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The Electrochemical Behavior of Ni-base Metallic Glasses Containing Cr in H2SO4 Solutions
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 Title & Authors
The Electrochemical Behavior of Ni-base Metallic Glasses Containing Cr in H2SO4 Solutions
Arab, Sanaa.T.; Emran, Khadijah.M.; Al-Turaif, Hamad A.;
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 Abstract
In order to develop alloy resistance in aggressive sulphat ion, the corrosion behavior of metallic glasses , and (at %) at different concentrations of solutions was examined by electrochemical methods and Scanning Electron Microscope (SEM) and X-ray Photoelectron Microscopy (XPS) analyses. The corrosion kinetics and passivation behavior was studied. A direct proportion was observed between the corrosion rate and acid concentration in the case of and alloys. Critical concentration was observed in the case of alloy. The influence of the alloying element is reflected in the increasing resistance of the protective film. XPS analysis confirms that the protection film on the alloy was NiS which is less protective than that formed on Cr containing alloys. The corrosion rate of and . alloys containing 7% and 13% Cr are mm/y which is lower about 43-54 times of the alloy (free of Cr). The high resistance of alloy at the very aggressive media may due to thicker passive film of which hydrated to hydrated chromium oxyhydroxide.
 Keywords
Nickel base alloys;Metallic glasses;Passivity;Role of chromium;Corrosion;
 Language
English
 Cited by
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Temperature effect on the corrosion and passivation characterization of Ni82.3Cr7Fe3Si4.5B3.2 alloy in acidic media, International Journal of Minerals, Metallurgy, and Materials, 2016, 23, 2, 205  crossref(new windwow)
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