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Oxidative Dehydrogenation of n-Butenes over BiFe0.65MoP0.1 Oxide Catalysts Prepared with Various Synthesis Method
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  • Journal title : Korean Chemical Engineering Research
  • Volume 53, Issue 3,  2015, pp.391-396
  • Publisher : The Korean Institute of Chemical Engineers
  • DOI : 10.9713/kcer.2015.53.3.391
 Title & Authors
Oxidative Dehydrogenation of n-Butenes over BiFe0.65MoP0.1 Oxide Catalysts Prepared with Various Synthesis Method
Park, Jung-Hyun; Shin, Chae-Ho;
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 Abstract
To investigate the effect of the catalyst synthesis method on the oxidative dehydrogenation (ODH) of nbutenes, oxide catalysts were prepared with various synthesis methods such as co-precipitation, citric acid method, hydrothermal method, and surfactant templated method. The catalysts were characterized by X-ray Diffraction (XRD), sorption, and -butene-temperature programmed desorption (-butene-TPD) to correlate with catalytic activity in ODH reaction. Among the catalysts studied here, oxide catalyst prepared with co-precipitation method marked the highest activity showing 1-butene conversion, 79.5%, butadiene selectivity, 85.1% and yield, 67.7% after reaction for 14 h. From the result of -TPD, the catalytic activity is closely related to the acidity of the -x oxide catalyst and acidity of the oxde catalyst prepared with co-precipitation method was higher than that of other catalysts. In addition, combined with the 1-butene TPD, the higher catalytic activity is closely related to the amount of weakly adsorbed intermediate (< ) and the desorbing temperature of strongly adsorbed intermediates (> ).
 Keywords
Oxide Catalyst;1,3-butadiene;Acidity;-TPD;1-butene-TPD;
 Language
Korean
 Cited by
1.
BiFe0.65MoP0.1 촉매 상에서 1-부텐의 산화탈수소화 반응 : 인 전구체의 영향,박정현;윤현기;신채호;

Korean Chemical Engineering Research, 2015. vol.53. 6, pp.824-830 crossref(new window)
1.
Catalyst: Effect of Phosphorous Precursors, Korean Chemical Engineering Research, 2015, 53, 6, 824  crossref(new windwow)
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