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Analysis of Poly(Ethylene-co-Vinyl Acetate) Using Off-line Pyrolysis
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  • Journal title : Elastomers and Composites
  • Volume 51, Issue 1,  2016, pp.63-67
  • Publisher : The Rubber Society of Korea
  • DOI : 10.7473/EC.2016.51.1.63
 Title & Authors
Analysis of Poly(Ethylene-co-Vinyl Acetate) Using Off-line Pyrolysis
Choi, Sung-Seen; Kim, Eunha;
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 Abstract
Poly(ethylene-co-vinyl acetate) (EVA) was pyrolyzed to eliminate acetic acid of VA unit using off-line pyrolysis, and the deacetylated EVA was analyzed infrared spectroscopy (IR) and pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS). EVA film for deacetylation was prepared by solution casting on aluminum foil and it was pyrolyzed at low temperature of in the off-line pyrolysis apparatus. After deacetylation, carbon-carbon double bond (C
 Keywords
EVA;analysis;off-line pyrolysis;IR;Py-GC/MS;
 Language
Korean
 Cited by
1.
Novel analytical method for determination of contents of backbone and terminal/branch vinyl acetate groups of poly(ethylene-co-vinyl acetate) using deacetylation reaction, Polymer Testing, 2016, 56, 214  crossref(new windwow)
 References
1.
"Standard test method for determination of the vinyl acetate content of ethylene-vinyl acetate (EVA) copolymers by Fourier transform infrared spectroscopy (FT-IR)", ASTM D5594-98 (2012).

2.
E. Kim and S.-S. Choi, "Comparison of vinyl acetate contents of poly(ethylene-co-vinyl acetate) analyzed by IR, NMR, and TGA", Elast. Compos., 50, 18 (2015). crossref(new window)

3.
R. J. Koopmans, R. van der Linden, and E. F. Vansnat, "The characterisation of newly developed and promising hydrolyzed ethylene vinyl acetate copolymers", J. Adhes., 11, 191 (1980). crossref(new window)

4.
G. Meszlenyi and G. Kortvelyessy, "Direct determination of vinyl acetate content of ethylene vinyl acetate copolymers in thick films by infrared spectroscopy", Polym. Test., 18, 551 (1999). crossref(new window)

5.
I. Poljansek, E. Fadjan, K. Burja, and D. Kukanja, "Emulsion copolymerization of vinyl acetate-ethylene in high pressure reactor-characterization by inline FTIR spectroscopy", Prog. Org. Coat., 76, 1798 (2013). crossref(new window)

6.
Z. Wenwei, Z. Xiaoguang, Y. Li, Z. Yuefang, and S. Jiazhen, "Determination of the vinyl acetate content in ethylene-vinyl acetate copolymers by thermogravimetric analysis", Polymer, 35, 3348 (1994). crossref(new window)

7.
B. J. McGrattan, "Examining the decomposition of ethylene-vinyl acetate copolymers using TG/GC/IR", Appl. Spectrosc., 48, 1472 (1994). crossref(new window)

8.
A. Marcilla, A. Gomez, and S. Menargues, "TG/FTIR study of the thermal pyrolysis of EVA copolymers", J. Anal. Appl. Pyrolysis, 74, 224 (2005). crossref(new window)

9.
N. S. Allen, M. Edge, M. Rodriguez, C. M. Liauw, and E. Fontan, "Aspects of the thermal oxidation of ethylene vinyl acetate copolymer", Polym. Degrad. Stab., 68, 363 (2000). crossref(new window)

10.
ISO 21561:2005, "Styrene-butadiene rubber (SBR) -- Determination of the microstructure of solution-polymerized SBR".

11.
S.-S. Choi, Y. Kim, and H.-M. Kwon, "Microstructural analysis and cis-trans isomerization of BR and SBR vulcanizates reinforced with silica and carbon black using NMR and IR", RSC Adv., 4, 31113 (2014). crossref(new window)

12.
E. Kim and S.-S. Choi, "Photooxidation of BR vulcanizate using high pressure mercury lamp", Elast. Compos., 50, 1 (2015). crossref(new window)