Advanced SearchSearch Tips
Electrochemical Characteristics of Porous Silicon/Carbon Composite Anode Using Spherical Nano Silica
facebook(new window)  Pirnt(new window) E-mail(new window) Excel Download
  • Journal title : Korean Chemical Engineering Research
  • Volume 54, Issue 4,  2016, pp.459-464
  • Publisher : The Korean Institute of Chemical Engineers
  • DOI : 10.9713/kcer.2016.54.4.459
 Title & Authors
Electrochemical Characteristics of Porous Silicon/Carbon Composite Anode Using Spherical Nano Silica
Lee, Ho Yong; Lee, Jong Dae;
  PDF(new window)
In this study, the electrochemical characteristics of porous silicon/carbon composite anode were investigated to improve the cycle stability and rate performance in lithium ion batteries. In this study, the effect of TEOS and concentration, mixing speed and temperature on particle size of nano silica was investigated using method. Nano porous Si/C composites were prepared by the fabrication processes including the synthesis of nano , magnesiothermic reduction of nano to obtain nano porous Si by HCl etching, and carbonization of phenolic resin. Also the electrochemical performances of nano porous Si/C composites as the anode were performed by constant current charge/discharge test, cyclic voltammetry and impedance tests in the electrolyte of dissolved inorganic solvents (EC:DMC:EMC
method;Nano Silica;Porous Silicon;Anode;Lithium ion battery;
 Cited by
Jeon, B. J., Kang, S. W. and Lee, J. K., "Electrochemical Characteristics of Silicon Coated Graphite Prepared by Gas Suspension Spray Method for Anode Material of Lithium Secondary Batteries," Korean J. Chem. Eng., 23(5), 854-859 (2006). crossref(new window)

Park, J. Y. and Lee, J. D., "Electrochemical Characteristics of Silicon/Carbon Composites with CNT for Anode Material," Korean Chem. Eng. Res., 54(1), 16-21(2016). crossref(new window)

Ma, C., Ma, C., Wang, J., Wang, H., Shi, J., Song, Y., Guo, Q. and Liu, L., "Exfoliated Graphite as a Flexible and Conductive Support for Si-based Li-ion Battery Anodes," Carbon, 72, 38-46(2014). crossref(new window)

Ko, H. S., Choi, J. E. and Lee, J. D., "Electrochemical Characteristics of Lithium Ion Battery Anode Materials of Graphite/$SiO_2$," Appl. Chem. Eng., 25(6), 592-597(2014). crossref(new window)

Zheng, Y., Yang, J., Wang, J. and NuLi, Y., "Nano-porous Si/C Composites for Anode Material of Lithium-ion Batteries," Electrochimica Acta 52, 5863-5867(2007). crossref(new window)

Lv, P., Zhao, H., Gao, C., Zhang, T. and Liu, X., "Highly Efficient and Scalable Synthesis of $SiO_x$/C Composite with Core-shell Nanostructure as High-performance Anode Material for Lithium ion Batteries," Electrochimica Acta, 152, 345-351(2015). crossref(new window)

Zhou, R., Fan, R., Tian, Z., Zhou, Y., Guo, H., Kou, L. and Zhang, D., "Preparation and Characterization of Core Shell Structure Si/C Composite with Multiple Carbon Phases as Anode Materials for Lithium ion Batteries," Journal of Alloys and Compounds, 658, 91-97(2016). crossref(new window)

Yuan, Q., Zhao, F., Zhao, Y., Liang, Z. and Yan, D., "Evaluation and Performance Improvement of Si/SiOx/C Based Composite as Anode Material for Lithium ion Batteries," Electrochimica Acta, 115, 16-21(2014). crossref(new window)

Ma, X., Liu, M., Gan, L., Tripathi, P. K., Zhao, Y., Zhu, D., Xu, Z. and Chen, L., "Novel Mesoporous Si@C Microspheres as Anodes for Lithium-ion Batteries," Phys. Chem. Chem. Phys., 16, 4135-4142(2014). crossref(new window)

Stober, W., Fink, A. and Bohn, E., "Controlled Growth of Monodisperse Silica Spheres in the Micron Size Range," Journal of Colloid and Interface Science, 26, 62-69(1968). crossref(new window)

Green, D. L., Jayasundara, S., Lam, Y. F. and Harris, M. T., "Chemical Reaction Kinetics Leading to the First Stober Silica Nanoparticles - NMR and SAXS Investigation," Journal of Non-Crystalline Solids, 315, 166-179(2003). crossref(new window)

Sada, E., Kumazawa, H. and Koresawa, E., "Reaction Kinetics and Size Control in the Formation of Monosized Silica Spheres by Controlled Hydrolysis of Tetraethyl Orthosilicate in Ethanol," The Chemical Engineering Journal, 44(3), 133-139(2003).

Hwa, Y., Kim, W. S., Yu, B. C., Kim, J. H., Hong, S. H. and Sohn, H. J., "Facile Synthesis of Si Nanoparticles Using Magnesium Silicide Reduction and Its Carbon Composite as a High-performance Anode for Li ion Batteries," Journal of Power Sources, 252, 144-149(2014). crossref(new window)

Tao, H. C., Fan, L. Z. and Qu, X., "Facile Synthesis of Ordered Porous Si@C Nanorods as Anode Materials for Li-ion Batteries," Electrochimica Acta, 71 194-200(2012). crossref(new window)

Zhang, Y., Jiang, Y., Li, Y., Li, B., Li, Z. and Niu, C., "Preparation of Nanographite Sheets Supported Si Nanoparticles by in Situ Reduction of Fumed $SiO_2$ with Magnesium for Lithium ion Battery," Journal of Power Sources, 281, 425-431(2015). crossref(new window)

Wu, X., Wang, Z., Chen, L. and Huang, X., "Ag-enhanced SEI Formation on Si Particles for Lithium Batteries," Electrochem. Commun., 5, 935-939(2003). crossref(new window)