JOURNAL BROWSE
Search
Advanced SearchSearch Tips
Solubilization of 4-Alkylbenzoic Acid Isomers by the Aqueous Solution of Tetradecyltrimethylammonium Bromide
facebook(new window)  Pirnt(new window) E-mail(new window) Excel Download
 Title & Authors
Solubilization of 4-Alkylbenzoic Acid Isomers by the Aqueous Solution of Tetradecyltrimethylammonium Bromide
Lee, Nam-Min; Lee, Byung-Hwan;
  PDF(new window)
 Abstract
The interaction of 4-alkylbenzoic acid isomers with the micellar system of TTAB (tetradecyltrimethylammonium bromide) was studied by the UV/Vis spectrophotometric method. The solubilization constants () of 4-alkylbenzoic acid isomers into the TTAB micellar system and the critical micelle concentration (CMC) of TTAB have been measured with the change of temperature. Various thermodynamic parameters have been calculated and analyzed from those measurements. The results show that the values of for the solubilization of all the isomers are negative and the values of and are all positive within the measured temperature range. The effects of additives (n-butanol and NaCl) on the solubilization of 4-alkylbenzoic acid isomers have been also measured. There was a great change on the values of and CMC simultaneously with these additives. From these changes we can postulate that the solubilization sites of 4-alkylbenzoic acids are the core or deep palisade region of the TTAB micelle.
 Keywords
TTAB;Solubilization constant;4-Alkylbenzoic acid;Critical micelle concentration;Isostructural temperature;
 Language
Korean
 Cited by
1.
TTAB와 다른 계면활성제(DTAB, CTAB, Tween-20, Tween-40 및 Tween-80)와의 혼합미셀화에 대한 연구,이남민;이병환;

대한화학회지, 2012. vol.56. 5, pp.556-562 crossref(new window)
2.
TTAB 용액에서 p-브로모페놀의 가용화와 TTAB의 미셀화와의 상관관계에 대한 연구,이병환;

대한화학회지, 2013. vol.57. 6, pp.665-671 crossref(new window)
3.
TTAB 수용액에서 p-할로겐화 페놀유도체들의 가용화에 대한 열역학적 연구,이병환;

공업화학, 2014. vol.25. 1, pp.20-26 crossref(new window)
4.
양이온성, 비이온성 및 혼합성 계면활성제에 의한 4-클로로벤조산의 가용화에 대한 연구,이남민;이병환;

한국유화학회지, 2014. vol.31. 2, pp.244-254 crossref(new window)
5.
Dodecyldimethyl(3-sulfopropyl)ammonium Hydroxide와 다른 계면활성제와의 혼합미셀화에 관한 연구,이남민;이병환;

한국유화학회지, 2014. vol.31. 4, pp.602-611 crossref(new window)
6.
Lauryl Sulfobetaine과 혼합계면활성제에 의한 4-클로로벤조산의 가용화에 대한 연구,이남민;이병환;

한국유화학회지, 2014. vol.31. 4, pp.612-622 crossref(new window)
7.
TTAB 수용액에서 4-할로겐화 페놀유도체의 가용화에 미치는 NaCl과 n-부탄올의 효과,이병환;

대한화학회지, 2014. vol.58. 6, pp.517-523 crossref(new window)
1.
Relationship between the Micellization of TTAB and the Solubilization of p-Bromophenol in TTAB Solution, Journal of the Korean Chemical Society, 2013, 57, 6, 665  crossref(new windwow)
2.
Thermodynamic Study on the Solubilization of p-Halogenated Phenol Derivatives in TTAB Solution, Applied Chemistry for Engineering, 2014, 25, 1, 20  crossref(new windwow)
3.
Effects of NaCl and n-Butanol on the Solubilization of 4-Halogenated Phenols in Aqueous Solution of TTAB, Journal of the Korean Chemical Society, 2014, 58, 6, 517  crossref(new windwow)
4.
Mixed Micellizations of TTAB with Other Surfactants (DTAB, CTAB, Tween-20, Tween-40, and Tween-80), Journal of the Korean Chemical Society, 2012, 56, 5, 556  crossref(new windwow)
 References
1.
Lee, B. H; Christian, S. D.; Tucker, E. E.; Scamehorn, J. F. Langmuir 1991, 7, 1332. crossref(new window)

