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Natural and Anthropogenic Heavy Metal Deposition to the Snow in King George Island, Antarctic Peninsula
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  • Journal title : Ocean and Polar Research
  • Volume 24, Issue 3,  2002, pp.279-287
  • Publisher : Korea Institute of Ocean Science & Technology
  • DOI : 10.4217/OPR.2002.24.3.279
 Title & Authors
Natural and Anthropogenic Heavy Metal Deposition to the Snow in King George Island, Antarctic Peninsula
Hong, Sung-Min; Lluberas, Albert; Lee, Gang-Woong; Park, Jun-Kun;
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 Abstract
Successive 24 snow samples, collected from a 1.2m snow pit at a site on the summit of Main Dome in King George Island, Antarctic Peninsula, were measured for heavy metals such as Pb, Cd, Cu, and Zn and other chemical species. The mean concentrations of heavy metals are 3.48pg/g for Pb, 0.10pg/g for Cd, 16.6 pg/g for Cu and 15.8 pg/g for Zn, respectively. Pb and Cd concentrations observed in our samples are very comparable to those reported for recent snow at other Antarctic sites, while Zn and Cu levels are much higher than those at other sites. The annual fallout fluxes of all heavy metals approximately calculated are, however, much greater in King George Island than at other sites. With respect to the estimates of natural contributions, sea salt spray is found to be a major contributor to Cd and Zn inputs to the snow and minor to Cu inputs. On the other hand, the anthropogenic input can account for a large part of Pb concentrations. A tentative estimate represents that local emissions could be responsible for more than half of the excess Pb flux to the snow in King George Island.
 Keywords
snow;heavy metals;natural sources;anthropogenic input;
 Language
English
 Cited by
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 References
1.
Arimoto, R., R.A. Duce, B.J. Ray, A.D. Hewitt, and J. Williams. 1987. Trace elements in the atmosphere of American Samoa : concentrations and deposition to the tropical South Pacific. J. Geophys. Res., 92, 8465-8479. crossref(new window)

2.
Barbante, C., C. Turetta, A. Gambaro, G. Capodaglio, and G. Scarponi. 1998. Sources and origins of aerosols reaching Antarctica as revealed by lead concentration profiles in shallow snow. Ann. Glaciol., 27, 674-678.

3.
Batifol, F., C.F. Boutron, and M. De Angelis. 1989. Changes in copper, zinc and cadmium concentrations in Antarctic ice during the past 40,000 years. Nature, 377, 544-546. crossref(new window)

4.
Boutron, C.F. and C.C. Patterson. 1986. Lead concentration changes in Antarctic ice during the Wisconsin/Holocene transition. Nature, 323, 222-225. crossref(new window)

5.
Boutron, C.F. and E.W. Wolff. 1989. Heavy metal and sulphur emissions to the atmosphere from human activities in Antarctica. Atmos. Environ., 23, 1669-1675. crossref(new window)

6.
Chýlek, P., B. Johnson, and H. Wu. 1992. Black carbon concentration in Byrd Station ice core: from 13,000 to 700 years before present. Annal. Geophys., 10, 625-629.

7.
Dick, A.L. 1991. Concentrations and sources of metals in the Antarctic Peninsula aerosol. Geochim. Cosmochim. Acta, 55, 1827-1836.

8.
Duce, R.A., R. Arimoto, B.J. Ray, C.K. Unni, and P.J. Harder. 1983. Atmospheric trace elements at Enewetak atoll: 1. Concentrations, sources and temporal variability. J. Geophys. Res., 88, 5321-5342. crossref(new window)

9.
Flegal, A.R., H. Maring, and S. Niemeyer. 1993. Anthropogenic Pb in Antarctic sea water. Nature, 365, 242-244. crossref(new window)

10.
Gorlach, U. and C.F. Boutron. 1990. Preconcentration of lead, cadmium, copper and zinc in water at the pg g-1 level by non-boiling evaporation. Anal. Chim. Acta, 236, 391-398. crossref(new window)

11.
Hong, S., C.F. Boutron, R. Edward, and V.I. Morgan. 1998. Heavy metals in Antarctic ice from Law Dome: Initial results. Environ. Res., A78, 94-103.

12.
Hong, S., A. Lluberas, and F. Rodriguez. 2000a. A clean protocol for determining ultralow heavy metal concentrations: its application to the analysis of Pb, Cd, Cu, Zn and Mn in Antarctic snow. Korean J. Polar Res., 11, 35-47.

