Advanced SearchSearch Tips
Effects of Promoter on the Formation of Gas Hydrate from Blast Furnace Gas
facebook(new window)  Pirnt(new window) E-mail(new window) Excel Download
  • Journal title : Korean Chemical Engineering Research
  • Volume 53, Issue 1,  2015, pp.103-110
  • Publisher : The Korean Institute of Chemical Engineers
  • DOI : 10.9713/kcer.2015.53.1.103
 Title & Authors
Effects of Promoter on the Formation of Gas Hydrate from Blast Furnace Gas
Kwak, Gye-Hoon; Sa, Jeong-Hoon; Kim, Si-Hwan; Lee, Bo Ram; Lee, Kun-Hong;
  PDF(new window)
In this work, the performance of various promoters was investigated used in separation from the gases emitted from steel-making process using gas hydrate technology. The studied promoters are tetrahydrofuran (THF), propylene oxide and 1,4-dioxane, which are all expected to form a structure II hydrate, and the target gases include mixed gases (
Gas Hydrates; Separation;Promotion Effect;Blast Furnace Gas (BFG);
 Cited by

Association, W. S., "World Steel in Figures 2008. Brussels: World steel association," (2008).



Kang, S.-P. and Lee, H., "Recovery of $CO_2$ from Flue Gas Using Gas Hydrate: Thermodynamic Verification Through Phase Equi-Librium Measurements," Environ. Sci. Technol., 34, 4397(2000). crossref(new window)

Lee, B. R., Ryu, J.-H., Han, K., Park, D.-H., Lee, K.-H. and Lee, I.-B., "Recent Research Trends on Separation of $CO_2$ Emitted From Steelmaking Process using Gas Hydrate Technology," Korean Chem. Eng. Res., 48, 232(2010).

Sloan Jr, E. D. and Koh, C., Clathrate Hydrates of Natural Gases, CRC press(2007).

Seo, Y.-T., Kang, S.-P. and Lee, H., "Experimental Determination and Thermodynamic Modeling of Methane and Nitrogen Hydrates in the Presence of THF, Propylene oxide, 1, 4-dioxane and Acetone," Fluid Phase Equilib., 189, 99(2001). crossref(new window)

Saito, Y., Kawasaki, T., Kondo, T. and Hiraoka, R., "Methane Storage in Hydrate Phase with Water Soluble Guests," Proceeding of the Second International Conference on Gas Hydrate, Toulouse, France, pp. 459-465(1996).

Maekawa, T., "Equilibrium Conditions of Clathrate Hydrates Formed from Carbon Dioxide and Aqueous Acetone Solutions," Fluid Phase Equilib., 303, 76(2011). crossref(new window)

Seo, Y., Kang, S.-P., Lee, S. and Lee, H., "Experimental Measurements of Hydrate Phase Equilibria for Carbon Dioxide in the Presence of THF, Propylene Oxide, and 1, 4-dioxane," J. Chem. Eng. Data, 53, 2833(2008). crossref(new window)

Mohammadi, A. H., Martinez-Lopez, J. F. and Richon, D., "Determining Phase Diagrams of Tetrahydrofuran + Methane, Carbon Dioxide or Nitrogen Clathrate Hydrates Using an Artificial Neural Network Algorithm," Chem. Eng. Sci., 65, 6059(2010). crossref(new window)

Strobel, T. A., Koh, C. A. and Sloan, E. D., "Thermodynamic Predictions of Various Tetrahydrofuran and Hydrogen Clathrate Hydrates," Fluid Phase Equilib., 280, 61(2009). crossref(new window)

Yoon, J.-H., "A Theoretical Prediction of Cage Occupancy and Heat of Dissociation of THF-$CH_4$ Hydrate," Korean J. Chem. Eng., 29, 1670(2012). crossref(new window)

Fan, S., Liang, D. and Guo, K., "HydrRAate Equilibrium Conditions for Cyclopentane and a Quaternary Cyclopentane-rich Mixture," J. Chem. Eng. Data, 46, 930(2001). crossref(new window)

Trueba, A. T., Rovetto, L. J., Florusse, L. J., Kroon, M. C. and Peters, C. J., "Phase Equilibrium Measurements of Structure II Clathrate Hydrates of Hydrogen with Various Promoters," Fluid Phase Equilib., 307, 6(2011). crossref(new window)

Zhang, J. and Lee, J. W., "Equilibrium of Hydrogen + Cyclopentane and Carbon Dioxide + Cyclopentane Binary Hydrates," J. Chem. Eng. Data, 54, 659(2008).

