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Structural evolution and kinetic study of high isotacticity poly(acrylonitrile) during isothermal pre-oxidation
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  • Journal title : Carbon letters
  • Volume 12, Issue 4,  2011, pp.229-235
  • Publisher : Korean Carbon Society
  • DOI : 10.5714/CL.2011.12.4.229
 Title & Authors
Structural evolution and kinetic study of high isotacticity poly(acrylonitrile) during isothermal pre-oxidation
Zhang, Li; Dai, Yongqiang; Kai, Yi; Jin, Ri-Guang;
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Isotactic polyacrylonitrile (PAN) with triad isotacticity of 0.53, which was determined by NMR, using dialkylmagnesium as an initiator, was successfully synthesized. Isothermal treatment of iso-PAN was conducted in air at 200, 220, 250 and . Structural evolutions and chemical changes were studied with Fourier transformation infrared and wide-angle X-ray diffraction during stabilization. A new parameter $CNF
high isotacticity;polyacrylonitrile;stabilization;kinetics;iso-conversional;
 Cited by
POSS 부가가 폴리아크릴로니트릴 중합과 열적 성질에 미치는 영향,김미희;하유미;김민아;핫산 말릭 삼시;구자람;김현철;길명섭;

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