Advanced SearchSearch Tips
Synthesis of Copoly(amide-imide)s Based on Silica Nano Particles-polyacrylamide
facebook(new window)  Pirnt(new window) E-mail(new window) Excel Download
  • Journal title : Elastomers and Composites
  • Volume 51, Issue 2,  2016, pp.138-146
  • Publisher : The Rubber Society of Korea
  • DOI : 10.7473/EC.2016.51.2.138
 Title & Authors
Synthesis of Copoly(amide-imide)s Based on Silica Nano Particles-polyacrylamide
Min, Jun Ho; Park, Chan Young; Min, Seong Kee;
  PDF(new window)
It is an inconvenience for silica nano-particles to dry again when using it in that they cohere each other through moisture in the air. Acrylamide groups were introduced to improve such inconvenience and copolymerized with silica nano-particles and then we copolymerized again with polyamic acid in order to increase thermal characteristic. Amide block copolymers were prepared using silica and (3-mercaptopropyl) trimethoxysilane (MPTMS) with a siloxane group, using 2,6-Lutidine as a catalyst. Amide block polymers and copolymers were synthesized via ATRP after brominating pyromellitic dianhydride (PMDA) and polyamic acid of methylene diphenyl diamine (MDA), using -bromo isobutyryl bromide. Characteristic peaks of copolymer with amide and imide groups and patterns of amorphous polymers were researched by FT-IR and XRD analyses and the analysis of surface characteristic groups was conducted via XPS. A change in thermal properties was examined through DSC and TGA and solubility for solvents was also researched.
PAI;poly(amic acid);siloxane group;DABCO;MPTMS;
 Cited by
P. A. Lovell and M. S. El-Aasser, In "Emulsion polymerization and Emulsion polymer", Wiley, New York (1997).

W. C. Bigelow, D. L. Pickett, and W. A. Zisman, "Self-assembly at solid surfaces", J. Colloid Interface Sci., 1, 513 (1946). crossref(new window)

J. J. Sagiv, "Organized monolayers by adsorption. 1. Formation and structure of oleophobic mixed monolayers on solid surfaces", Am. Chem. Soc., 102, 92 (1980). crossref(new window)

R. G. Nuzzo and D. L. J. Allora, "Self-assemblede monolayers containing ${\omega}$-mercaptoalkylboronic acids adsorbed onto gold form a highly cross-linked, thermally stable borate glass surface", Am. Chem. Soc., 105, 4481 (1983). crossref(new window)

K. G. Das, Controlled Release Technology, Bioengineering Aspects, Wiley, New York (1983).

Y. Haga, S. Inoue, T. Sato, and R. Yosomiya, "Photoconductivity properties of zinc oxide encapsulated in polymers", Angew. Makromol. Chem., 139, 49 (1986). crossref(new window)

G. Mayes and K. Mosbach, "Molecularly imprinted polymers: useful materials for analytical chemistry?", Trends Anal. Chem., 16, 321 (1997). crossref(new window)

B. Sellergren, C. Dauwe, and T. Schneider, "Monolithic materials: Preparation, properties and applications", Macromolecules, 30, 2454 (1997). crossref(new window)

M. Takenaga, Y. Serizawa, Y. Azechi, A. Ochiai, Y. Kosaka, R. Igarashi, and Y. Mizushima, "Synthesis of highlt cross-linked polymers in supercritical carbon dioxide by heterogeneous polymerization", J. Control Release., 52, 81 (1998). crossref(new window)

C. Gauthier, G. Thollet, G. Vigier, E. Bourgeat-Lami, and A. Guyot, "Transmission electron microscopy observations of composite polymer colloid nucleated by functionalized silica", Polym. Adv. Technol., 6, 345 (2003).

G. Laruelle, J. Parvole, J. Francois, and L. Billon, "Block copolymer grafted-silica particles: a core/double shell hybrid inorganic/organic material", Polymer, 45, 5013 (2004). crossref(new window)

I. Sondi, T. H. Fedynyshyn, R. Sinta, and E. Matijevic, "Colloidal polymers: synthesis and characterization", Langmuir, 16, 9031 (2000). crossref(new window)

Z. Z. Yang and D. Qiu, "Functional coatings: by polymer microencapsulation", Macromol. Rapid Commun., 23, 479 (2002). crossref(new window)

S. W. Zhang, S. X. Zhou, Y. M. Weng, and L. M. Wu, "Mass transport of nanocarriers", Langmuir, 21, 2124 (2008).

B. Erdem, E. D. Sudol, V. L. Dimonie, and M. S. El-Aasser, "Encapsulation of inorganic particles via miniemulsion polymerization", Macromol. Sym., 155, 181 (2000). crossref(new window)

D. G. Yu and J. H. An, Colloids Surfaces A: Physicochem. "Titanium dioxide core/polymer shell hybrid composite particles prepared by two-step dispersion polymerization", Eng. Aspects, 237, 87 (2004).

D. G. Yu, J. H. An, J. Y. Bae, S. Kim, Y. E. Lee, S. D. Alm, S. Y. Kang, and K. S. Suh, "Carboxylic acid functional group containing inorganic core/polymer shell hybrid composite particles prepared by two-step", Colloids Surfaces A: Physicochem. Eng. Aspects, 245, 29 (2004).

