Advanced SearchSearch Tips
Effect of SiC Crystal Phase on Growing ZSM-5 on the Surface of SiC
facebook(new window)  Pirnt(new window) E-mail(new window) Excel Download
  • Journal title : Korean Chemical Engineering Research
  • Volume 53, Issue 2,  2015, pp.247-252
  • Publisher : The Korean Institute of Chemical Engineers
  • DOI : 10.9713/kcer.2015.53.2.247
 Title & Authors
Effect of SiC Crystal Phase on Growing ZSM-5 on the Surface of SiC
Jung, Eunjin; Lee, Yoon Joo; Kim, Younghee; Kwon, Woo Teck; Shin, Dong-Geun; Kim, Soo Ryong;
  PDF(new window)
ZSM-5 crystals grew on the surface of -SiC and -SiC particles by hydrothermal synthesis method. SiC particles which were > of size were used, and oxide layer were developed on the surface of the particles to induce growth of ZSM-5 from the surface. Then, synthesis time and temperature condition were considered growing ZSM-5. In this study, oxide layer was formed on -SiC at in air, and it was controlled to grow ZSM-5 grew from the -SiC surface with synthesis condition. This is due to Si-O-Si or Si-O-Al bond, which is basic framework of ZSM-5 can be easily formed, from the silicon oxide film on the surface of -SiC. When the synthesis temperature was , the size of ZSM-5 was increased, and it covered much area of the SiC surface with better crystal shapes with longer synthesis time.
Zeolite;Silicon Carbide;SiC;Catalyst Support;Catalyst;
 Cited by
Baerlocher, C., Meier, W. M. and Olson, D. H., "Atlas of Zeolite Structure Types," Vol 190. London, Elsevier (1996).

Van Donk, S., Janssen, A. H., Bitter, J. H. and de Jong, K. P., "Generation, Characterization, and Impact of Mesopores in Zeolite Catalysts," Catal. Rev., 45, 297-319(2003). crossref(new window)

Darthomeuf, D., "Zeolite Acidity Dependence on Structure and Chemical Environment. Correlations with Catalysis," Mater. Chem. Phys., 17, 49-71(1987). crossref(new window)

Meusinger, J. and Corma, A., "Influence of Zeolite Composition and Structure on Hydrogen Transfer Reactions from Hydrocarbons and from Hydrogen," J. Catal. 159, 353-360(1996). crossref(new window)

Weitkamp, J., "Zeolites and Catalysis," Solid State Ion., 131, 175-188(2000). crossref(new window)

Argenauer, R. J. and Landolt, G. R., "Crystalline Zeolite ZSM-5 and Method of Preparing the Same," US Patent 3,702,886(1972).

Olson, D. H., Haag, W. O. and Lago, R. M., "Chemical and Physical Properties of the ZSM-5 Substitutional Series," J. Catal., 61, 390-396(1980). crossref(new window)

Yang, G., He, J., Yoneyama, Y., Tan, Y., Han, Y. and Tsubaki, N., "Preparation, Characterization and Reaction Performance of HZSM-5/Cobalt/Silica Capsule Catalysts with Different Sizes for Direct Synthesis of Isoparaffins," Appl. Catal. A, 329, 99-105 (2007). crossref(new window)

Lee, Y.-J., Kim, Y.-W., Viswanadham, N., Jun, K.-W. and Bae, J. W., "Novel Aluminophosphate (AlPO) Bound ZSM-5 Extrudates with Improved Catalytic Properties for Methanol to Propylene (MTP) Reaction," Appl. Catal. A, 374, 18-25(2010). crossref(new window)

Suzuki, H., "Composite Membrane Having a Surface Layer of an Ultrathin Film of Cage-shaped Zeolite and Processes for Production Thereof," US Patent 4,699,892(1987).

