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Benzyl Alcohol Oxidation over H5PMo10V2O40 Catalyst Chemically Immobilized on Sulfur-containing Mesoporous Carbon
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  • Journal title : Korean Chemical Engineering Research
  • Volume 54, Issue 3,  2016, pp.419-424
  • Publisher : The Korean Institute of Chemical Engineers
  • DOI : 10.9713/kcer.2016.54.3.419
 Title & Authors
Benzyl Alcohol Oxidation over H5PMo10V2O40 Catalyst Chemically Immobilized on Sulfur-containing Mesoporous Carbon
Gim, Min Yeong; Kang, Tae Hun; Choi, Jung Ho; Song, In Kyu;
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() catalyst chemically immobilized on sulfur-containing mesoporous carbon (S-MC) was prepared, and it was applied to the benzyl alcohol oxidation reaction. S-MC was synthesized by a templating method using SBA-15 and p-toluenesulfonic acid as a templating agent and a carbon precursor, respectively. S-MC was then modified to have a positive charge, and thus, to provide sites for the immobilization of . By taking advantage of the overall negative charge of , catalyst was immobilized on the S-MC support as a charge matching component. It was revealed that species were finely and molecularly dispersed on the S-MC via chemical immobilization. In the vapor-phase oxidation of benzyl alcohol, /S-MC catalyst showed higher conversion of benzyl alcohol and higher yield for benzaldehyde and benzoic acid than unsupported catalyst. The enhanced catalytic performance of /S-MC was due to fine dispersion of species on the S-MC via chemical immobilization.
Heteropolyacid catalyst;Sulfur-containing mesoporous carbon;Chemical immobilization;Benzyl alcohol oxidation;
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