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Surface Modification of Fine Particle by Plasma Grafting in a Circulating Fluidized Bed Reactor under Reduced Pressure
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  • Journal title : Korean Chemical Engineering Research
  • Volume 53, Issue 5,  2015, pp.614-619
  • Publisher : The Korean Institute of Chemical Engineers
  • DOI : 10.9713/kcer.2015.53.5.614
 Title & Authors
Surface Modification of Fine Particle by Plasma Grafting in a Circulating Fluidized Bed Reactor under Reduced Pressure
Park, Sounghee;
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A plasma surface modification of powders has been carried out in a circulating fluidized bed reactor under reduced pressure. Polystyrene (PS) particles treated by plasma are grafted with polyethylene glycol (PEG) on the surface. The virgin, plasma-treated and grafted powders were characterized by DPPH method, FTIR, SEM and contact angle meter. The plasma-treated PS powders have well formed peroxide on the surface, By PEG grafting polymerization, PEG is well grafted and dispersed on the surface of the plasma-treated PS powders. The PEG-g-PS particle was successfully synthesized using the plasma circulating fluidized bed reactor under reduced pressure.
Plasma;Surface Modification;Circulating Fluidized Bed;Polystyrene;Polyethylene Glycol;Grafting;
 Cited by
감압 순환유동층 플라즈마 반응기의 축방향 고체체류량,박성희;

Korean Chemical Engineering Research, 2016. vol.54. 4, pp.527-532 crossref(new window)
McGint, K. M. and Brittain, W. J., "Hydrophilic Surface Modification of Poly(vinyl chloride) Film and Tubing using Physisorbed Free Radical Grafting Technique," Polymer, 49, 4350-4357(2008). crossref(new window)

Nie, F. Q., Xu, Z. K., Ye, P., Wu, J. and Seta, P., "Acrylonitrile-based Copolymer Membranes Containing Reactive Groups: Effects of Surface-immobilized Poly(ethylene glycol)s on Anti-fouling Properties and Blood Compatibility," Polymer, 45, 399-407(2004). crossref(new window)

Park, B. D. and Lee, Y. S., "The Effect of PEG Groups on Swelling Properties of PEG Grafted-polystyrene Resins in Various Solvents," React. Funct. Polym., 44, 41-46(2000). crossref(new window)

Jo, S. and Park, K., "Surface Modification using Silanated Poly (ethylene glycol)s," Biomaterials, 21, 605-616(2000). crossref(new window)

Qui, Y. X., Klee, D., Pluster, W., Severich, B. and Hocker, H., "Surface Modification of Polyurethane by Plasma-Induced Graft Polymerization of Poly(ethy1ene glycol) Methacrylate," J. Appl. Polym. Sci., 61, 2372-2382(1996).

Suzuki, M., Kishida, A., Iwata, H. and Ikada, Y., "Graft Copolymerization of Acrylamide onto a Polyethylene Surface Pretreated with a Glow Discharge", Macromolecules, 19, 1804-1808(1986). crossref(new window)

Fujimoto, K., Takebayashi, Y., Inoue, H. and Ikada, "Ozone-Induced Graft Polymerization onto Polymer Surface," J. Polym. Sci. Pol. Chem., 31, 1035-1043(1993). crossref(new window)

Kim, H. Y. and Yashuda, H. K., "Improvement of Fatigue Properties of Poly(methyl methacrylate) Bone Cement by Means of Plasma Surface Treatment of Fillers," J. Biomed., Mater. Res., 48, 135-142(1999). crossref(new window)

Zhang, F., Kang, E. T., Neoh, K. G., Wang, P. and Tian, K. L., "Modification of Si(100) Surface by the Grafting of Poly(ethylene glycol) for Reduction in Protein Adsorption and Platelet Adhesion," J. Biomed. Mater. Res., 56, 324-332(2001). crossref(new window)

Yim, E. C., Kim, S. J., Oh, I. K. and Kee, C. D., "Plasma Surface Modification of Graphene and Combination with Bacteria Cellulose," Korean Chem. Eng. Res., 51, 388-393(2013). crossref(new window)