Zhang, J. and Lee, J. W., "Enhanced Kinetics of $CO_2$ Hydrate Formation Under Static Conditions," Ind. Eng. Chem. Res., 48, 5934(2008).

Mohammadi, A. H. and Richon, D., "Phase Equilibria of Clathrate Hydrates of Methyl Cyclopentane, Methyl Cyclohexane, Cyclopentane or Cyclohexane + Carbon Dioxide," Chem. Eng. Sci., 64, 5319(2009). crossref(new window)

Lim, Y.-A., Babu, P., Kumar, R. and Linga, P., "Morphology of Carbon Dioxide-hydrogen-cyclopentane Hydrates with or Without Sodium Dodecyl Sulfate," Crystal Growth & Design 13, 2047(2013). crossref(new window)

Shimada, W., Ebinuma, T., Oyama, H., Kamata, Y., Takeya, S., Uchida, T., Nagao, J. and Narita, H., "Separation of Gas Molecule Using Tetra-n-butyl Ammonium Bromide Semi-clathrate Hydrate Crystals," Jpn. J. Appl. Phys., 42, L129(2003). crossref(new window)

Kamata, Y., Oyama, H., Shimada, W., Ebinuma, T., Takeya, S., Uchida, T., Nagao, J. and Narita, H., "Gas Separation Method Using Tetra-n-butyl Ammonium Bromide Semi-clathrate Hydrate," Jpn. J. Appl. Phys., 43, 362(2004). crossref(new window)

Shin, K., Kim, Y., Strobel, T. A., Prasad, P., Sugahara, T., Lee, H., Sloan, E. D., Sum, A. K. and Koh, C. A., "Tetra-n-butylammonium Borohydride Semiclathrate: A Hybrid Material for Hydrogen Storage," J. Phys. Chem. A, 113, 6415(2009).

Acosta, H. Y., Bishnoi, P. R. and Clarke, M. A., "Experimental Measurements of the Thermodynamic Equilibrium Conditions of Tetra-n-butylammonium Bromide Semiclathrates Formed from Synthetic Landfill Gases," J. Chem. Eng. Data, 56, 69(2010).

Lee, S., Lee, Y., Park, S. and Seo, Y., "Phase Equilibria of Semiclathrate Hydrate for Nitrogen in the Presence of Tetra-n-Butylammonium Bromide and Fluoride," J. Chem. Eng. Data, 55, 5883 (2010). crossref(new window)

Chapoy, A., Gholinezhad, J. and Tohidi, B., "Experimental Clathrate Dissociations for the Hydrogen + Water and Hydrogen + Tetrabutylammonium Bromide + Water Systems," J. Chem. Eng. Data, 55, 5323(2010). crossref(new window)

Li, G., Liu, D. and Xie, Y., "Study on Thermal Properties of TBAB-THF Hydrate Mixture for Cold Storage by Dsc," J. Therm. Anal. Calorim., 102, 819(2010). crossref(new window)

Oshima, M., Shimada, W., Hashimoto, S., Tani, A. and Ohgaki, K., "Memory Effect on Semi-clathrate Hydrate Formation: A Case Study of Tetragonal Tetra-n-butyl Ammonium Bromide Hydrate," Chem. Eng. Sci., 65, 5442(2010). crossref(new window)

Rodionova, T., Komarov, V., Villevald, G., Aladko, L., Karpova, T. and Manakov, A., "Calorimetric and Structural Studies of Tetrabutylammonium Chloride Ionic Clathrate Hydrates," J. Phys. Chem. B, 114, 11838(2010). crossref(new window)

Deschamps, J. and Dalmazzone, D., "Hydrogen Storage in Semiclathrate Hydrates of Tetrabutyl Ammonium Chloride and Tetrabutyl Phosphonium Bromide," J. Chem. Eng. Data, 55, 3395(2010). crossref(new window)

Li, S., Fan, S., Wang, J., Lang, X. and Wang, Y., "Semiclathrate Hydrate Phase Equilibria for $CO_2$ in the Presence of Tetra-n-Butyl Ammonium Halide (bromide, chloride, or fluoride)," J. Chem. Eng. Data, 55, 3212(2010). crossref(new window)

