Thermophysical Properties of Acetophenone with Ethylchloroacetate at Temperatures of 303.15, 313.15 and 323.15 K

Saravanakumar, K.; Baskaran, R.; Kubendran, T.R.

doi:10.5012/jkcs.2012.56.4.424

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Thermophysical Properties of Acetophenone with Ethylchloroacetate at Temperatures of 303.15, 313.15 and 323.15 K

Journal title : Journal of the Korean Chemical Society
Volume 56, Issue 4, 2012, pp.424-430
Publisher : Korean Chemical Society
DOI : 10.5012/jkcs.2012.56.4.424

Title & Authors

Thermophysical Properties of Acetophenone with Ethylchloroacetate at Temperatures of 303.15, 313.15 and 323.15 K
Saravanakumar, K.; Baskaran, R.; Kubendran, T.R.;

Abstract

Densities, viscosities, refractive indices and speed of sounds of the binary mixtures of Acetophenone with Ethylchloroacetate were measured over the entire mole fractions at (303.15, 313.15 and 323.15) K. From these experimental results, excess molar volume ${$V^E$}$ , viscosity deviation ${${\Delta}{\eta}$}$ , refractive index deviation ${${\Delta}n_D$}$ , deviations in speed of sound ${${\Delta}u$}$ , deviations in isentropic compressibility ${${\Delta}k_s$}$ and excess intermolecular free length ${${\Delta}L_f$}$ were calculated. The viscosity data have been correlated with the equations of Grunberg and Nissan, Hind et al., Tamura and Kurata, Katti and Chaudri, Sedgwick, Krishnan-Laddha and McAllister. The thermo physical properties under study were fit to the Jouyban-Acree model. The excess values were correlated using Redlich-Kister polynomial equation to obtain their coefficients and standard deviations. It was found that in all cases, the data obtained fitted with the values correlated by the corresponding models very well. The results are interpreted in terms of molecular interactions occurring in the solution.

Keywords

Viscosity;Density;Refractive index;Ultrasonic velocity;Molecular interactions;

Language

English

Cited by

2time(s) in CrossRef

Thermophysical and thermoacoustical properties of acetophenone with ethyl butyrate at temperatures of 303.15, 313.15, and 323.15 K, Journal of Engineering Thermophysics, 2016, 25, 2, 227

Thermo-physical properties for the binary system of propiophenone-methyl acetate at 303.15–313.15 K, Russian Journal of Physical Chemistry A, 2015, 89, 10, 1828

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