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Adsorption properties of activated carbon prepared from pre-carbonized petroleum coke in the removal of organic pollutants from aqueous solution
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  • Journal title : Carbon letters
  • Volume 12, Issue 3,  2011, pp.152-161
  • Publisher : Korean Carbon Society
  • DOI : 10.5714/CL.2011.12.3.152
 Title & Authors
Adsorption properties of activated carbon prepared from pre-carbonized petroleum coke in the removal of organic pollutants from aqueous solution
Ahmed, S.A. Sayed; El-Enin, Reham M.M. Abo; El-Nabarawy, Th.;
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Activated carbon was prepared from pre-carbonized petroleum coke. Textural properties were determined from studies of the adsorption of nitrogen at 77 K and the surface chemistry was obtained using the Fourier-transform infrared spectrometer technique and the Boehm titration process. The adsorption of three aromatic compounds, namely phenol (P), p-nitrophenol (PNP) and benzoic acid (BA) onto APC in aqueous solution was studied in a batch system with respect to contact time, pH, initial concentration of solutes and temperature. Active carbon APC obtained was found to possess a high surface area and a predominantly microporous structure; it also had an acidic surface character. The experimental data fitted the pseudo-second-order kinetic model well; also, the intraparticle diffusion was the only controlling process in determining the adsorption of the three pollutants investigated. The adsorption data fit well with the Langmuir and Freundlich models. The uptake of the three pollutants was found to be strongly dependent on the pH value and the temperature of the solution. Most of the experiments were conducted at pH 7; the of the active carbon under study was 5.0; the surface of the active carbon was negatively charged. The thermodynamic parameters evaluated for APC revealed that the adsorption of P was spontaneous and exothermic in nature, while PNP and BA showed no-spontaneity of the adsorption process and that process was endothermic in nature.
activated carbon petroleum coke;adsorption;aromatic organic acids;equilibrium;thermodynamic parameters;
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seeds-derived adsorbents, Adsorption Science & Technology, 2016, 34, 9-10, 565  crossref(new windwow)
Belhachemi M, Rios RVRA, Addoun F, Silvestre-Albero J, Sepulveda- Escribano A, Rodriguez-Reinoso F. Preparation of activated carbon from date pits: effect of the activation agent and liquid phase oxidation. J Anal Appl Pyrolysis, 86, 168 (2009). crossref(new window)

Girgis BS, El-Hendawy A-NA. Porosity development in activated carbons obtained from date pits under chemical activation with phosphoric acid. Microporous Mesoporous Mater, 52, 105 (2002). crossref(new window)

Liu QS, Zheng T, Wang P, Guo L. Preparation and characterization of activated carbon from bamboo by microwave-induced phosphoric acid activation. Ind Crop Prod, 31, 233 (2010). crossref(new window)

Lua AC, Yang T. Theoretical and experimental $SO_2$ adsorption onto pistachio-nut-shell activated carbon for a fixed-bed column. Chem Eng J, 155, 175 (2009). crossref(new window)

Tay T, Ucar S, Karagoz S. Preparation and characterization of activated carbon from waste biomass. J Hazard Mater, 165, 481 (2009). crossref(new window)

Moreno-Castilla C, Rivera-Utrilla J, Lopez-Ramon MV, Carrasco-Marin F. Adsorption of some substituted phenols on activated carbons from a bituminous coal. Carbon, 33, 845 (1995). crossref(new window)

Mishra SB, Langwenya SP, Mamba BB, Balakrishnan M. Study on surface morphology and physicochemical properties of raw and activated South African coal and coal fly ash. Phys Chem Earth, 35, 811 (2010). crossref(new window)

Jiang B, Zhang Y, Zhou J, Zhang K, Chen S. Effects of chemical modification of petroleum cokes on the properties of the resulting activated carbon. Fuel, 87, 1844 (2008). crossref(new window)

Ahmed SAS, El-enin RMMA, El-Nabarawy T. Preparation and characterization of KOH-activated carbons developed from petroleum coke. Carbon Lett, 10, 293 (2009). crossref(new window)

Kawano T, Kubota M, Onyango MS, Watanabe F, Matsuda H. Preparation of activated carbon from petroleum coke by KOH chemical activation for adsorption heat pump. Appl Therm Eng, 28, 865 (2008). crossref(new window)

Pelech R, Bembnowska A, Milchert E. Kinetics of adsorption of hydrocarbon chloro-derivatives from seven-component aqueous solution onto a thin layer of DTO-activated carbon. J Colloid Interface Sci, 290, 83 (2005). crossref(new window)

Carrott PJM, Ribeiro Carrott MML, Vale TSC, Marques L, Nabais VJM, Mourao PAM. Characterisation of surface ionisation and adsorption of phenol and 4-nitrophenol on non-porous carbon blacks. Adsorpt Sci Technol, 26, 827 (2008). crossref(new window)

Pelech R, Milchert E. Adsorption of 1,2-dichloropropane from aqueous solution onto activated carbon. Adsorpt Sci Technol, 26, 251 (2008). crossref(new window)

Garcia-Garcia A, Gregorio A, Boavida D, Gulyurtlu I. Activated carbons prepared from pine wastes for the uptake of organic compounds from aqueous solution. Adsorpt Sci Technol, 20, 1051 (2002). crossref(new window)

Yamashita Y, Ouchi K. Influence of alkali on the carbonization process--I: Carbonization of 3,5-dimethylphenol-formaldehyde resin with NaOH. Carbon, 20, 41 (1982). crossref(new window)

Nouri S. Amir Kabir, 14, 12 (2002).

