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Kinetics and Mechanism of Ruthenium(III) Catalyzed Oxidation of Butanone and Uncatalyzed Oxidation of Cychlohexanone by Cerium(IV) in Acid Sulphate Medium
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 Title & Authors
Kinetics and Mechanism of Ruthenium(III) Catalyzed Oxidation of Butanone and Uncatalyzed Oxidation of Cychlohexanone by Cerium(IV) in Acid Sulphate Medium
Sharma, Priyamvada; Hemkar, Shalini; Khandelwal, C.L.; Sharma, P.D.;
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 Abstract
The kinetics of ruthenium(III) chloride catalyzed oxidation of butanone and uncatalyzed oxidation of cyclohexanone by cerium(IV) in sulphuric acid medium have been studied. The kinetic rate law(I) in case of butanone conforms to the proposed mechanism. $$-\frac{1}{2}\frac{d[Ce^{IV}]}{dt}
 Keywords
Kinetics;Ruthenium(III);Oxidation;Ketones; Cerium(IV);
 Language
English
 Cited by
 References
1.
Devra, V.; Sharma, Indu; Sharma, P. D. Int. J. Chem. Kinet. 1993, 245, 538.

2.
Ho, T. L. Synthesis 1973, 347.

3.
Galliani, G.; Rindone, B.; Scolastico, C. Synth. Commun. 1975, 5, 319. crossref(new window)

4.
McAuley, A. Coord. Chem. Rev. 1970, 5, 245. crossref(new window)

5.
Sherril, M. S.; King, C. B.; Spoonen, R. C. J. Am. Chem. Soc. 1943, 65, 170. crossref(new window)

6.
Berka, A.; Vulterin, J.; Zyka, J. Newer Redox Titrants; Pergamon Press: UK, 1965.

7.
Farokhi, S. A.; Kini, A. K.; Nandibewor, S. T. Oxid. Commun. 2007, 20(1), 141.

8.
Singh, K.; Tripathi, H.; Awasthi, A.; Shrivastva, S. N. Oxid. Commun. 2001, 24(3), 388.

9.
Singh, B.; Sisodia, A. K.; Chand, R. Oxid. Commun. 1986, 9, 219.

10.
Singh, M. P.; Singh, H. S.; Verma, M. K. J. Phys. Chem. 1980, 84, 256. crossref(new window)

11.
Pillai, G. C.; Rajaman, J.; Kuriacose, J. C. Ind. J. Chem. A, 1977, 15(A), 608.

12.
Panigrahi, G. D.; Mipro, P. K. Ind. J. Chem. 1976, 14(A), 579.

13.
Latshaw, M. J. Am. Chem. Soc. 1925, 47, 793.

14.
Agarwal Anju, Sharma Gayatri, Khandelwal, C. L.; Sharma, P. D. Inorg. React. Mech. 2002, 4, 233 crossref(new window)