JOURNAL BROWSE
Search
Advanced SearchSearch Tips
Application of Emulsion Liquid Membrane to Removal of Fermentation Inhibitors from Simulated Hemicellulosic Hydrolysates
facebook(new window)  Pirnt(new window) E-mail(new window) Excel Download
  • Journal title : Korean Chemical Engineering Research
  • Volume 53, Issue 4,  2015, pp.457-462
  • Publisher : The Korean Institute of Chemical Engineers
  • DOI : 10.9713/kcer.2015.53.4.457
 Title & Authors
Application of Emulsion Liquid Membrane to Removal of Fermentation Inhibitors from Simulated Hemicellulosic Hydrolysates
Lee, Sang Cheol;
  PDF(new window)
 Abstract
Hemicellulosic hydrolysates contain not only sugars but also several kinds of ethanol fermentation inhibitory substances such as carboxylic acids, furans and phenolic compounds. In this work, emulsion liquid membrane (ELM) was chosen as a separation technology to remove the inhibitors. A basic simulated hemicellulosic hydrolysate was composed of xylose as sugar, dilute sulfuric acid solution as solvent, and acetic acid as carboxylic acid, and furfural as furan derivative or p-hydroxybenzoic acid(HBA) as phenolic compound was added to the hydrolysate when necessary. Acetic acid and HBA as weak acid could be selectively removed from the hydrolysates in all the ELM systems considered here, but furfural as aldehyde was quite hard to remove. Also, when HBA was added to the basic simulated hemicellulosic hydrolysate, both of acetic acid and HBA in the feed phase could be selectively removed up to 99% in an ELM system with tributyl phosphate as extractant.
 Keywords
Simulated Hemicellulosic Hydrolysate;Emulsion Liquid Membrane;Xylose;Fermentation Inhibitor;Extraction;
 Language
Korean
 Cited by
 References
1.
Park, Y. C. and Kim, J. S., "Enzymatic Hydrolysis Characteristics of Pretreated Rice Straw by Aqueous Ammonia for Bioethanol Production," Korean Chem. Eng. Res., 49(4), 470-474(2011). crossref(new window)

2.
Fernandes, M. C., Ferro, M. D., Paulino, A. F. C., Mendes, J. A. S., Gravitis, J., Evtuguin, D. V. and Xavier, A. M. R. B., "Enzymatic Saccharification and Bioethanol Production from Cynara cardunculus Pretreated by Steam Explosion," Bioresour. Technol., 186, 309-315(2015). crossref(new window)

3.
Novy, V., Longus, K. and Nidetzky, B., "From Wheat Straw to Bioethanol: Integrative Analysis of a Separate Hydrolysis and cofermentation Process with Implemented Enzyme Production," Biotechnol. Biofuels, 8(46), 1-12(2015). crossref(new window)

4.
Won, K. Y., Kim, Y. S. and Oh, K. K., "Comparison of Bioethanol Production of Simultaneous Saccharification & Fermentation and Separation Hydrolysis & Fermentation from Cellulose-rich Barley Straw," Korean J. Chem. Eng., 29(10), 1341-1346(2012). crossref(new window)

5.
Parajo, J. C., Dominguez, H. and Dominguez, J. M., "Biotechnological Production of Xylitol. Part 3: Operation in Culture Media Made from Lignocellose Hydrolysates," Bioresour. Technol., 66, 25-40(1998). crossref(new window)

6.
Grzenia, D. L., Schell, D. J. and Wickramasinghe, S. R., "Membrane Extraction for Removal of Acetic Acid from Biomass Hydrolysates," J. Membr. Sci., 322, 189-195(2008). crossref(new window)

7.
Nam, H. G., Jo, S. H. and Mun, S., "Comparison of Amberchrom-CG161C and Dowex99 as the Adsorbent of a Four-zone Simulated Moving Bed Process for Removal of Acetic Acid from Biomass Hydrolysate," Process Biochem., 46, 2044-2053(2011). crossref(new window)

