JOURNAL BROWSE
Search
Advanced SearchSearch Tips
Spectrophotometric Quantitative Analysis of Cu(II) Ion Using N,N'-bis(4-methoxysalicylidene)phenylendiamine
facebook(new window)  Pirnt(new window) E-mail(new window) Excel Download
 Title & Authors
Spectrophotometric Quantitative Analysis of Cu(II) Ion Using N,N'-bis(4-methoxysalicylidene)phenylendiamine
Kim, Sun-Deuk; Seol, Jong-Min;
  PDF(new window)
 Abstract
A Schiff base ligand, N,N'-bis(4-methoxysalicylidene)phenylendiamine (4--salphen) was synthesized. Using the 4--salphen, the spectrophoto-metric quantitative analysis of Cu(II) ion in aqueous solution was performed. The optimum condition for the quantitative analysis of Cu(II) ion was determined as the following; the concentration of 4--salphen is , ratio between solvent DMSO and water is 50/50(v/v), pH is 5.5. After 1 hr water incubation at and then the absorbance measurements at 388 nm, a calibration curve () with a correlation coefficient (=0.9963) was obtained in this condition. Using this optimized condition, the quantitative analysis of Cu(II) ion was performed with various samples such as hot spring water, semiconductor factory waste water and treated water from sewage treatment plant. The average value of the measured values agreed well with standard value with a range of 0.6~5.4%. The limit of determination was 31.77 ng/mL ().
 Keywords
4--salphen;Spectrophotometric quantitative analysis of Cu(II);Limit of determination;
 Language
Korean
 Cited by
 References
1.
Buffle, J. Complexation Reactions in Aquatic Systems: An Analytical Approach; Ellis Horwood: Chichester, UK, 1990; pp 1-15.

2.
Fu, D.; Yuan, D. Spectrochim. Acta, Part A 2007, 66, 434. crossref(new window)

3.
Kenduzler, E.; Turuker, A. R. Anal. Chim. Acta 2003, 408, 163.

4.
Ghiasvand, A. R.; Ghaderi, R.; Kakanejadifard, A. Talanta 2004, 287.

5.
Szigeti, Z.; Bitter, I.; Toch, K.; Latkoczy, C.; Fliegel, D. J.; Gunther, D.; Pretsch, E. Anal. Chim. Acta 2005, 532, 129. crossref(new window)

6.
Tabrizi, A. B. J. Hazardous Materials 2007, 139, 260. crossref(new window)

7.
Marczenko, Z. Separation and Spectrophotometric Determination of Elements, Ellis Horwood Limited; John Wiley & Sons: New York, 1986; pp 257-268.

8.
Cimerman, Z.; Galic, N.; Bosner, B. Anal. Chim. Acta 1997, 343, 145. crossref(new window)

9.
Ishii, H.; Einaga, H. Analyst 1969, 94, 1038. crossref(new window)

10.
Ishii, H.; Einaga, H. Bunseki Kagaku 1969, 18, 230. crossref(new window)

11.
J-S.; Jung, D-I.; Lee, I-H. Anal. Sci. Technol. 1991, 4(2), 163.

12.
Kim, Y-N.; Choi, K-S.; Lee, I-H.; Bark, K-M.; Chung, R-J. J. Kor. Chem. Soc. 1992, 36(1), 95.

13.
Kabak, M.; Elmali, A.; J. Phys. 1998, 22, 797.

14.
Oyaizu, K.; Tsuchida, E.; Inorg. Chim. Acta 2003, 355, 414. crossref(new window)

15.
Nabei, A.; Kuroda-Sowa, T.; Okubo, T.; Maekawa, M.; Munakata, M. Inorg. Chim. Acta 2008, 361, 3489. crossref(new window)

16.
Mingxing, Q.; Mei, W.; Ren, H. J. Molecular Catalysis A: Chemical 2000, 160, 243. crossref(new window)

17.
Gholiveand, M. B.; Ahmadi, F.; Rafiee, E. Electroanalysis 18 2006, 16, 1620.

18.
Giacomelli, A.; Rotunno, T.; Senatore, L. Inorg. Chem. 1985, 24, 1303. crossref(new window)

19.
Kim, E-J.; Kim, Y-S.; Choi, J-M. Bull. Korean Chem. Soc. 2008, 29(1), 99. crossref(new window)

20.
Kim, S-D.; Seol, J-M. J. Kor. Chem. Soc. 2011, 55(3), 463. crossref(new window)

21.
Aggett, J.; Richardson, R. A. Anal. Chim. Acta 1970, 50, 269. crossref(new window)

22.
Aggett, J.; Khoo, A. W.; Richardson, R. A. J. Inorg. Nucl. Chem. 1981, 43, 1867. crossref(new window)

23.
Kim, Y-S.; In, G.; Kim, M-S.; Choi, J-M. Bull. Korean Chem. Soc. 2006, 27(11), 1757. crossref(new window)

24.
Eaton, A. D.; Clesceri, L. S.; Greenberg, A. E. Standard Methods for the Examination of Water and Wastewater, 19th ed.; A.P.H.A.: Washington, DC 2005, 1995; pp 1-21-1-23.

25.
Pavia, D. L.; Lampman, G. M.; Kriz, G. S. Introduction to Spectroscopy, 3rd ed.; Thomson Corporation Korea Limited and SciPlus: 2007; pp 636-644.