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Synthesis, Properties, and X-ray Crystal Structure of Copper(II) Complex with Bis[(2-pyridyl)methyl]-2-(2-pyridyl)ethylamine
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 Title & Authors
Synthesis, Properties, and X-ray Crystal Structure of Copper(II) Complex with Bis[(2-pyridyl)methyl]-2-(2-pyridyl)ethylamine
Choi, Ki-Young;
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 Abstract
The tripodal copper(II) complex [Cu(pmea)(H2O)](ClO4)2·H2O (1) (pmea = bis[(2-pyridyl)methyl]-2-(2-pyridyl)ethylamine) has been synthesized and structurally characterized by X-ray diffraction method. It crystallizes in the triclinic system P-1 with a = 9.9362(9), b = 15.7299(17), c = 18.0562(11) A, α = 68.760(8), β = 76.331(6), γ = 77.092(9)°, V = 2526.2(4) A3, Z = 2. Each copper atom reveals a distorted square pyramidal with three nitrogen atoms of the pmea ligand and water molecule occupying the basal plane and one nitrogen atom from the pyridine ring according the axial position. The cyclic voltammogram of 1 undergoes reversible one-electron oxidation to the CuIII and reversible one-electron reduction to the CuI.
 Keywords
Crystal Structure;Copper(II) Complex;Tripodal Ligand;Distorted Square Pyramidal Geometry;Bis[(2-pyridyl)methyl]-2-(2-pyridyl)ethylamine;
 Language
English
 Cited by
1.
Comparative investigation of the copper(II) complexes of (R)-, (S)- and (R,S)-1-phenyl-N,N-bis(pyridine-3-ylmethyl)ethanamine along with the related complex of (R,S)-1-cyclohexyl-N,N-bis(pyridine-3-ylmethyl)ethanamine. Synthetic, magnetic, and structural studies, Journal of Inclusion Phenomena and Macrocyclic Chemistry, 2011, 71, 3-4, 409  crossref(new windwow)
2.
Interaction of an extended series of N-substituted di(2-picolyl)amine derivatives with copper(II). Synthetic, structural, magnetic and solution studies, Dalton Transactions, 2009, 24, 4795  crossref(new windwow)
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