Nouri S. Effect of different treatment on the adsorption of p-cresol by activated carbon (Langmuir Isotherm). Asian J Chem, 14, 934 (2002).

Nouri S, Haghseruht F, Lu M. Effects of Solution pH on the Adsorption of Aromatic Compounds from Aqueous Solution by Activated carbon. Amir Kabir, 13, 26 (2002).

Nouri S, Haghseresht F, Lu M. Adsorption of aromatic compounds by activated carbon: effects of functional groups and molecular size. Adsorpt Sci Technol, 20, 1 (2002). crossref(new window)

Ayranci E, Duman O. Adsorption of aromatic organic acids onto high area activated carbon cloth in relation to wastewater purification. J Hazard Mater, 136, 542 (2006). crossref(new window)

Ayranci E, Hoda N, Bayram E. Adsorption of benzoic acid onto high specific area activated carbon cloth. J Colloid Interface Sci, 284, 83 (2005). crossref(new window)

Chern JM, Chien YW. Competitive adsorption of benzoic acid and p-nitrophenol onto activated carbon: isotherm and breakthrough curves. Water Res, 37, 2347 (2003). crossref(new window)

Gasten VA, Weiss DE. Rev Pure Appl Chem, 7, 69 (1957).

Lim PK, Cha JA, Patel CP. Aerobic coupling of aqueous phenol catalyzed by cuprous chloride: basis of a novel dephenolization scheme for phenolic wastewaters. Ind Eng Chem Process Des Dev, 22, 477 (1983). crossref(new window)

Noh JS, Schwarz JA. Estimation of the point of zero charge of simple oxides by mass titration. J Colloid Interface Sci, 130, 157 (1989). crossref(new window)

Boehm HP. Some aspects of the surface chemistry of carbon blacks and other carbons. Carbon, 32, 759 (1994). 10.1016/0008-6223(94)90031-0. crossref(new window)

Sing KSW. Empirical method for analysis of adsorption isotherms. Chem Ind (London), 44, 1520 (1968).

Friedel RA, Queiser JA. Infrared analysis of bituminous coals and other carbonaceous materials. Anal Chem, 28, 22 (1956). crossref(new window)

Gomez-Serrano V, Acedo-Ramos M, Lopez-Peinado AJ, Valenzuela- Calahorro C. Oxidation of activated carbon by hydrogen peroxide. Study of surface functional groups by FT-i.r. Fuel, 73, 387 (1994). crossref(new window)

Bansal RC, Donnet JB, Stoeckli F. Active Carbon, Marcel Dekker, New York, 435 (1988).

Stuart B, Ando DJ. Modern Infrared Spectroscopy, Wiley, New York (1996).

Nassar M, Magdy Y, Daifullah AEH, Kelany, Kelany H. Mass transfer and adsorption kinetics of phenolic compounds onto activated carbon prepared from rice husk. Adsorpt Sci Technol, 26, 157 (2008). crossref(new window)

Nouri S, Haghseresht F. Adsorption of dissociating aromatic compounds by activated carbon: effects of ionization on the adsorption capacity. Adsorpt Sci Technol, 20, 417 (2002). crossref(new window)

Hall KR, Eagleton LC, Acrivos A, Vermeulen T. Pore- and soliddiffusion kinetics in fixed-bed adsorption under constant-pattern conditions. Ind Eng Chem Fundam, 5, 212 (1966). crossref(new window)

Terzyk AP, Gauden PA. The simple procedure of the calculation of diffusion coefficient for adsorption on spherical and cylindrical adsorbent particles--experimental verification. J Colloid Interface Sci, 249, 256 (2002). crossref(new window)

Terzyk A. Adsorption of biologically active compounds from aqueous solutions on to commercial unmodified activated carbons. Part V. The mechanism of the physical and chemical adsorption of phenol. Adsorpt Sci Technol, 21, 539 (2003). crossref(new window)

Abuzaid NS, Nakhla GF. Modeling of the temperature variation effects on the polymerization reactions of phenolics on granular activated carbon. Sep Sci Technol, 32, 1255 (1997). crossref(new window)

Koganovski AM, Zaidel A, Radeke KH. Khim Teknol Vody, 6, 500 (1987).

Juang RS, Lin SH, Tsao KH. Sorption of phenols from water in column systems using surfactant-modified montmorillonite. J Colloid Interface Sci, 269, 46 (2004). crossref(new window)

Bartelt-Hunt SL, Burns SE, Smith JA. Nonionic organic solute sorption onto two organobentonites as a function of organic-carbon content. J Colloid Interface Sci, 266, 251 (2003). crossref(new window)