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Aluminium Salt of Phosphomolybdic Acid Fabricated by Nanocasting Strategy: An Efficient System for Selective Oxidation of Benzyl Alcohols
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 Title & Authors
Aluminium Salt of Phosphomolybdic Acid Fabricated by Nanocasting Strategy: An Efficient System for Selective Oxidation of Benzyl Alcohols
Aliyan, Hamid; Fazaeli, Razieh; Habibollahi, Nasibeh;
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 Abstract
Preparation of (AlPMo) salts, supported on mesostructured SBA-15 silica, by the reaction deposition strategy causes the formation of isolated AlPMo nanocrystals inside the nanotubular channels. The remarkable characteristic of the SBA-15 structure is that all the cylindrical pores are connected by some small channels. This makes the whole pore system in SBA-15 three-dimensional. We have used 2D hexagonal SBA-15 silicas as hard templates for the nanofabrication of AlPMo salt nanocrystal. The oxidation of alcohols occurs effectively and selectively with as the oxidant. AlPMo salt nanocrystal was used as the catalyst.
 Keywords
Nanocasting;Mesoporous silica SBA-15;Green chemistry;Polyoxometalates (POMs);
 Language
English
 Cited by
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