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Preparation of Electrically Conductive Composites Filled with Nickel Powder and MWCNT Fillers
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  • Journal title : Korean Chemical Engineering Research
  • Volume 54, Issue 3,  2016, pp.410-418
  • Publisher : The Korean Institute of Chemical Engineers
  • DOI : 10.9713/kcer.2016.54.3.410
 Title & Authors
Preparation of Electrically Conductive Composites Filled with Nickel Powder and MWCNT Fillers
Kim, Sunghoon; Park, Seonghwan; Kwon, Jaebeom; Ha, KiRyong;
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In this study, we prepared electrically conducting composites using epoxy resin of diglycidyl ether of bisphenol A (DGEBA) as a matrix, triethylenetetramine (TETA) as a hardener and nickel powder or multi-walled carbon nanotubes (MWCNTs) grafted with groups (MWCNT-) as electrically conducting fillers. Electrical conductivity of composite films were measured by coating on the slide glass with a doctor blade. We measured modification reactions of MWCNT and reaction of MWCNT- with DGEBA epoxy resin by fourier transform infrared spectrometer (FTIR), thermogravimetric analyzer (TGA) and elemental analyzer (EA). Morphology of composites was investigated by scanning electron microscope (SEM) and sheet resistances of composites were measured by 4-point probe. We found of sheet resistance for epoxy composite containing both 40 wt% nickel powder and 0.5 wt% of MWCNT- as fillers, equivalent to epoxy composite containing 53.3 wt% nickel powder only as a filler.
Diglycidyl ether of bisphenol A (DGEBA);Surface modification;MWCNT;Nanocomposite;Sheet resistance;
 Cited by
Shin, H. B., Kim, T. J. and Rhee, B. S., "Effects of Fiber Orientation on Reflectivity and Transmittivity of Microwave for Carbon Fiber Reinforced Epoxy Composites," Korean Chem. Eng. Res., 35(5), 667-672(1997).

Park, H. S., "Study about the In-situ Synthesis and Structure Control of Multi-walled Carbon Nanotubes and their Nanocomposites," Korean Chem. Eng. Res., 50(4), 729-732(2012). crossref(new window)

Kim, S. W., "Preparation and Characteristics of Biodegradable Polyurethane/Clay Nanocomposite Films," Korean Chem. Eng. Res., 51(3), 382-387(2013). crossref(new window)

Kang, C. S., Jee, M. H. and Baik, D. H., "Mechanical and Electrical Properties of Polyurethane Hybrid Nanocomposites Containing MWNT and Graphite as Conducting Nanoparticles," Textile Science and Engineering, 49(3), 174-180(2012). crossref(new window)

Kim, D. Y., Yun, K. J. and Lee, Y. S., "Electromagnetic Interference Shielding Characteristics of Electroless Nickel Plated Carbon Nanotubes," Appl. Chem. Eng., 25(3), 268-273(2014). crossref(new window)

Heo, S. I., Yun, J. C., Oh, K. S. and Han, K. S., "Electrical and the Mechanical Properties of Graphite Particle/carbon Fiber Hybrid Conductive Polymer Composites," Journal of the Korean Society for Composite Materials, 19(2), 7-12(2006).

Kim, J. B., Lee, S. K. and Kim, C. G., "A study on Carbon Nano Materials as Conductive Fillers for Microwave Absorbers," Journal of the Korean Society for Composite Materials, 19(5), 28-33(2006).

Lee, J. I. and Jung, H. T., "Technical Status of Carbon Nanotubes Composites," Korean Chem. Eng. Res., 46(1), 7-14 (2008).

Ryu, J. H. and Nam, B. U., "Dispersibility of Multi-walled Carbon Nanotubes Functionalized with Butyl and Hexyl Group," Journal of the Korea Academia-Industrial cooperation Society, 11(7), 2713-2718(2010). crossref(new window)

Kim, S. H., Park, S. H., Kwon, J. B. and Ha, K. R., "Optimum Conditions for Introducing Free Radical Polymerizable Methacrylate Groups on the MWCNT Surface by Michael Addition Reaction," Korean Chem. Eng. Res., 53(1), 83-90(2015). crossref(new window)

Kim, J., Im, H. and Kim, J., "The Effect of Surface Modification on the Disperisibilities and the Thermal Conductivities of Single-Walled Carbon Nanotube (SWCNT)/Epoxy Composites," Appl. Chem. Eng., 22(3), 266-271(2011).

Seo, M. K. and Park, S. J., "Studies on Thermal and Dynamic Viscoelastic Behaviors of Multiwalled Carbon Nanotubes-reinforced Epoxy Matrix Composites," Korean Chem. Eng. Res., 43(3), 401-406(2005).

