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Azomethine Yilde Forming Photoreaction of N-(Tributylstannyl)methylphthalimide
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 Title & Authors
Azomethine Yilde Forming Photoreaction of N-(Tributylstannyl)methylphthalimide
Jeong, Ho-Cheol; Park, Ki-Hyun; Park, Hea-Jung; Cho, Dae-Won; Yoon, Ung-Chan;
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 Abstract
Investigation was conducted to examine whether photochemical reaction of N-(tributylstannyl)- methylphthalimide generates an azomethine ylide intermediate in its excited state as its silyl derivative N-(trimethylsilyl)methylphthalimide which has been observed to form an azomethine ylide. The irradiation of N-(tributylstannyl)methylphthalimide in CN generates mono-deuterated N-methylphthalimide as an exclusive product which supports the efficient generation of azomethine ylide intermediate and its trapping by water molecule through a proto-destannylation pathway. However the generated tributylstannyl subsitiuted ylide was not observed to be trapped with a dipolarophile such as methyl acrylate and acrylonitrile present in the reactions which is in contrast with the ylide from N-(trimethylsilyl)methylphthalimide.
 Keywords
N-(tributylstaanyl)methylphthalimide;Azomethine ylide;Photochemical reaction;Mono-deuterated N-methylphthalimide;
 Language
Korean
 Cited by
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