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Effect of n-Butanol on the Micellization of DBS/Brij 35 Mixed Surfactant Systems
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 Title & Authors
Effect of n-Butanol on the Micellization of DBS/Brij 35 Mixed Surfactant Systems
Lee, Byeong-Hwan; Park, In-Jeong;
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 Abstract
The critical micelle concentration (CMC) and the counterion binding constant (B) in a mixed micellar state of the sodium dodecylbenzenesulfonate (DBS) with the polyoxyethylene(23) lauryl ether (Brij 35) at 25oC in water and aqueous solutions of n-butanol (0.1M, 0.2M, and 0.3M) were determined as a function of a1 (the overall mole fraction of DBS) by the use of electric conductivity method and surface tensiometer method. Various thermodynamic parameters (Xi, i, Ci, aiM, , and Hmix) were calculated by means of the equations derived from the nonideal mixed micellar model. The effect of n-butanol on the micellization of the DBS/Brij 35 mixtures has been also studied by analyzing the measured and calculated thermodynamic parameters.
 Keywords
DBS;Brij 35;Critical Micelle Concentration;Counter Ion Binding Constant;Non Ideal Mixed Micellar Model
 Language
Korean
 Cited by
1.
음이온성 계면활성제(DBS)와 비이온성 계면활성제(Brij 30과 Brij 35)와의 혼합미셀화에 대한 비교연구,박인정;이병환;

대한화학회지, 2009. vol.53. 5, pp.491-498 crossref(new window)
2.
순수 물에서 SDS/Brij 30, DBS/Brij 30 및 SDS/DBS 혼합계면활성제의 미셀화에 대한 비교연구,이병환;박인정;

대한화학회지, 2011. vol.55. 3, pp.379-384 crossref(new window)
1.
Comparative Study on the Micellization of SDS/Brij 30, DBS/Brij 30, and SDS/DBS Mixed Surfactant Systems in Pure Water, Journal of the Korean Chemical Society, 2011, 55, 3, 379  crossref(new windwow)
2.
Comparative Study on the Mixed Micellizations of Anionic Surfactant (DBS) with Nonionic Surfactnats (Brij 30 and Brij 35), Journal of the Korean Chemical Society, 2009, 53, 5, 491  crossref(new windwow)
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