Sun, Z.-G. and Sun, L., "Equilibrium Conditions of Semi-clathrate Hydrate Dissociation for Methane + Tetra-n-butyl Ammonium Bromide," J. Chem. Eng. Data, 55, 3538(2010). crossref(new window)

Li, X.-S., Xu, C.-G., Chen, Z.-Y. and Wu, H.-J., "Tetra-n-butyl Ammonium Bromide Semi-clathrate Hydrate Process for Post-combustion Capture of Carbon Dioxide in the Presence of Dodecyl Trimethyl Ammonium Chloride," Energy, 35, 3902(2010). crossref(new window)

Li, X.-S., Xia, Z.-M., Chen, Z.-Y., Yan, K.-F., Li, G. and Wu, H.- J., "Equilibrium Hydrate Formation Conditions for the Mixtures of $CO_2$ + $H_2$ + Tetrabutyl Ammonium Bromide," J. Chem. Eng. Data, 55, 2180(2009).

Mayoufi, N., Dalmazzone, D., Furst, W., Delahaye, A. and Fournaison, L., "$CO_2$ Enclathration in Hydrates of Peralkyl-(ammonium/ phosphonium) Salts: Stability Conditions and Dissociation Enthalpies," J. Chem. Eng. Data, 55, 1271(2009).

Makino, T., Yamamoto, T., Nagata, K., Sakamoto, H., Hashimoto, S., Sugahara, T. and Ohgaki, K., "Thermodynamic Stabilities of Tetra-n-butyl Ammonium Chloride + $H_2$, $N_2$, $CH_4$, $CO_2$, or $C_2H_6$ Semiclathrate Hydrate Systems," J. Chem. Eng. Data, 55, 839 (2009).

Deschamps, J. and Dalmazzone, D., "Dissociation Enthalpies and Phase Equilibrium for TBAB Semi-clathrate Hydrates of $N_2$, $CO_2$, $N_2$ + $CO_2$ and $CH_4$ + $CO_2$," J. Therm. Anal. Calorim., 98, 113(2009). crossref(new window)

Fan, S., Li, S., Wang, J., Lang, X. and Wang, Y., "Efficient Capture of $CO_2$ from Simulated Flue Gas by Formation of TBAB or TBAF Semiclathrate Hydrates," Energy Fuels, 23, 4202(2009). crossref(new window)

Lee, B. R., Sa, J.-H., Park, D.-H., Cho, S., Lee, J., Kim, H.-J., Oh, E., Jeon, S., Lee, J. D. and Lee, K.-H., "Continuous" Method for the Fast Screening of Thermodynamic Promoters of Gas Hydrates Using a Quartz Crystal Microbalance," Energy Fuels, 26, 767(2011).

Sa, J.-H., Kwak, G.-H., Lee, B. R., Park, D.-H., Han, K. and Lee, K.-H., "Hydrophobic Amino Acids as a New Class of Kinetic Inhibitors for Gas Hydrate Formation," Scientific Reports, 3 (2013).

Seo, Y.-T. and Lee, H., "Structure and Guest Distribution of the Mixed Carbon Dioxide and Nitrogen Hydrates as Revealed by X-ray Diffraction and 13c Nmr Spectroscopy," J. Phys. Chem. B, 108, 530(2004). crossref(new window)

Florusse, L. J., Peters, C. J., Schoonman, J., Hester, K. C., Koh, C. A., Dec, S. F., Marsh, K. N. and Sloan, E. D., "Stable Low-pressure Hydrogen Clusters Stored in a Binary Clathrate Hydrate," Science, 306, 469 (2004). crossref(new window)

Alavi, S., Susilo, R. and Ripmeester, J. A., "Linking Microscopic Guest Properties to Macroscopic Observables in Clathrate Hydrates: Guest-host Hydrogen Bonding," J. Chem. Phys., 130, 174501(2009). crossref(new window)

Van Cleeff, A. and Diepen, G., "Gas Hydrates of Nitrogen and Oxygen Ii," Recueil des Travaux Chimiques des Pays-Bas 84, 1085(1965).

Adisasmito, S., Frank III, R. J. and Sloan Jr, E. D., "Hydrates of Carbon Dioxide and Methane Mixtures," J. Chem. Eng. Data, 36, 68(1991). crossref(new window)