Influence of Nitrogen moieties on CO2 capture of Carbon Aerogel Jeon, Da-Hee; Min, Byung-Gak; Oh, Jong Gab; Nah, Changwoon; Park, Soo-Jin;
Carbon aerogel is a porous carbon material possessing high porosity and high specific surface area. Nitrogen doping reduced the specific surface area and micropores, but it furnished basic sites to improve the selectivity. In this work, N-doped carbon aerogels were prepared with different ratios of resorcinol/melamine by using the sol-gel method. The morphological properties were characterized by scanning electron microscopy (SEM). Nitrogen content was studied by X-ray photoelectron spectroscopy (XPS) and the specific surface area and micropore volume were analyzed by adsorption-desorption isotherms at 77 K. The adsorption capacity was investigated by adsorption-desorption isotherms at 298 K and 1 bar. Melamine containing N-doped CAs showed a high nitrogen content (5.54 wt.%). The prepared N-doped CAs exhibited a high capture capacity of 118.77 mg/g (at resorcinol/melamine = 1:0.3). Therefore, we confirmed that the adsorption capacity was strongly affected by the nitrogen moieties.
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