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Effect of Initiator on Performance of Polyvinylacetate as Emulsion Adhesive
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  • Journal title : Elastomers and Composites
  • Volume 50, Issue 4,  2015, pp.286-291
  • Publisher : The Rubber Society of Korea
  • DOI : 10.7473/EC.2015.50.4.286
 Title & Authors
Effect of Initiator on Performance of Polyvinylacetate as Emulsion Adhesive
Lee, Kangseok; Shim, Sang Eun;
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 Abstract
Polyvinylacetate (PVAc) was prepared using thermal initiation and redox initiation via emulsion polymerization at . The polymerization conditions had a significant effect on the properties of the synthesized PVAc. When hydrogen peroxide and tartaric acid as the initiator for redox polymerization were used, the synthesized PVAc had a low molecular weight. In comparison with thermal polymerization, smaller PVAc particles were formed during the redox polymerization due to relatively faster polymerization rate, which in turn resulted in improved adhesion property. It is considered that the rapid generation of smaller particles induces the formation of a large surface area.
 Keywords
polyvinylacetate;thermal initiation;redox initiation;emulsion polymerization;adhesive;
 Language
Korean
 Cited by
 References
1.
J. W. McBain and D. G. Hopkins, "On adhesives and adhesive action", J. Phys. Chem., 29, 88 (1925).

2.
P. J. Hine, S. El Muddarris, and D. E. Packham, "Surface pretreatment of zinc and its adhesion to epoxy resins", J. Adhesi., 17, 207 (1984). crossref(new window)

3.
A. N. Gent and J. Schultz, "Effect of wetting liquids on the strength of adhesion of viscoelastic material", J. Adhes., 3, 281 (1972). crossref(new window)

4.
N. H. Ladizesky and I. M. Ward, "A study of the adhesion of drawn polyethylene fibre/polymeric resin systems", J. Mater. Sci., 18, 533(1983) crossref(new window)

5.
M. Nardin and I. M. Ward, "Influence of surface treatment on adhesion of polyethylene fibres", Mater. Sci. Technol., 3, 814 (1987). crossref(new window)

6.
N. H. Ladizesky and I. M. Ward, "The adhesion behaviour of high modulus polyethylene fibres following plasma and chemical treatment", J. Mater. Sci., 24, 3763 (1989). crossref(new window)

7.
L. H. Sharpe and H. Schonhorn, "Surface tension of molten polypropylene", Chem. Eng. News, 15, 67 (1963).

8.
F. M. Fowkes, "Attractive forces at interfaces", Ind. Eng. Chem., 56, 40 (1964).

9.
F. M. Fowakes and M. A. Mostafa, "Acid-base interactions in polymer adsorption", Ind. Eng. Chem. Prod. Res. Dev., 17, 3 (1978). crossref(new window)

10.
S. S. Voyutskii, Autohesion and Adhesion of High Polymers, Wiley-Interscience, New York (1963).

11.
R. M. Vasenin and A.Ye. Chalykh, "Diffusion and viscosity in polymer-solvent systems", Polym. Sci. U.S.S.R., 8, 2311 (1966). crossref(new window)

12.
A. Pizzi and K. L. Mittal, Handbook of Adhesive Technology, Marcel Dekker Inc., New York (2003).

13.
J. M. Blakely, Surface Physics of Materials: Materials Science and Technology, Academic Press, London (1975).

14.
A. J. Kinloch, Adhesion and Adhesives Science and Technology, Springer Science & Business Media, Netherlands (1987).

15.
L. H. Lee, Fundamentals of Adhesion, Springer Science & Business Media, New York (1991).

16.
J. J. Bikerman, The Science of Adhesive Joints, Academic Press, New York (1968).

17.
A. T. Hubbard, Encyclopedia of Surface and Colloid Science, Marcel Dekker Inc., New York (2002).

18.
S. Shin and M. S. El-Aasser, "Preparation and morphological characterization of microscopic composite particles", J. Polym. Sci., Part A: Polym. Chem., 29, 857 (1991).

19.
W. D. Harkins, "A General Theory of the Mechanism of Emulsion Polymerization", J. Am. Chem. Soc., 69, 1428 (1947). crossref(new window)

20.
W. V. Smith and R. H. Ewart, "Kinetics of Emulsion Polymerization", J. Chem. Phys., 16, 592 (1948). crossref(new window)

21.
R. M. Fitch, M. B. Preosil, and K. J. Sprick, "The mechanism of particle formation in polymer hydrosols. I. kinetics of aqueous polymerization of methyl methacrylate", J. Polym. Sci., 27, 95 (1969).

22.
F. K. Hansen and J. Ugelstad, "Particle nucleation in emulsion polymerization. I. A theory for homogeneous nucleation", J. Polym. Sci. Polym. Chem., 16, 1953 (1978). crossref(new window)

23.
C. P. Roe, "Surface chemistry aspects of emulsion polymerization", Ind. Eng. Chem., 60, 20 (1968).

24.
F. K. Hansen and J. Ugelstad, "The effect of desorption in micellar particle nucleation in emulsion polymerization", Makromol. Chem., 180, 2423 (1979). crossref(new window)

25.
R. L. Zollar, "Kinetics of the emulsion polymerization of vinyl acetate", J. Appl. Polym. Sci., 24, 1353 (1979). crossref(new window)

26.
M. M. Rieger and L. D. Rhein, Surfactants in Cosmetics, Marcel Dekker Inc., New York (1985).

27.
A. Datyner, Surfactants in Textile Processing, Marcel Dekker Inc., New York (1983).

28.
D. Zou, V. Derlich, K. Gandhi, M. Park, L. Sun, D. Kriz, Y. D. Lee, G. Kim, J. J. Aklonis, and R. Salovey, "Model filled polymers. I. Synthesis of crosslinked monodisperse polystyrene beads", J. Polym. Sci.: Polym. Chem., 28, 1909 (1990).