027. crossref(new window)

37.
Poots VJP, McKay G, Healy JJ. Removal of basic dye from effluent using wood as an adsorbent. J Water Pollut Control Fed, 50, 926 (1978).

38.
Allen SJ, McKay G, Khader KYH. Intraparticle diffusion of a basic dye during adsorption onto sphagnum peat. Environ Pollut, 56, 39 (1989). http://dx.doi.org/10.1016/0269-7491(89)90120-6. crossref(new window)

39.
Choy KKH, McKay G, Porter JF. Sorption of acid dyes from effluents using activated carbon. Resour Conservat Recycl, 27, 57 (1999). http://dx.doi.org/10.1016/s0921-3449(98)00085-8. crossref(new window)

40.
Kim Y, Kim C, Choi I, Rengaraj S, Yi J. Arsenic removal using mesoporous alumina prepared via a templating method. Environ Sci Technol, 38, 924 (2004). http://dx.doi.org/10.1021/es0346431. crossref(new window)

41.
Gottipati R, Mishra S. Application of biowaste (waste generated in biodiesel plant) as an adsorbent for the removal of hazardous dye--methylene blue--from aqueous phase. Braz J Chem Eng, 27, 357 (2010). http://dx.doi.org/10.1590/S0104-66322010000200014. crossref(new window)

42.
Bhattacharyya KG, Sharma A. Azadirachta indica leaf powder as an effective biosorbent for dyes: a case study with aqueous Congo Red solutions. J Environ Manage, 71, 217 (2004). http://dx.doi.org/10.1016/j.jenvman.2004.03.002. crossref(new window)

43.
Gokulakrishnan N, Pandurangan A, Sinha PK. Removal of decontaminating agent from aqueous solution using microporous and mesoporous materials: activated carbon as an effective adsorbent. Adsorpt Sci Technol, 26, 291 (2008). http://dx.doi.org/10.1260/026361708786934415. crossref(new window)

44.
Mittal AK, Venkobachar C. Studies on sorption of dyes by sulfonated coal and Ganoderma lucidum. Indian J Environ Health, 31, 105 (1989).

45.
Gupta VK, Mohan D, Sharma S. Removal of lead from wastewater using bagasse fly ash--a sugar industry waste material. Sep Sci Technol, 33, 1331 (1998). crossref(new window)