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Changes of Furfural and Levulinic Acid Yield from Small-diameter Quercus mongolica Depending on Dilute Acid Pretreatment Conditions
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 Title & Authors
Changes of Furfural and Levulinic Acid Yield from Small-diameter Quercus mongolica Depending on Dilute Acid Pretreatment Conditions
Jang, Soo-Kyeong; Jeong, Han-Seob; Hong, Chang-Young; Kim, Ho-Yong; Ryu, Ga-Hee; Yeo, Hwanmyeong; Choi, Joon Won; Choi, In-Gyu;
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In this study, dilute acid pretreatment was operated using small-diameter Quercus mongolica for evaluating the yield change of furfural and levulinic acid depending on pretreatment factors. The dilute acid pretreatment was conducted depending on reaction temperature (), reaction time (10-30 min), and sulfuric acid concentration (0-2%, w/w). Then, glucose, XMG (xylose + mannose + galactose), furfural, and levulinic acid contents in the liquid hydrolyzate were measured and analyzed after pretreatment. Glucose content increased to 16.02% as reaction temperature, reaction time, and sulfuric acid concentration increased, but it decreased at the sulfuric acid concentration of 2% (reaction temperature: > , reaction time: > 20 min). On the other hand, reaction temperature had a strong influenced on XMG content, and XMG content decreased to 1.63% through increasing of reaction temperature and sulfuric acid concentration, but XMG content was less affected by changes of reaction time. Furfural content increased with the increase of reaction temperature, reaction time, and sulfuric acid concentration, and maximum furfural content was 7.61% (reaction temperature: , reaction time: 20 min, sulfuric acid concentration: 1%) based on a weight of raw material, while furfural content was dropped in more severe condition than in maximum furfural content condition. Levulinic acid content also increased with higher reaction temperature, reaction time, and sulfuric acid concentration. Especially, the sharp increase of levulinic acid content was observed above , and maximum levulinic acid content was 10.98% (reaction temperature: , reaction time: 30 min, sulfuric acid concentration: 2%). However, less than 1% of furfural and levulinic acid content was obtained in non-acidic catalyst condition that in whole conditions of reaction temperature and reaction time.
dilute acid pretreatment;small diameter Quercus mongolica;furfural;levulinic acid;hydrolyzate;
 Cited by
Carroll, A., Somerville, C. 2009. Cellulosic biofuels. Annual review of plant biology 60: 165-182. crossref(new window)

Chandra, R.P., Bura, R., Mabee, W., Berlin, A., Pan, X., Saddler, J. 2007. Substrate pretreatment: The key to effective enzymatic hydrolysis of lignocellulosics? in: Biofuels. Springer: 67-93.

Chang, C., Cen, P., Ma, X. 2007. Levulinic acid production from wheat straw. Bioresource technology 98(7): 1448-1453. crossref(new window)

Chundawat, S.P., Beckham, G.T., Himmel, M.E., Dale, B.E. 2011. Deconstruction of lignocellulosic biomass to fuels and chemicals. Annual review of chemical and biomolecular engineering 2: 121-145. crossref(new window)

De Jong, W., Marcotullio, G. 2010. Overview of biorefineries based on co-production of furfural, existing concepts and novel developments. International journal of chemical reactor engineering 8(1).

Girisuta, B., Danon, B., Manurung, R., Janssen, L. P. B. M., Heeres, H. J. 2008. Experimental and kinetic modelling studies on the acid-catalysed hydrolysis of the water hyacinth plant to levulinic acid. Bioresource technology 99(17): 8367-8375. crossref(new window)

Girisuta, B., Dussan, K., Haverty, D., Leahy, J. J., Hayes, M. H. B. 2013. A kinetic study of acid catalysed hydrolysis of sugar cane bagasse to levulinic acid. Chemical Engineering Journal 217: 61-70. crossref(new window)

Hendriks, A., Zeeman, G. 2009. Pretreatments to enhance the digestibility of lignocellulosic biomass. Bioresource technology 100(1): 10-18. crossref(new window)

Karimi, K., Kheradmandinia, S., Taherzadeh, M.J. 2006. Conversion of rice straw to sugars by dilute-acid hydrolysis. Biomass and Bioenergy 30(3): 247-253. crossref(new window)

Klingler, F.D., Ebertz, W. 2003. Oxocarboxylic acids. Ullmann's Encyclopedia of Industrial Chemistry.

