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Electrochemical Reduction of Carbon Dioxide Using Porous La0.8Sr0.2CuO3 Electrode
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  • Journal title : Korean Chemical Engineering Research
  • Volume 52, Issue 2,  2014, pp.247-255
  • Publisher : The Korean Institute of Chemical Engineers
  • DOI : 10.9713/kcer.2014.52.2.247
 Title & Authors
Electrochemical Reduction of Carbon Dioxide Using Porous La0.8Sr0.2CuO3 Electrode
Kim, Jung Ryoel; Lee, Hong Joo; Park, Jung Hoon;
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powder with the perovskite structure was prepared as electrode catalyst using citrate method. Porous electrode was made with as-prepared catalyst, carbon as supporter and polytetrafluoroethylene (PTFE) as hydrophobic binder. As results of potentiostatic electrolysis with potential of -1.5~-2.5 V vs. Ag/AgCl in 0.1, 0.5 and 1.0 M KOH at 5 and on the porous electrode, liquid products were methanol, ethanol, 2-propanol and 1, 2-butanol regardless reaction temperature, while gas products were methane, ethane and ethylene at , and methane, ethane and propane at respectively. Optimal potentials for reduction in the view of over all faradic efficiency were high values (-2.0 and -2.2 V) for gas products whereas low potential (-1.5 V) for liquid products regardless of concentration and temperature.
; Reduction;Electrochemical Reaction;Perovskite;Porous Electrode;
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