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Selective Silylation Reaction of Aldehydes with 1,1'-Bis(dimethylsilyl)ferrocene in the Presence of Ni/Pt Catalyst
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 Title & Authors
Selective Silylation Reaction of Aldehydes with 1,1'-Bis(dimethylsilyl)ferrocene in the Presence of Ni/Pt Catalyst
Kim, Jin-Sik; Choi, Sung-Keun; Lee, Jung-Hyun; Kong, Young-Kun;
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 Abstract
The reaction of 1,1'-bis(dimethylsilyl)ferrocene with various aldehydes in the presence of a catalytic amount of Ni(PEt3)4 lead to the acyclic products by monohydrosilylation. The same reaction in the presence of a catalytic amount of (C2H4)Pt(PPh3)2 leads to the different cyclic six membered ring compound by double silylation. Platinum catalyzed double silylation of 4-cyanobenzaldehyde was generated 5,6-ferrocenylene-1,1,4,4,-tetramethyl-2-oxa-2- cyanophenyl-1,4-disylacyclehexane which was crystallized to have crystal structure.
 Keywords
1,1'-bis(dimethylsilyl)ferrocene;Hydrosilylation;Double Silylation;Aldehydes;
 Language
Korean
 Cited by
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