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Synthesis of Some 2-Amino-5-Substituted-1,3,4-Oxadiazoles Through the Electrooxidation of Semicarbazone
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 Title & Authors
Synthesis of Some 2-Amino-5-Substituted-1,3,4-Oxadiazoles Through the Electrooxidation of Semicarbazone
Kumar, Sanjeev;
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 Abstract
The synthesis of 2-amino-5-substituted-1,3,4-oxadiazoles 4 were carried out from the electrooxidation of semicarbazone 3 at the platinum electrode under controlled potential electrolysis in an undivided cell. This is an environmentally benign method in the field of synthetic organic chemistry. The non-aqueous solvents acetic acid and acetonitrile and a supporting electrolyte lithium perchlorate were used for the electrolysis in the electrooxidation. The products were structurally charecterised by IR, -NMR, -NMR and elemental analysis.
 Keywords
Electrooxidation;Constant potential;Electrolysis;Electrolyte;Oxadiazole;Semicarbazone;Platinum electrode;Green chemistry;
 Language
English
 Cited by
1.
Synthesis of 2-Amino-1,3,4-oxadiazoles and 2-Amino-1,3,4-thiadiazoles via Sequential Condensation and I2-Mediated Oxidative C–O/C–S Bond Formation, The Journal of Organic Chemistry, 2015, 80, 2, 1018  crossref(new windwow)
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