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Electrochemical Analysis of the Electrodeposition of Platinum Nanoparticles
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  • Journal title : Korean Chemical Engineering Research
  • Volume 53, Issue 5,  2015, pp.540-544
  • Publisher : The Korean Institute of Chemical Engineers
  • DOI : 10.9713/kcer.2015.53.5.540
 Title & Authors
Electrochemical Analysis of the Electrodeposition of Platinum Nanoparticles
Lee, Hae-Min; Cho, Sung-Woon; Kim, Jun-Hyun; Kim, Chang-Koo;
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 Abstract
A bath for electrodeposition of platinum nanoparitcles on low-cost graphite substrates was developed to attach nanoparticles directly onto a substrate, and electrochemical characteristics of the electrodeposition of platinum nanoparticles were investigated. The reaction mechanism was examined by the analysis of polarization behavior. Cyclic voltammetry measurements revealed that the elecrodeposition of platinum nanoparticles was limited by mass transfer. The chronoamperometric study showed an instantaneous nucleation mechanism during the electrodeposition of platinum nanoparticles on graphite. Because graphite is much cheaper than other carbon-based substrates, the electrodeposition of platinum nanoparticles on the graphite is expected to have useful applications.
 Keywords
Electodeposition;Platinum Nanoparticle;Graphite Substrate;Reaction Mechanism;
 Language
Korean
 Cited by
 References
1.
Abeles, B., Sheng, P., Coutts, M. D. and Arie, Y., "Structural and Electrical Properties of Granular Metal Films," Adv. Phys., 24, 407-461(1975). crossref(new window)

2.
Lu, G. and Zangari, G., "Electrodeposition of Platinum on Highly Oriented Pyrolytic Graphite. Part I: Electrochemical Characterization," J. Phys. Chem. B, 109, 7998-8007(2005). crossref(new window)

3.
Lu, G. and Zangari, G., "Electrodeposition of Platinum Nanoparticles on Highly Oriented PyroliticGraphite Part II: Morphological Characterization by Atomic Force Microscopy," Electrochim. Acta, 51, 2531-2538(2006). crossref(new window)

4.
Duarte, M. M. E., Pilla, A. S., Sieben, J. M. and Mayer, C. E., "Platinum Particles Electrodeposition on Carbon Substrates," Electrochem. Commun., 8, 159-164(2006). crossref(new window)

5.
Tsai, M.-C.,Yeh, T.-K. and Tsai, C.-H., "An Improved EelectrodepositionTechnique for Preparing Platinum and Platinum-Ruthenium Nanoparticles on Carbon Nanotubes Directly Grown on Carbon Cloth for Methanol Oxidation," Electrochem. Commun., 8, 1445-1452(2006). crossref(new window)

6.
El-Deab, M. S. and Ohsaka, T., "Electrocatalysis by Nanoparticles: Oxygen Reduction on Gold Nanoparticles-Electrodeposited Platinum Electrodes," J. Electroanal. Chem., 553, 107-115(2003). crossref(new window)

7.
Naohara, H., Ye, S. and Uosaki, K., "Electrocatalytic Reactivity for Oxygen Reduction at Epitaxially Grown Pd Thin Layers of Various Thickness on Au(111) and Au(100)," Electrochim. Acta, 45, 3305-3309(2000). crossref(new window)

8.
Kim, K. M., Kang, K.-Y., Choi, M. G., and Lee, Y.-G., "Anode Properties of Sn-Ni Nanoparticle Composites for Rechargeable Lithium Batteries," Korean Chem. Eng. Res., 49, 846-850(2011). crossref(new window)

9.
Bae, E., Park, H. J., Yoon, J., Kim, Y., Choi, K. and Yi, J., "Bacterial uptake of Silver Nanoparticles in the Presence of Humic Acid and $AgNO_3$," Korean J. Chem. Eng., 28, 267-271(2011). crossref(new window)

10.
Guo, L., Liang, H., Xu, T., Li, C., Meng, Q., Liu, H. and Huang, Y., "A Facile Approach to Preparing Palladium Nanoparticlesembedded Polyvinylpyrrolidone (PVP) Heterogeneous Hybrid Nanofibers Mats by Electrospinning," Korean J. Chem. Eng., 30, 2142-2150(2013). crossref(new window)

11.
Wu, G., Li, L. and Xu, B.-Q., "Effect of Electrochemical Polarization of PtRu/C Catalysts on Methanol Electrooxidation," Electrochim. Acta, 50, 1-10(2004). crossref(new window)

12.
Oliveira, R. T. S., Santos, M. C., Marcussi, B. G., Nascente, P. A. P., Bulhoes, L. O. S. and Pereira, E. C., "The Use of a Metallic Bilayer for the Oxidation of Small Organic Molecules," J. Electroanal. Chem., 575, 177-182(2005). crossref(new window)

13.
Pingarron, J. M., Yanez-Sedeno, P. and Gonzalez-Cortes, A., "Gold Nanoparticle-Based Electrochemical Biosensors," Electrochim. Acta, 53, 5848-5866(2008). crossref(new window)

14.
Ramirez, E., Erades, L., Philippot, K., Lecante, P. and Chaudret, B., "Shape Control of Platinum Nanoparticles," Adv. Funct. Mater., 17, 2219-2228(2007). crossref(new window)

15.
Guo, D.-J. and Li, H.-L., "High Dispersion and Electrocatalytic Properties of Pt Nanoparticles on SWNT Bundles," J. Electroanal. Chem., 573, 197-202(2004).

16.
Feltham, A. M. and Spiro, M., "Platinized Platinum Electrodes," Chem. Rev., 71, 177-193(1971). crossref(new window)

17.
Bard, A. J. and Faulkner, L.R., Electrochemical. Methods: Fundametals and Applications, 2nd ed., John Wiley & Sons, Inc., Hobeken, NJ(2001).

18.
Scharifker, B. and Hills, G., "Theoretical and Experimental Studies of Multiple Nucleation," Electrochim. Acta, 28, 879-889(1983). crossref(new window)