S. D. Seul, S. R. Lee, and Y. H. Kim, "Poly(methyl methacrylate) encapsulation of calcium carbonate particles", J. Polym. Sci. Part A: Polym. Chem., 42, 4063 (2004).

Y. Yang, X. Z. Kong, C. Y. Kan, and C. G. Sun, "Encapsulation of calcium carbonate by styrene polymerization", Polym. Adv. Technol., 10, 54 (1999). crossref(new window)

L. Quaroni and G. Chunmanov, "Preparation of polymer-coated functionalized silver nanoparticles", J. Am. Chem. Soc., 121, 10642 (1999). crossref(new window)

L. Quaroni and G. J. Chunmanov, "Preparation of polymer-coated functionalized silver nanoparticles", Am. Chem. Soc., 121, 10642 (1999). crossref(new window)

J. H. Kim and T. R. Lee, "Thermo- and pH-responsive hydrogel-coated gold nanoparticles", Chem. Mater., 16, 3647 (2004). crossref(new window)

E. Y. Lee, T. S. Hwang, and J. D. Nam, "Analysis of Thermal Imidization Kinetics of 6FDA-BAPP Polyimide in Relation with Solvent Evaporation", Polymer(Korea), 36, 448 (2012).

J. G. Liu, X. J. Zhao, H.-S. Li. Fan, and S.-Y. Yang, "Organo-soluble fluorinated polyimides derived from bis-trifluoromethyl-substituted aromatic diamines and various aromatic dianhydrides", High Perform. Polym., 18, 851 (2006). crossref(new window)

M. P. Stevens, "Polymer chemistry an introduction", 3rd Ed. p. 106, Oxford University Press Inc., New York (1999).

J. M. Margolis, "Engineering thermoplastics", ed. by J. M. Margolis, p. 315, Marcel Dekker Inc., New York (1985).

R. Yokota, S. Yamamoto, S. Yano, T. Sawaguchi, M. Hasegawa, and R. Sato, "Molecular design of heat resistant polyimides having excellent processability and high glass transition temperature", High Perform. Polymer., 13, S61 (2001). crossref(new window)

J. E. Han, B. K. Jeon, B. J. Goo, S. H. Cho, S. H. Kim, K. S. Lee, Y. H. Park, and J. Y. Lee, "Heat resistant electromagnetic noise absorber films using poly(amide imide)/soft magnet composite", Polym. (Korea), 33, 91 (2009).

A. Halim, P. A. Gurr, A. Blencowe, G. Bryant, S. E. Kentish, and G. G. Qiao, "Synthesis and self-assembly of polyimide/poly(dimethylsiloxane) brush triblock copolymers", Polymer, 54, 520 (2013). crossref(new window)

M. Ghosh and K. L. Mittal, eds., "Polyimides: Fundamentalsand applications", Marcel Dekker, New York (1996).

Cheil Industries Inc.. "Highly heat resistant acrylic copolymer and method for manufacturing same", Inc. Korea Patent, WO2013085153A1 (2013).

J. H. Min and S. K. Min, "The characteristics of poly(acrylamide)-SiOx nanoparticles prepared by graft-polymerizaton", Appl. Chem. Eng., 21, 34 (2010).

Y. Yang and Y. Dan, "Preparation of PMMA/$SiO_2$ composite particles via emulsion polymerization", Colloid Polym. Sci., 281, 794 (2003). crossref(new window)

S. Park, S. Chae, J. Rhee, and S. J. Kang, "A study on electrical and thermal properties of polyimide/MWNT nanocomposites", Bull. Korean Chem. Soc., 2279 (2010).

M. Niwa, S. Nagaoka, and H. Kawakami, "Preparation of novel fluorinated block copolyimide membranes for gas separation", J. Appl. Polym. Sci., 100, 2436 (2006). crossref(new window)

T. P. Bender and Z. Y. Wang, "Synthesis of polyimides and segmented block copolyimides by transimidization", J. Polym. Sci., Part A Polym. Chem., 38, 3991 (2000). crossref(new window)

I. Honma, O. Nishikawa, T. Sugimoto, S. Nomura, and H. Nakajima, "Fuel cells", 2, 52 (2002). crossref(new window)

J. A. Dean, "Lange,s handbook of chemistry", McGraw-Hill Professional, USA (1999).

S. Y. Ha, B. K. Oh, and Y. M. Lee, "Preparation of poly(amideimide siloxane) from trimellitic anhydride chloride, oxylene diamine and oligo(dimethylsiloxane) diamine", Polymer, 36, 3549 (1995). crossref(new window)

M. Y. Jin, H. G. Jung, K. Y. Choi, and C. H. Yoon, "Synthesis and characterization of aromatic poly(amideimide-co-amide)s", Polym. Korea, 21, 973 (1997).

Y. Kano and S. Akiyama, "Contact angle of organic liquids on poly(2-ethylhexyl acrylate-co-acrylic acid)", Polymer, 34, 376 (1993). crossref(new window)