Yu, H. Y., Tiang, Z. Q., Huang, L., Gheng, G., Li, W., Zhou, J., Yan, M. G., Gu, J. S. and Wei, X. W., "Surface Modification of Polypropylene Macroporous Membrane to Improve Its Antifouling Characteristics in a Submerged Membrane Bioreactor: $H_2O$ Plasma Treatment," Water Res., 42, 4341-4347(2008). crossref(new window)

Gaiolas, C., Belgacem, M. N., Siva, L., Thielemans, W., Costa, A. P., Nunes, M. and Silva, M. J. S., "Green Chemicals and Process to Graft Cellulose Fibers," J. Colloid Interf. Sci., 330, 298-302(2009). crossref(new window)

Yasuda, H. and Yashuda, T., "The Competitive Ablation and Polymerization (CAP) Principle and the Plasma Sensitivity of Elements in Plasma Polymerization and Treatment," J. Polymer. Sci. Pol. Chem., 38, 943-953(2000). crossref(new window)

Ferrari, B., Herencia, A. J. S. and Moreno, R., "Electrophoretic Forming of $Al_2O_3$/Y-TZP Layered Ceramics From Aqueous Suspensions," Mater. Res. Bull., 33, 487-499(1998). crossref(new window)

Oh, S. M. and Park, D. W., "Preparation of Ultra-fine Alumina Powders by D. C. Plasma Jet," Korean J. Chem. Eng., 17, 299-303(2000). crossref(new window)

Jung, S. H., Park, S. H. and Kim, S. D., "Surface Treatment of Polymeric Fine Powders by CF4 Plasma in a Circlulating Fluidized Bed Reactor," J. Chem. Eng. Jap., 37, 166-173(2004). crossref(new window)

Jung, S. H., Park, S. H., Lee, D. H. and Kim, S. D., "Surface Modification of HDPE Powders by Oxygen Plasma in a Circulating Fluidized Bed Reactor," Polym. Bull., 47, 199-205(2001). crossref(new window)

Park, S. H. and Kim, S. D., "Oxygen Plasma Surface Treatment of Polymer Powder in a Fluidized Bed Reactor," Colloid Surface A., 133, 33-39(1998). crossref(new window)

Park, S. H. and Kim, S. D., "Plasma Surface treatment of HDPE Powder in a Fluidized Bed Reactor," Polym. Bull., 33, 249-256(1994). crossref(new window)

Gref, R., Luck, M., Quellec, P., Marchand, M., Dellacherie, D., Harnisch, S., Blunk, T. and Muller, R. H., "'Stealth' Corona-core Nanoparticles Surface Modified by Polyethylene Glycol (PEG): Influences of the Corona (PEG Chain Length and Surface Density) and of the Core Composition on Phagocytic Uptake and Plasma Protein Adsorption," Colloid Surface. B, 18, 301-313(2000). crossref(new window)

Feng, L. B., Zhou, S. X., You, B. and Wu, L. M., "Synthesis and Surface Properties of Polystyrene-graftpoly(ethylene glycol) Copolymers," J. Appl. Polym. Sci., 103, 1458-1465(2007). crossref(new window)

Appendini, P. and Hotchkiss, J. H., "Surface Modification of Poly(styrene) by the Attachment of an Antimicrobial Peptide," J. Appl. Polym. Sci., 81, 609-616(2001). crossref(new window)

Song, L. H., Park, S. H., Jung, S. H., Kim, S. D. and Park, S. B., "Synthesis of Polyethylene glycol-polystyrene Core-shell Structure Particles in a Plasma-fluidized Bed Reactor," Korean J. Chem. Eng., 28(2), 627-632(2011). crossref(new window)

Song, L. H., "Surface Modification of Polystyrene by Plasma Grafting of PEG in a Fluidized Bed Reactor," MS. Thesis, KAIST, Korea (2002).

Park, S. H., "Study on Plasma Surface Grafting Modification of Fine Particle in a Circulating Fluidized Bed Reactor," KOSEF report, R05-2002-000-0129-0(2004).

Lee, S. H., Hsiue, G. H., Kao, C. H. and Chang, P. C. T., "Artificial Cornea: Surface Modification of Silicone Rubber Membrane by Graft Polymerization of PHEMA via Glow Discharge," Biomaterials, 17, 587-595(1996). crossref(new window)