2.
Mehta, S. K.; Chaudhary, S.; Kumar, R.; Bhasin, K. K. J. Phys. Chem. B 2009, 113, 7188. crossref(new window)

3.
Chakraborty, T.; Chakraborty, I.; Moulik, S. P.; Ghosh, S. Langmuir 2009, 25, 3062. crossref(new window)

4.
Chaghi, R.; Menorval, L. C.; Charnay, C.; Derrin, G.; Zajac, J. Langmuir 2009, 25, 4868. crossref(new window)

5.
Su, T. L.; Lai, C. C.; Tsai, P. C. J. Surfact. Deterg. 2011, 14, 363. crossref(new window)

6.
Gharanjig, K.; Sadeghi-Kiakhani, M,; Tehrani-Bagha, A. R.; Khosravi, A.; Menger F. M. J. Surfact. Deterg. 2011, 14, 381. crossref(new window)

7.
Nazar, M. F.; Shah, S. S.; Khosa, M. A. J. Surfact. Deterg. 2010, 13, 529. crossref(new window)

8.
Rao, K. J.; Paria, S. J. Phys. Chem. B 2009, 113, 474. crossref(new window)

9.
Mehta, S. K.; Chaudhary, S.; Kumar, R.; Bhasin, K. K. J. Phys. Chem. B 2009, 113, 7188. crossref(new window)

10.
Mahata, A.; Sarkar, D.; Bose, D.; Ghosh, D.; Girigoswami, A.; Das, P.; Chattopadhyay, N. J. Phys. Chem. B 2009, 113, 7517. crossref(new window)

11.
Nakamura, S.; Kobayashi, L.; Tanaka, R.; Yamashita, T. I.; Motomura, K.; Moroi, Y. Langmuir 2008, 24, 15. crossref(new window)

12.
Ali. M.; Jha, M.; Das, S. K.; Saha, S. K. J. Phys. Chem. B 2009, 113, 15563. crossref(new window)

13.
Banipal, T. S.; Sood, A. K.; Singh, K. J. Surfact. Deterg. 2011, 14, 235. crossref(new window)

14.
Lee, B. H.; Lee, N. M. J. Kor. Chem. Soc. 2010, 54, 374. crossref(new window)

15.
Lee, B. H. Appl. Chem. Eng. 2011, 22, 473.

16.
Behera, K.; Om, H.; Pandey, S. J. Phys. Chem. B 2009, 113, 786. crossref(new window)

17.
Sammalkorpi, M.; Karttunen, M.; Haatoja, M. J. Phys. Chem. B 2009, 113, 5863. crossref(new window)

18.
Lee, B. H.; Park, I. J. J. Kor. Chem. Soc. 2011, 55, 1.

19.
Rozner, S.; Kogan, A.; Mehta, S.; Somasundaran, P.; Aserin, A.; Garti, N.; Ottaviani, M. F. J. Phys. Chem. B 2009, 113, 700. crossref(new window)

20.
Penfold, J; Green, T. A.; Jones, G. C.; Ford, G.; Roberts, C.; Hubbard, J.; Petkov, J.; Thomas, R. K.; Grillo, I. Langmuir 2008, 24, 12209. crossref(new window)

21.
Jusufi, A.; Hynninen, A. P.; Haataja, M.; Panagiotopoulos, A. Z. J. Phys. Chem. B 2009, 113, 6314. crossref(new window)

22.
Khan, M. N.; Azri, H. R. J. Phys. Chem. B 2010, 114, 8089. crossref(new window)