JOURNAL BROWSE
Search
Advanced SearchSearch Tips
Effect of Fabrication Method of Anode on Performance in Enzyme Fuel Cells
facebook(new window)  Pirnt(new window) E-mail(new window) Excel Download
  • Journal title : Korean Chemical Engineering Research
  • Volume 53, Issue 6,  2015, pp.667-671
  • Publisher : The Korean Institute of Chemical Engineers
  • DOI : 10.9713/kcer.2015.53.6.667
 Title & Authors
Effect of Fabrication Method of Anode on Performance in Enzyme Fuel Cells
Lee, Se-Hoon; Hwang, Byung-Chan; Lee, Hye-Ri; Kim, Young-Sook; Chu, Cheun-Ho; Na, Il-Chai; Park, Kwon-Pil;
  PDF(new window)
 Abstract
Enzyme fuel cells were operated with cells composed of enzyme anode and PEMFC cathode. Enzyme anodes was fabricated by compression of a mixture of graphite particle, glucose oxidase(Gox) as a enzyme and ferrocene as a redox mediator, and then coated with Nafion ionomer solution. Performances of enzyme unit cell were measured with variation of anode manufacture factors, to find optimum condition of enzyme anode. Optimum pressure was 8.89MPa for enzyme anode pressing process. Highest power density was obtained at 60% graphite composition in enzyme anode. Optimum glucose concentration was 1.7 mol/l in anode substrate solution. The enzyme anode was stabilized by two times of deeping in Nafion solution for 1 sec.
 Keywords
Enzyme fuel cells;Performance;Pressing Anode;Fabrication method;Glucose oxidase;Stability;
 Language
Korean
 Cited by
 References
1.
Heller, A., "Miniature Biofuel Cells," Physical Chemistry Chemical Physics, 6, 209-216(2004). crossref(new window)

2.
Mano, N., Mao, F. and Heller, A., "Characteristics of a Miniature Compartment-less Glucose-$O_2$ Biofuel Cell and Its Operation in a Living Plant," Journal of the American Chemical Society, 125, 6588-6594(2003). crossref(new window)

3.
Mano, N., Mao, F. and Heller, A., "A Miniature Biofuel Cell Operating in A Physiological Buffer," Journal of the American Chemical Society, 124, 12962-12963(2002). crossref(new window)

4.
Mano, N., Mao, F., Shin, W., Chen, T. and Heller, A., "A Miniature Biofuel Cell Operating at 0.78V," Chemical Communications, 518- 519(2003).

5.
Leech, D., Kavanagh, P. and Schuhmann, W., "Enzymatic Fuel Cells: Recent Progress," Electrochimica Acta, 84, 223-234(2012). crossref(new window)

6.
Yuhashi, N., Tomiyama, M., Okuda, J., Igarashi, S., Ikebukuro, K. and Sode, K., "Glucose of a Novel Glucose Enzyme Fuel Cell System Employing Protein Engineered PQQ Glucose Dehydrogenase," Biosensors and Bioelectronics, 20, 2145-2150(2005). crossref(new window)

7.
Jenkins, P., Tuurla, S., Vaari, A., Valkiainen, M., Smolander, M. and Leech, D., "A Mediated Glucose/oxygen Enzymatic Fuel Cell Based on Printed Carbon Inks Containing Aldose Dehydrogenase and Laccase as Anode and Cathode," Enzyme and Microbial Technology, 50, 181-187(2012). crossref(new window)

8.
Tsujimura, S., Kano, K. and Ikeda, T., "Glucose/$O_2$ Biofuel Cell Operating at Physiological Conditions," Electrochemistry, 70, 940 (2002).

9.
Sato, F., Togo, M., Islam, M. K., Matsue, T., Kosuge, J., Fukasaku, N., Kurosawa, S. and Nishizawa, M., "Enzyme-based Glucose Fuel Cell Using Vitamin K3-immobilized Polymer as an Electron Mediator," Electochemistry Communication, 7, 643-647(2005). crossref(new window)

10.
Kim, H., Lee, I., Kwon, Y., Kim, B., Ha, S., Lee, J.-H., Kim, J., "Immobilization of Glucose Oxidase Into Polyaniline Nanofiber Matrix for Biofuel Cell Applications," Biosensors and Bioelectronics, 26, 3908-3913(2011). crossref(new window)

11.
Cosnier, S., Shan, D., Ding, S. N., "An Easy Compartment-less Biofuel Cell Construction Based on the Physical co-inclusion of Enzyme and Mediator Redox Within Pressed Graphite Discs," Electrochemistry Communications, 12, 266-269(2010). crossref(new window)

12.
Zebda, A., Gondran, C., Cinquin, P. and Consier, S., "Glucose Biofuel Cell Construction Based on Enzyme, Graphite Particle and Redox Mediator Compression," Sensors and Actuators B, 173, 760-764(2012). crossref(new window)

13.
Song, J., Woo, M., Kim, K., Kim, S., Ahn, B., Lim, T. and Park, K. P., "Decrease of PEMFC Performance by Ion Contamination," Korean Chem. Eng. Res., 50, 187-190(2012). crossref(new window)

14.
Lee, H., Kim, T. H., Sim, W. J., Kim, S. H., Ahn, B. K., Lim, T. W. and Park, K. P., "Pinhole Formation in PEMFC Membrane After Electrochemical Degradation and Wet/dry Cycling Test," Korean J. Chem. Eng., 28, 487-491(2011). crossref(new window)

15.
Kim, Y. S., Lee, S. H., Chu, C. H., Na, I. C., Lee, H. and Park, K. P., "Effect of Fabrication Method of Anode on OCV in Enzyme Fuel Cells," Korean Chem. Eng. Res. in Print.