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Microwave-assisted Synthesis of Mixed Ligand Complexes of Zn(II), Cd(II) and Hg(II) Derived from 4-aminopyridine and Nitrite Ion: Spectral, Thermal and Biological Investigations
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 Title & Authors
Microwave-assisted Synthesis of Mixed Ligand Complexes of Zn(II), Cd(II) and Hg(II) Derived from 4-aminopyridine and Nitrite Ion: Spectral, Thermal and Biological Investigations
Dhaveethu, Karuthakannan; Ramachandramoorthy, Thiagarajan; Thirunavukkarasu, Kandasamy;
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 Abstract
Zn(II), Cd(II) and Hg(II) complexes with a general composition[], where L=4-aminopyridine (4AP) and were prepared under microwave irradiation. The metal complexes were characterized by elemental analyses, molar conductance, IR, Far-IR, electronic, NMR (, ), XPS spectral and thermal studies. The spectroscopic studies reveal the composition, different modes of bonding, electronic transition, different chemical environment of C and H atoms and the electronic state of the metal atoms. On the basis of the characterization data, tetrahedral geometry is suggested for all the complexes. The free ligand (4-aminopyridine) and their metal complexes were screened against phytopathogenic fungi and bacteria in vitro and the activities were compared.
 Keywords
Mixed ligand complexes;4-aminopyridine;Nitrito;Biological activities;
 Language
English
 Cited by
1.
Spectroscopic, Thermal and Biological Studies of Zn(II), Cd(II) and Hg(II) Complexes Derived from 3-Aminopyridine and Nitrite Ion,;;;

대한화학회지, 2013. vol.57. 6, pp.712-720 crossref(new window)
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Spectroscopic, Thermal and Biological Studies of Zn(II), Cd(II) and Hg(II) Complexes Derived from 3-Aminopyridine and Nitrite Ion, Journal of the Korean Chemical Society, 2013, 57, 6, 712  crossref(new windwow)
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