Allaois, A., Bai, S., Cheng, H. M., and Bai, J. B., "Mechanical and Electrical Properties of a MWNT/epoxy Composite," Composites Science and Technology, 62(15), 1993-1998(2002). crossref(new window)

Myung, I. H., Chung, I. J. and Lee, J. R., "Chemo-mechanical Analysis of Bifunctional Linear DGEBA/Linear Amine Resin Casting Systems," Polymer(Korea), 24(2), 201-210(2000).

Liu, Y. and Gao, L, "A Study of the Electrical Properties of Carbon Nanotube-$NiFe_2O_4$ Composites: Effect of the Surface Treatment of the Carbon Nanotube," Carbon, 43(1), 47-52(2005). crossref(new window)

Mira, I. A. and Kumara, D., "Carbon Nanotube-filled Conductive Adhesives for Electronic Applications," Nanoscience Methods, 1(1), 183-193(2012). crossref(new window)

Oh, D. H., Lim, D. J., Lee, J. E., Park, Y. H. and Oh, S. M., "Electrical Properties of Conductive Nickel Powder-Epoxy Resin Composites," J. Korean Oil Chemists' Soc., 31(2), 329-336(2014). crossref(new window)

Shahzad, M., Giorcelli, M., Shahzad, N., Guastella, S., Castellino, M., Jagdale, P. and Tagliaferro, A., "Study of Carbon Nanotubes Base Polydimethylsiloxane Composite Films," Journal of Physics: Conference Series, 439(1), 1-7(2013).

d'Almeida, J., Menezes, G. and Monteiro, S., "Ageing of the DGEBA/TETA Epoxy System with off-Stoichiometric Compositions," Materials Research, 6(3), 415-420(2003). crossref(new window)

Rosu, D., Cascaval, C. N., Mustata, F. and Ciobanu, C., "Cure Kinetics of Epoxy Resins Studied by Non-isothermal DSC Data," Thermochimica Acta, 383(1-2), 119-127(2002). crossref(new window)

Brown, J., Rhoney, I. and Pethrick, R. A., "Epoxy Resin Based Nanocomposites: 1. Diglycidylether of Bisphenol A (DGEBA) with Triethylenetetramine (TETA)," Polym. Int., 53(12), 2130-2137 (2004). crossref(new window)

Vignoud, L., David, L., Sixou, B. and Vigier, G., "Influence of Electron Irradiation on the Mobility and on the Mechanical Properties of DGEBA/TETA Epoxy Resins," Polymer, 42(10), 4657-4665 (2001). crossref(new window)

Benard, F., Campistron, I., Laguerre, A., Vigier, G. and Laval, F., "Influence of Silica Fillers During the Electron Irradiation of DGEBA/TETA Epoxy Resins, Part II: Study of the Thermomechanical Properties," Polymer Degradation and Stability, 91(9), 2199-2125 (2006).

Gonzalez, M. G., Cabanelas, J. C. and Baselga, J. in Theophile, T., Materials Science, Engineering and Technology: Applications of FTIR on Epoxy Resins - Identification, Monitoring the Curing Process, Phase Separation and Water Uptake, InTech, Croatia, 265-269(2012).

Silva, W. M., Ribeiro, H., Seara. L. M., Calado, H. D. R., Ferlauto, A. S., Paniago, R. M., Leitec, C. F. and Silva, G. G., "Surface Properties of Oxidized and Aminated Multi-Walled Carbon Nanotubes," J. Braz. Chem. Soc., 23(6), 1078-1086(2012). crossref(new window)

Yang, K. and Gu, M., "The Effects of Triethylenetetramine Grafting of Multi-Walled Carbon Nanotubes on Its Dispersion, Filler-Matrix Interfacial Interaction and the Thermal Properties of Epoxy Nanocomposites," Polym. Eng. Sci., 49(11), 2158-2167(2009). crossref(new window)

Shokralla, S. A. and Al-Muaikel, "Thermal Properties of Epoxy (Dgeba)/phenolic Resin (Novolac) Blends," The Arabian Journal for Science and Engineering, 35(1B), 7-14(2010).

Gojny, F. H., Wichmann, M. H. G., Fiedler, B., Kinloch, I. A., Bauhofer, W., Windle, A. H. and Schulte, K., "Evaluation and Indentification of Electracal and Thermal Conduction Mechanisms in Carbon Nanotube/epoxy Composites," Polymer, 47(6), 2036-2045(2006). crossref(new window)

Kim, J. A., Seong, D. G., Kang, T. J. and Youn, J. R., "Effects of Surface Modification on Rheological and Mechanical Properties of CNT/epoxy Composites," Carbon, 44(10), 1898-1905(2006). crossref(new window)