JOURNAL BROWSE
Search
Advanced SearchSearch Tips
Formation and Annealing Effect of Tolanethioacetate Self-Assembled Monolayers on Au(111)
facebook(new window)  Pirnt(new window) E-mail(new window) Excel Download
 Title & Authors
Formation and Annealing Effect of Tolanethioacetate Self-Assembled Monolayers on Au(111)
Jeong, Young-Do; Han, Jin-Wook; Kim, Nak-Joong; Lee, Young-Il; Lee, Chang-Jin; Hara, Masahiko; Noh, Jaeg-Eun;
  PDF(new window)
 Abstract
Self-assembled monolayers (SAMs) were formed by adsorption of thioacetyl-terminated tolanethioacetate (TTA) on Au(111) in a 0.5-mM ethanol solution after one day immersion at room temperature. Molecular-scale STM imaging revealed that the TTA SAMs were composed of two mixed phases; an ordered phase with small domains describing a ( × 2 )R30° structure and a disordered phase. Interestingly, after annealing the precovered TTA SAMs on Au(111) at 90 °C for 1 h, the small ordered domains grew unidirectionally, resulting in the formation of unique rod-like domains, which were assigned a ( × 2 )R7° structure. These results will be very useful in understanding the formation and thermal behavior of TTA SAMs on gold surfaces.
 Keywords
Self-assembled monolayers;Tolanethioacetate;Ordered domains;Annealing effect;Scanning tunneling microscopy;
 Language
English
 Cited by
1.
Physical Chemistry Research Articles Published in the Bulletin of the Korean Chemical Society: 2003-2007,;;;

Bulletin of the Korean Chemical Society, 2008. vol.29. 2, pp.450-462 crossref(new window)
2.
Effect of Solution Temperature on the Structure of Thioacetyl-terminated Tolane Self-assembled Monolayers on Au(111),;;;;

Bulletin of the Korean Chemical Society, 2008. vol.29. 6, pp.1105-1106 crossref(new window)
3.
pH-Dependent Stability of Self-Assembled Monolayers on Gold,;;;

Bulletin of the Korean Chemical Society, 2008. vol.29. 9, pp.1843-1846 crossref(new window)
4.
Self-Assembled Monolayers of Dioctyl Diselenides on Au(111),;;;;;

Bulletin of the Korean Chemical Society, 2008. vol.29. 6, pp.1229-1232 crossref(new window)
5.
Formation and Structure of Self-Assembled Monolayers of Octylthioacetates on Au(111) in Catalytic Tetrabutylammonium Cyanide Solution,;;;;;;;

Bulletin of the Korean Chemical Society, 2009. vol.30. 2, pp.441-444 crossref(new window)
1.
Tripodal Osmium Polypyridyl Complexes for Self-Assembly on Platinum Nanoparticles, The Journal of Physical Chemistry Letters, 2011, 2, 12, 1460  crossref(new windwow)
2.
Light-induced reversible modification of the work function of a new perfluorinated biphenyl azobenzene chemisorbed on Au (111), Nanoscale, 2014, 6, 15, 8969  crossref(new windwow)
3.
Unexpected Formation of Dense Phases along with Temperature-Induced, Self-Assembled Terphenylthiolate Monolayers on Au(111), The Journal of Physical Chemistry C, 2016, 120, 31, 17308  crossref(new windwow)
 References
1.
Love, J. C.; Estroff, L. A.; Kriebel, J. K.; Nuzo, R. G.; Whitesides, G. M. Chem. Rev. 2005, 105, 1103 crossref(new window)

2.
Noh, J.; Jeong, Y.; Ito, E.; Hara, M. J. Phys. Chem. C 2007, 111, 2691 crossref(new window)

3.
Noh, J.; Kato, H. S.; Kawai, M.; Hara, M. J. Phys. Chem. B 2006, 110, 2793 crossref(new window)

4.
Noh, J.; Park, H.; Jeong, Y.; Kwon, S. Bull. Korean Chem. Soc. 2006, 27, 403 crossref(new window)

5.
Noh, J. Bull. Korean Chem. Soc. 2006, 27, 944 crossref(new window)

6.
Tour, J. M. Acc. Chem. Res. 2000, 33, 791 crossref(new window)

7.
Smalley, J. F.; Sachs, S. B.; Chidsey, C. E. D.; Dudek, S. P.; Sikes, H. D.; Creager, S. E.; Yu, C. J.; Feldberg, S. W.; Newton, M. D. J. Am. Soc. Chem. 2004, 126, 14620 crossref(new window)

8.
Flood, A. H.; Stoddart, J. F.; Steuerman, D. W.; Heath, J. R. Science 2004, 306, 2055 crossref(new window)

9.
Kagan, C. R.; Afzali, A.; Martek, R.; Gignac, L. M.; Solomon, P. M.; Schrott, A. G.; Ek, B. Nano Lett. 2003, 3, 119 crossref(new window)

10.
Chen, J.; Reed, M. A. Chem. Phys. 2002, 281, 127 crossref(new window)

11.
Cai, L.; Yao, Y.; Yang, J.; Price, D. W.; Tour, J. M. Chem. Mater. 2002, 14, 2905 crossref(new window)

12.
Stapleton, J. J.; Harder, P.; Daniel, T. A.; Reinard, M. D.; Yao, Y.; Price, D. W.; Tour, J. M.; Allara, D. L. Langmuir 2003, 19, 8245 crossref(new window)

13.
Tour, J. M.; Jones II, L.; Pearson, D. L.; Lamba, J. J. S.; Burgin, T. P.; Whitesides, G. M.; Allara, D. L.; Parikh, A. N.; Atre, S. V. J. Am. Chem. Soc. 1995, 117, 9529 crossref(new window)

14.
Kang, Y.; Won, D.; Kim, S. R.; Seo, K.; Choi, H.-S.; Lee, G.; Noh, Z.; Lee, T. S.; Lee, C. Mater. Sci. Eng. C 2004, 24, 43 crossref(new window)

15.
Jeong, Y.; Lee, C.; Ito, E.; Hara, M.; Noh, J. Jpn. J. Appl. Phys. 2006, 45, 5906 crossref(new window)

16.
Bucher, J.-P.; Santesson, L.; Kern, K. Langmuir 1994, 10, 979

17.
Sondag-Huethorst, J. A. M.; Schonenberger, C.; Fokkink, L. G. J. J. Phys. Chem. 1994, 98, 6826

18.
Schonenberger, C.; Sondag-Huethorst, J. A. M.; Jorritsma, J.; Fokkink, L. G. J. Langmuir 1994, 10, 611

19.
Yamada, R.; Wano, H.; Uosaki, K. Langmuir 2000, 16, 5223

20.
Huang, S. H.; Tour, J. M. J. Org. Chem. 1999, 64, 8898 crossref(new window)

21.
Noh, J.; Murase, T.; Nakajima, K.; Lee, H.; Hara, M. J. Phys. Chem. B 2000, 110, 7411

22.
Yang, G.; Liu, G.-y. J. Phys. Chem. B 2003, 107, 8746 crossref(new window)

23.
Chambliss, D. D.; Willson, R. J.; Chiang, S. Phys. Rev. Lett. 1991, 66, 1761 crossref(new window)

24.
Chambliss, D. D.; Willson, R. J. J. Vac. Sci. Technol. B 1991, 9, 933 crossref(new window)