Synthesis and Characterization of Homo Binuclear Macrocyclic Complexes of UO<sub>2</sub>(VI), Th(IV), ZrO(IV) and VO(IV) with Schiff-Bases Derived from Ethylene diamine/Orthophenylene Diamine, Benzilmonohydrazone and Acetyl Acetone

Mohapatra, R.K.; Ghosh, S.; Naik, P.; Mishra, S.K.; Mahapatra, A.; Dash, D.C.

doi:10.5012/jkcs.2012.56.1.062

Title & Authors

Synthesis and Characterization of Homo Binuclear Macrocyclic Complexes of UO₂(VI), Th(IV), ZrO(IV) and VO(IV) with Schiff-Bases Derived from Ethylene diamine/Orthophenylene Diamine, Benzilmonohydrazone and Acetyl Acetone
Mohapatra, R.K.; Ghosh, S.; Naik, P.; Mishra, S.K.; Mahapatra, A.; Dash, D.C.;

Abstract

A series of homo binuclear complexs of the type ${$[M_2(L/L^$ , [where ${$M=U{O_2}^{2+},\;Th^{4+},\;ZrO^{2+}$}$ ] and ${$[(VO)_2(L/L^$ , L=1,5,6,9,12,15,16,20 octaaza-7,813,14-tetraphenyl-2,4,17,19-tetramethyl-1,4,6,8,12,14,16,19-docosaoctene (OTTDO) or L'=10:11;21:22-dibenzo-1,5,6,9,12,15,16,20-octaaza-7,813,14-tetraphenyl-2,4,17,19-tetramethyl-1,4,6,8,12,14,16,19-docosaoctene (DOTTOT), n=4 for ${$U{O_2}^{2+}$}$ , ${$ZrO^{2+}$}$ n=8 for ${$Th^{4+}$}$ m=1,2,3 respectively, have been synthesized in template method from ethylenediamine/orthophenylene diamine, benzil monohydrazone and acetyl acetone and characterized on the basis of elemental analysis, thermal analysis, molar conductivity, magnetic moment, electronic, infrared, ${$^1H$}$ -NMR studies. The results indicate that the VO(IV) ion is penta co-ordinated yielding paramagnetic complexes; ${$UO_2(VI)$}$ , ZrO(IV) ions are hexa co-ordinated where as Th(IV) ion is octa co-ordinated yielding diamagnetic complexes of above composition. The fungi toxicity of the ZrO(IV) and VO(IV) complexes against some fungal pathogen has been studied.

Keywords

Schiff base;Binuclear macrocyclic complexes;Template synthesis;Structure and spectral properties;

Language

English

Cited by

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