8.
Wickramasinghe, S. R. and Grzenia, D. L., "Adsorptive Membranes and Resins for Acetic Acid Removal from Biomass Hydrolysates," Desalination, 234, 144-151(2008). crossref(new window)

9.
Schneider, H., "Selective Removal of Acetic Acid from Hardwood-spent Sulfite Liquor Using a Mutant Yeast," Enzyme Microb. Technol., 19, 94-98(1996). crossref(new window)

10.
Persson, P., Andersson, J., Gorton, L., Larsson, S., Nilvebrant, N. and Jönsson, L. J., "Effect of Different Forms of Alkali Treatment on Specific Fermentation Inhibitors and on Fermentability of Lignocellulose Hydrolysates for Production of Fuel Ethanol," J. Agric. Food Chem., 50, 5318-5325(2002). crossref(new window)

11.
Lee, S. C., "Purification of Xylose in Simulated Hemicellulosic Hydrolysates Using a Two-step Emulsion Liquid Membrane Process," Bioresour. Technol., 169, 692-699(2014). crossref(new window)

12.
Lee, J., An, J., Park, S., Kim, T., Kim, S., Lee, D., Lee, W., Son, D., Ji, S. and Lee, K., "An Entire Process for Purification of Xylose Including Electrodialysis & Crystallization," U.S. Patent No. 0211366(2012).

13.
Gaddy, J. L. and Clausen, E. C., "Method of Separation of Sugars and Concentrated Sulfuric Acid," U.S. Patent No. 4608245(1986).

14.
Neuman, R. P., Rudge, S. R. and Ladisch, M. R., "Sulfuric Acidsugar Separation by Ion Exclusion," React. Polym., 5, 55-61(1987).

15.
Lee, S. C., "Development of An Emulsion Liquid Membrane System for Removal of Acetic Acid from Xylose and Sulfuric Acid in a Simulated Hemicellulosic Hydrolysate," Sep. Purif. Technol., 118, 540-546(2013). crossref(new window)

16.
Lim, S. J. and Lee, S. C., "Effects of Main Constituents of w/o Ratio Emulsion on Removal of Acetic Acid in a Simulated Hemicellulosic Hydrolysate," Korean Chem. Eng. Res., 52(6), 789-795(2014). crossref(new window)

17.
Lee, S. C. and Hyun, K. S., "A Study on Reactive Extraction Equilibrium Between Acetic Acid and Bis-succinimide of C9232," Korean J. Chem. Eng., 30(7), 1454-1457(2013). crossref(new window)

18.
Perrin, D. D. and Dempsey, B., Buffers for pH and metal ion control, Chapman and Hall, London(1974).

19.
Lee, S. C., "Effect of Volume Ratio of Internal Aqueous Phase to Organic Membrane Phase (w/o ratio) of Water-in-oil Emulsion on Penicillin G Extraction by Emulsion Liquid Membrane," J. Membr. Sci., 163, 193-201(1999). crossref(new window)

20.
Sidiras, D., Batzias, F., Ranjan, R., Tsapatsis, M., "Simulation and Optimization of Batch Autohydrolysis of Wheat Straw to Monosaccharides and Oligosaccharides," Bioresour. Technol., 102, 10486-10492(2011). crossref(new window)

21.
Jacquet, N., Maniet, G., Vanderghem, C., Delvigne, F., Richel, A., "Application of Steam Explosion as Pretreatment on Lignocellulosic Material: A Review," Ind. Eng. Chem. Res., 54, 2593-2598(2015). crossref(new window)

22.
Sharma, L. N., "Identification and Quantification of Potential Fermentation Inhibitors in Biomass Pretreatment Hydrolysates Using HPLC in Combination with UV and Tandem MS," Ph.D Dissertation, Baylor University, Waco, Texas(2009).