13.
Hong, S., G. Lee, K. Van de Velde, and C.F. Boutron. 2000b. Variability of Pb, Mn, Al and Na concentrations in snow deposited from winter to early summer 1998 in Livingston Island, Antarctic Peninsula. J. Korean Soc. Atmos. Environ., 16, 85-96.

14.
Lee, B.Y., Y.-I. Won, and U. Choi. 2001. Annual weather report, Antarctic King Sejong Station (2000). p. 405-504. In: Annual Report of Environmental Monitoring on Human Impacts at the King Sejong Station, Korea Ocean Research & Development Institute, EC PP 01 001-B2.

15.
Martin, J.H., R.M. Gordon, and S.E. Fitzwater. 1990. Iron in Antarctic waters. Nature, 345, 156-158. crossref(new window)

16.
Minikin, A., M. Legrand, J. Hall, D. Wagenbach, C. Kleefeld, E. Wolff, E.C. Pasteur, and F. Ducroz. 1998. Sulfur-containing species (sulfate and methanesulfonate) in coastal Antarctic aerosol and precipitation. J. Geophys. Res., 103, 10975-10990. crossref(new window)

17.
Mulvaney, R., E.C. Pasteur, and D.A. Peel. 1992. The ratio of MSA to non-sea-salt sulfate in Antarctic Peninsula ice cores. Tellus, 44B, 295-303.

18.
Nriagu, J.O. 1979. Global inventory of natural and anthropogenic emissions of trace metals to the atmosphere. Nature, 279, 409-411. crossref(new window)

19.
Nriagu, J.O. 1989. A global assessment of natural sources of atmospheric trace metals. Nature, 338, 47-49. crossref(new window)

20.
Rosman, K.J.R., W. Chisholm, C.F. Boutron, J.P. Candelone, and C.C. Patterson. 1994. Anthropogenic lead isotopes in Antarctica. Geophys. Res. Lett., 21, 2669-2672. crossref(new window)

21.
Sanudo-Wilhelmy, S.A., K.A. Olsen, J.M. Scelfo, T.D. Foster, and A.R. Flegal. 2002. Trace metal distributions off the Antarctic Peninsula in the Weddell Sea. Mar. Chem., 77, 157-170. crossref(new window)

22.
Suttie, E.D. and E.W. Wolff. 1992. Seasonal input of heavy metals to Antarctic snow. Tellus, 44B, 351-357.

23.
Suttie, E.D. and E.W. Wolff. 1993. The local deposition of heavy metal emissions from point sources in Antarctica. Atmos. Environ., 27A, 1833-1841.

24.
Wedepohl, K.H. 1995. The composition of the continental crust. Geochim. Cosmochim. Acta, 59, 1217-1232. crossref(new window)

25.
Weisel, C.P., R.A. Duce, J.L. Fasching, and R.W. Heaton. 1984. Estimates of the transport of trace metals from the ocean to the atmosphere. J. Geophys. Res., 89, 11607-11618. crossref(new window)

26.
Wen, J., J. Kang, J. Han, Z. Xie, L. Liu, and D. Wang. 1998. Glaciological studies on the King George Island ice cap, South Shetland Islands, Antarctica. Ann. Glaciol., 27, 105-109.

27.
Westerlund, S. and P. Öhman. 1991. Cadmium, copper, cobalt, nickel, lead, and zinc in the water column of the Weddell Sea, Antarctica. Geochim. Cosmochim. Acta, 55, 2127-2146. crossref(new window)

28.
Wolff, E.W. and D.A. Peel. 1988. Concentrations of cadmium, copper, lead and zinc in snow from near Dye 3 in south Greenland. Ann. Glaciol., 7, 61-69.

29.
Wolff, E.W., E.D. Suttie, and D.A. Peel. 1999. Antarctic snow record of cadmium, copper, and zinc content during the twentieth century. Atmos. Environ., 33, 1535-1541. crossref(new window)

30.
Wolff, E.W., J.S. Hall, R. Mulvaney, E.C. Pasteur, D. Wagenbach, and M. Legrand. 1998. Relationship between chemistry of air, fresh snow and firn cores for aerosol species in coastal Antarctica. J. Geophys. Res., 103, 11057-11070. crossref(new window)