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CO2 adsorption characteristics of slit-pore shaped activated carbon prepared from cokes with high crystallinity
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  • Journal title : Carbon letters
  • Volume 16, Issue 1,  2015, pp.45-50
  • Publisher : Korean Carbon Society
  • DOI : 10.5714/CL.2015.16.1.045
 Title & Authors
CO2 adsorption characteristics of slit-pore shaped activated carbon prepared from cokes with high crystallinity
Park, Mi-Seon; Lee, Si-Eun; Kim, Min Il; Lee, Young-Seak;
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High crystallinity coke-based activated carbon (hc-AC) is prepared using a potassium hydroxide solution to adsorb carbon dioxide (). The adsorption characteristics of the prepared hc-AC are investigated at different temperatures. The X-ray diffraction patterns indicate that pitch-based cokes prepared under high temperature and pressure have a high crystal structure. The textural properties of hc-AC indicate that it consists mainly of slit-like pores. Compared to other textural forms of AC that have higher pore volumes, this slit-pore-shaped hc-AC exhibits higher adsorption due to the similar shape between its pores and molecules. Additionally, in these high-crystallinity cokes, the main factor affecting adsorption at lower temperature is the pore structure, whereas the presence of oxygen functional groups on the surface has a greater impact on adsorption at higher temperature.
activated carbon; adsorption;coke;activation;porosity;
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Bai BC, Cho S, Yu HR, Yi KB, Kim KD, Lee YS. Effects of aminated carbon molecular sieves on breakthrough curve behavior in $CO_2/CH_4$ separation. J Ind Eng Chem, 19, 776 (2013). crossref(new window)

Miyamoto M, Fujioka Y, Yogo K. Pure silica CHA type zeolite for $CO_2$ separation using pressure swing adsorption at high pressure. J Mater Chem, 22, 20186 (2012). crossref(new window)

Cho S, Yu HR, Kim KD, Yi KB, Lee YS. Surface characteristics and carbon dioxide capture characteristics of oxyfluorinated carbon molecular sieves. Chem Eng J, 211-212, 89 (2012). crossref(new window)

Xu X, Song C, Andresen JM, Miller BG, Scaroni AW. Novel polyethylenimine- modified mesoporous molecular sieve of MCM-41 type as high-capacity adsorbent for $CO_2$ capture. Energy Fuels, 16, 1463 (2002). crossref(new window)

Siriwardane RV, Shen M-S, Fisher EP, Losch J. Adsorption of $CO_2$ on zeolites at moderate temperatures. Energy Fuels, 19, 1153 (2005). crossref(new window)

Labus K, Gryglewicz S, Machnikowski J. Granular KOH-activated carbons from coal-based cokes and their $CO_2$ adsorption capacity. Fuel, 118, 9 (2014). crossref(new window)

Lee SG, Park KH, Shim WG, balathanigaimani MS, Moon H. Performance of electrochemical double layer capacitors using highly porous activated carbons prepared from beer lees. J Ind Eng Chem, 17, 450 (2011). crossref(new window)

Adinaveen T, Kennedy LJ, Vijaya JJ, Sekaran G. Studies on structural, morphological, electrical and electrochemical properties of activated carbon prepared from sugarcane bagasse. J Ind Eng Chem, 19, 1470 (2013). crossref(new window)

Jagiello J, Tolles ED. Calculation of pore size distribution of activated carbons based on density functional theory (DFT) data. In: Meunier F, ed. Fundamentals of Adsorption 6, Elsevier, New York, NY, 629 (1998).

Yu L, Kim KJ, Park DY, Kim MS, Kim KI, Lim YS. Preparation and characterization of pitch/cokes composite anode material for high power lithium secondary battery. Carbon Lett, 9, 210 (2008). crossref(new window)

Park MS, Cho S, Jeong E, Lee YS. Physico-chemical and electrochemical properties of pitch-based high crystallinity cokes used as electrode material for electric double layer capacitor. J Ind Eng Chem, in press.

Condon JB. Surface Area and Porosity Determinations by Physisorption: Measurements and Theory, Elsevier, Amsterdam (2006).

Yu HR, Cho S, Jung MJ, Lee YS. Electrochemical and structural characteristics of activated carbon-based electrodes modified via phosphoric acid. Microporous Mesoporous Mater, 172, 131 (2013). crossref(new window)

An H, Feng B, Su S. $CO_2$ capture by electrothermal swing adsorption with activated carbon fibre materials. Int J Greenh Gas Control, 5, 16 (2011). crossref(new window)

Shafeeyan MS, Daud WMAW, Houshmand A, Shamiri A. A review on surface modification of activated carbon for carbon dioxide adsorption. J Anal Appl Pyrolysis, 89, 143 (2010). crossref(new window)

Tressaud A, Durand E, Labrugere C. Surface modification of several carbon-based materials: comparison between $CF_4$ rf plasma and direct $F_2$-gas fluorination routes. J Fluorine Chem, 125, 1639 (2004). crossref(new window)

Mathur RB, Gupta V, Bahl OP, Tressaud A, Flandrois S. Improvement in the mechanical properties of polyacrylonitrile (PAN)- based carbon fibers after fluorination. Synth Met, 114, 197 (2000). crossref(new window)

Cho SH, Bai BC, Yu HR, Lee YS. Carbon capture and $CO_2/CH_4$ separation technique using porous carbon materials. Appl Chem Eng, 22, 343 (2011).

Lee CS, Ong YL, Aroua MK, Daud WMAW. Impregnation of palm shell-based activated carbon with sterically hindered amines for $CO_2$ adsorption. Chem Eng J, 219, 558 (2013). crossref(new window)

Shafeeyan MS, Daud WMAW, Houshmand A, Arami-Niya A. Ammonia modification of activated carbon to enhance carbon dioxide adsorption: effect of pre-oxidation. Appl Surf Sci, 257, 3936 (2011). crossref(new window)

Pevida C, Plaza MG, Arias B, Fermoso J, Rubiera F, Pis JJ. Surface modification of activated carbons for $CO_2$ capture. Appl Surf Sci, 254, 7165 (2008). crossref(new window)

Plaza MG, Garcia S, Rubiera F, Pis JJ, Pevida C. Evaluation of ammonia modified and conventionally activated biomass based carbons as $CO_2$ adsorbents in postcombustion conditions. Sep Purif Technol, 80, 96 (2011). crossref(new window)

Heidari A, Younesi H, Rashidi A, Ghoreyshi AA. Evaluation of $CO_2$ adsorption with eucalyptus wood based activated carbon modified by ammonia solution through heat treatment. Chem Eng J, 254, 503 (2014). crossref(new window)

Deng S, Wei H, Chen T, Wang B, Huang J, Yu G. Superior $CO_2$ adsorption on pine nut shell-derived activated carbons and the effective micropores at different temperatures. Chem Eng J, 253, 46 (2014). crossref(new window)

Torrisi A, Mellot-Draznieks C, Bell RG. Impact of ligands on $CO_2$ adsorption in metal-organic frameworks: first principles study of the interaction of $CO_2$ with functionalized benzenes. I. Inductive effects on the aromatic ring. J Chem Phys, 130, 194703 (2009). crossref(new window)

Torrisi A, Mellot-Draznieks C, Bell RG. Impact of ligands on $CO_2$ adsorption in metal-organic frameworks: first principles study of the interaction of $CO_2$ with functionalized benzenes. II. Effect of polar and acidic substituents. J Chem Phys, 132, 044705 (2010). crossref(new window)