JOURNAL BROWSE
Search
Advanced SearchSearch Tips
Effect of Fabrication Method of Cathode on OCV in Enzyme Fuel Cells
facebook(new window)  Pirnt(new window) E-mail(new window) Excel Download
  • Journal title : Korean Chemical Engineering Research
  • Volume 54, Issue 2,  2016, pp.171-174
  • Publisher : The Korean Institute of Chemical Engineers
  • DOI : 10.9713/kcer.2016.54.2.171
 Title & Authors
Effect of Fabrication Method of Cathode on OCV in Enzyme Fuel Cells
Lee, Se-Hoon; Kim, Young-Sook; Chu, Cheun-Ho; Na, Il-Chai; Lee, Jung-Hoon; Park, Kwon-Pil;
  PDF(new window)
 Abstract
Enzyme fuel cells were composed of enzyme cathode and PEMFC anode. Enzyme cathode was fabricated by compression of a mixture of graphite particle, laccase as a enzyme and ABTS as a redox mediator, and then coated with Nafion ionomer. Open circuit voltage (OCV) were measured with variation of cathode manufacture factors, to find optimum condition of enzyme cathode. Optimum pressure was 4.0 bar for enzyme cathode pressing process. Highest OCV was obtained at 95% graphite composition in enzyme cathodee. Optimum glucose concentration was 0.4 mol/l in cathode substrate solution.
 Keywords
Enzyme fuel cells;OCV;Pressing cathode;Fabrication method;Laccase;
 Language
Korean
 Cited by
 References
1.
Bruce, E. L., Bert, H., Rene, R., Uwe, S., Jurg, K., Stefano, F., Peter, A., Willy, V. and Korneel, R., "Microbial Fuel Cells : Methodology and Technology," Environ. Sci. Technol., 40, 5181-5192(2006). crossref(new window)

2.
Adam, H., "Miniature Biofuel Cells," Physical Chemistry Chemical Physics, 6, 209-216(2004). crossref(new window)

3.
Nicolas, M., Fei, M. and Adam, H., "Characteristics of a Miniature Compartment-less Glucose-$O_2$ Biofuel Cell and Its Operation in a Living Plant," Journal of the American Chemical Society, 125, 6588-6594(2003). crossref(new window)

4.
Nicolas, M., Fei, M. and Adam, H., "A Miniature Biofuel Cell Operating in A Physiological Buffer," Journal of the American Chemical Society, 124, 12962-12963(2002). crossref(new window)

5.
Nicolas, M., Fei, M., Woonsup, S., Ting, C. and Adam, H., "A Miniature Biofuel Cell Operating at 0.78 V," Chemical Communications, 518-519(2003).

6.
Donal, L., Paul, K., Wolfgang, S., "Enzymatic Fuel Cells: Recent Progress," Electrochimica Acta, 84, 223-234(2012). crossref(new window)

7.
Bruce, E. L., "Microbial Fuel Cells," Wiley-Interscience(2007).

8.
Juozas, K., Regina, V. and Palle, S., "Laccase Catalyzed Oxidation of Naphthol in the Presence of Soluble Polymers," Enzyme and Microbial Technology, 32, 455-463(2003). crossref(new window)

9.
Noriko, Y., Masamitsu, T., Junko, O., Satoshi, I., Kazunori, I. and Koji, S., "Development of a Novel Glucose Enzyme Fuel Cell System Employing Protein Engineered PQQ Glucose Dehydrogenase," Biosensors and Bioelectronics, 20, 2145-2150 (2005). crossref(new window)

10.
Zebda, A., Gondran, C., Le Goff, A. and Holzinger, M., "Mediatorless High-power Glucose Biofuel Cells Based on Compressed Carbon Nanotube-enzyme Electrodes," Nat.Commun. 2, 1-6(2001).

11.
Ross, D. M., Fabien, G. and Alfred, E. T., "Glucose Oxidase Progressively Lowers Bilirubin Oxidase Bioelectrocatalytic Cathode Performance in Single-compartment Glucose/oxygen Biological Fuel Cells," Electrochimica Acta. 140, 59-64(2014). crossref(new window)

12.
Peter, J., Saara, T., Anu, V., Matti, V., Maria, S. and Donal, L., "A Mediated Glucose/oxygen Enzymatic Fuel Cell Based on Printed Carbon Inks Containing Aldose Dehydrogenase and Laccase as Anode and Cathode," Enzyme and Microbial Technology, 50, 181-187(2012). crossref(new window)

13.
Seiya, T., Kenji, K. and Tokuji, I., "Glucose/$O_2$, Biofuel Cell Operating at Physiological Conditions," Electrochemistry, 70, 940(2002).

14.
Fuyuki, S., Makoto, T., Mohammed, K. I., Tomokazu, M., Junichi, K., Noboru, F., Satoshi, K. and Matsuhiko, N., "Enzyme-based Glucose Fuel Cell Using Vitamin K3-immobilized Polymer as An Electron Mediator," Electochemistry Communication, 7, 643-647(2005). crossref(new window)

15.
Kim, H., Lee, I., Kwon, Y., Kim, B., Ha, S., Lee, J. and Kim, J., "Immobilization of Glucose Oxidase Into Polyaniline Nanofiber Matrix for Biofuel Cell Applications," Biosensors and Bioelectronics, 26, 3908-3913(2011). crossref(new window)

16.
Cosnier, S., Shan, D., Ding, S.-N., "An Easy Compartment-less Biofuel Cell Construction Based on the Physical co-inclusion of Enzyme and Mediator Redox Within Pressed Graphite Discs," Electrochemistry Communications, 12, 266-269(2010). crossref(new window)

17.
Abdelkader, Z., Chantal, G., Philippe, C. and Serge, C., "Glucose Biofuel Cell Construction Based on Enzyme, Graphite Particle and Redox Mediator Compression," Sensors and Actuators B, 173, 760-764(2012). crossref(new window)

18.
Luo, H., Jin, S., Fallgren, P. H., Park, H. J. and Johnson, P. A., "A Novel Laccase-catalyzed Cathode for Microbial Fuel Cells," Chemical Engineering Journal, 165, 524-528(2010). crossref(new window)

19.
Kim, Y. S., Lee, S. H., Chu, C. H., Na, I. C., Lee, H. and Park, K. P., "Effect of Fabrication Method of Anode on OCV in Enzyme Fuel Cells," Korean Chem. Eng. Res., 53, 6-10(2015). crossref(new window)

20.
Lee, H., Kim, T. H., Sim, W. J., Kim, S. H., Ahn, B. K., Lim, T. W. and Park, K. P., "Pinhole Formation in PEMFC Membrane After Electrochemical Degradation and Wet/dry Cycling Test," Korean J. Chem. Eng., 28, 487-491(2011). crossref(new window)