Lee, Y., Iyer, P., Torget, R.W. 1999. Dilute-acid hydrolysis of lignocellulosic biomass. in: Recent Progress in Bioconversion of Lignocellulosics. Springer: 93-115.

Lopez, F., Garcia, M.T., Feria, M.J., Garcia, J.C., de Diego, C.M., Zamudio, M.A., Diaz, M.J. 2014. Optimization of furfural production by acid hydrolysis of Eucalyptus globulus in two stages. Chemical Engineering Journal 240: 195-201. crossref(new window)

Mandalika, A., Runge, T. 2012. Enabling integrated biorefineries through high-yield conversion of fractionated pentosans into furfural. Green Chemistry 14(11): 3175-3184. crossref(new window)

Martin, C., Garcia, A., Schreiber, A., Puls, J., Saake, B. 2015. Combination of water extraction with dilute-sulphuric acid pretreatment for enhancing the enzymatic hydrolysis of Jatropha curcas shells. Industrial Crops and Products 64: 233-241. crossref(new window)

Mes-Hartree, M., Saddler, J. 1983. The nature of inhibitory materials present in pretreated lignocellulosic substrates which inhibit the enzymatic hydrolysis of cellulose. Biotechnology Letters 5(8): 531-536. crossref(new window)

Mukherjee, A., Dumont, M.J., Raghavan, V. 2015. Review: Sustainable production of hydroxymethylfurfural and levulinic acid: Challenges and opportunities. Biomass and Bioenergy 72: 143-183. crossref(new window)

Olsson, L., Hahn-Hagerdal, B. 1996. Fermentation of lignocellulosic hydrolyzates for ethanol production. Enzyme and Microbial Technology 18(5): 312-331. crossref(new window)

Ragauskas, A.J., Williams, C.K., Davison, B.H., Britovsek, G., Cairney, J., Eckert, C.A., Frederick, W.J., Hallett, J.P., Leak, D.J., Liotta, C.L. 2006. The path forward for biofuels and biomaterials. science 311(5760): 484-489. crossref(new window)

Rajan, K., Carrier, D.J. 2014. Effect of dilute acid pretreatment conditions and washing on the production of inhibitors and on recovery of sugars during wheat straw enzymatic hydrolysis. Biomass and Bioenergy 62: 222-227. crossref(new window)

Sluiter, A., Hames, B., Ruiz, R., Scarlata, C., Sluiter, J., Templeton, D. 2006. Determination of sugars, byproducts, and degradation products in liquid fraction process samples. Golden, CO: National Renewable Energy Laboratory.

Taherzadeh, M.J., Niklasson, C., Liden, G. 1997. Acetic acid-friend or foe in anaerobic batch conversion of glucose to ethanol by Saccharomyces cerevisiae Chemical Engineering Science 52(15): 2653-2659. crossref(new window)

Tao, L., Aden, A., Elander, R.T., Pallapolu, V.R., Lee, Y., Garlock, R.J., Balan, V., Dale, B.E., Kim, Y., Mosier, N.S. 2011. Process and technoeconomic analysis of leading pretreatment technologies for lignocellulosic ethanol production using switchgrass. Bioresource technology 102(24): 11105-11114. crossref(new window)

Werpy, T.A., Holladay, J.E., White, J.F. 2004. Top value added chemicals from biomass: I. results of screening for potential candidates from sugars and synthesis gas. Pacific Northwest National Laboratory (PNNL). Richland. WA (US).

Wyman, C.E., Balan, V., Dale, B.E., Elander, R.T., Falls, M., Hames, B., Holtzapple, M.T., Ladisch, M.R., Lee, Y., Mosier, N. 2011. Comparative data on effects of leading pretreatments and enzyme loadings and formulations on sugar yields from different switchgrass sources. Bioresource technology 102(24): 11052-11062. crossref(new window)

Wyman, C.E., Dale, B.E., Elander, R.T., Holtzapple, M., Ladisch, M.R., Lee, Y. 2005. Coordinated development of leading biomass pretreatment technologies. Bioresource technology 96(18): 1959-1966. crossref(new window)

Yang, M., Kuittinen, S., Zhang, J., Keinanen, M., Pappinen, A. 2013. Effect of dilute acid pretreatment on the conversion of barley straw with grains to fermentable sugars. Bioresource technology 146: 444-450. crossref(new window)