Rauscher, M., Selvam, T., Schwieger, W. and Freude, D., "Hydrothermal Transformation of Porous Glass Granules into ZSM-5 Granules," Micropor. Mesopor. Mat., 75, 195-202(2004). crossref(new window)

Louis, B., Ocampo, F., Yun, H. S., Tessonnier, J. P. and Pereira, M. M., "Hierarchical Pore ZSM-5 Zeolite Structures: From Microto Macro-Engineering of Structured Catalysts," Chem. Eng. J., 161, 397-402(2010). crossref(new window)

Eslava, S., Iacopi, F., Baklanov, M. R., Kirschhock, C. E, Maex, K. and Martens, J. A., "Ultraviolet-Assisted Curing of Polycrystalline Pure-Silica Zeolites:Hydrophobization, Functionalization, and Cross-Linking of Grains," J. Am. Chem. Soc., 129, 9288-9289(2007). crossref(new window)

Seijger, G. B. F., Oudshoorn, O. L., Van Kooten, W. E. J., Jansen, J. C., Van Bekkum, H., Van Den Bleek, C. M. and Calis, H. P. A., "In Situ Synthesis of Binderless ZSM-5 Zeolitic Coatings on Ceramic Foam Supports," Micropor. Mesopor. Mat., 39, 195-204(2000). crossref(new window)

Ledoux, M. J. and Pham-Huu, C. "Silicon Carbide: a Novel Catalyst Support for Heterogeneous Catalysis," Cattech, 5, 226-246 (2001). crossref(new window)

Moene, R., Makkee, M. and Moulijn, J. A., "High Surface Area Silicon Carbide as Catalyst Support Characterization and Stability," Appl. Catal. A: Gen., 167, 321-330(1998). crossref(new window)

Krawiec, P. and Kaskel, S. "Thermal Stability of High Surface Area Silicon Carbide Materials," J. Solid State Chem., 179, 2281-2289 (2006). crossref(new window)

Ivanova, S., Vanhaecke, E., Louis, B., Libs, S., Ledoux, M. J., Rigolet, S. and Pham-Huu, C., "Efficient Synthesis of Dimethyl Ether over HZSM-5 Supported on Medium-Surface-Area $\beta$-SiC Foam," ChemSusChem, 1, 851-857(2008). crossref(new window)

Losch, P., Boltz, M., Soukup, K., Song, I. H., Yun, H. S. and Louis, B., "Binderless Zeolite Coatings on Macroporous Α-sic Foams," Micropor. Mesopor. Mat., 188, 99-107(2014). crossref(new window)

Jung, E. J., Lee, Y. J., Kim, S. R., Kwon, W. T., Choi, D. J. and Kim, Y., "Purification and Particle Size Control of $\beta$-SiC Powder Using Thermocycling Process," Adv. Appl. Ceram., 113, 352-357 (2014). crossref(new window)

Basso, S., Tessonnier, J.-P., Cuong, P.-H., Ledoux, M. J. and Wine, Gauthier, "Zeolite/SiC Composites and Their Use in Catalysis," US Patent 7,179,764.

Merle-Mejean, T., Abdelmounm̂ , E. and Quintard, P. "Oxide Layer on Silicon Carbide Powder: a FT-IR Investigation," J. Mol. Struc., 349, 105-108(1995). crossref(new window)

Kwon, W. T., Kim, S. R., Kim, Y., Lee, Y. J., Won, J., Park, W. K. and Oh, S. C., "Effect of Temperature and Carbon Contents on the Synthesis of $\beta$-SiC from Silicon Sludge by Direct Carbonization Method," Mater. Sci. Forum., 724, 45-48(2012). crossref(new window)

Shirazi, L., Jamshidi, E. and Ghasemi, M. R., "The Effect of Si/Al Ratio of ZSM-5 Zeolite on Its Morphology, Acidity and Crystal Size," Cryst. Res. Technol., 43, 1300-1306(2008). crossref(new window)

Nawaz, Z., Xiaoping, T. and Wei, F., "Influence of Operating Conditions, Si/Al Ratio and Doping of Zinc on Pt-Sn/ZSM-5 Catalyst for Propane Dehydrogenation to Propene," Korean J. Chem. Eng., 26, 1528-1532(2009). crossref(new window)

Kim, H. G., Yang, Y. C., Jeong, K. E., Kim, T. W., Jeong, S. Y., Kim, C. U., Jhung, S. H. and Lee, K. Y., "Effect of Metal Addition and Silica/Alumina Ratio of Zeolite on the Ethanol-to-Aromatics by Using Metal Supported ZSM-5 Catalyst," Korean Chem. Eng. Res., 51, 418-425(2013). crossref(new window)